• Title/Summary/Keyword: ionic strength

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The Dispersion Stability of $\alpha-Fe_2O_3$ Particulate Soil in the Anionic/Nonionic Mixed Surfactant Solution (음/비이온계 혼합계면활성제 용액에서 $\alpha-Fe_2O_3$ 입자의 분산안정성)

  • 정선영;강인숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.6
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    • pp.854-861
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    • 2004
  • To estimate dispersion stability of particles in anionic and nonionic surfactant mixed solution, suspending power was examined as functions of duration time of suspension, ionic and nonionic surfactant mixed ratio, surfactant concentration, kinds of electrolyte, ionic strength and mole numbers of oxyethylene additions to nonionic surfactant using $\alpha$-Fe$_2$O$_3$ particle as the model of particulate soil. The suspending power of anionic and nonionic surfactant mixed solution was relatively higher than that of anionic and nonionic surfactant single solution regardless of solution concentration. The suspending power was gradually decreased with increasing duration time of suspension. In the absence of electrolyte, the effect of surfactant concentration on suspending power was small but in solution with electrolyte, suspending power was lowest at 1 % surfactant concentration. With 1${\times}$10$^{-3}$ ionic strength and polyanionic electrolyte in solution, the suspending power was high but effects of oxyethylene mole number to nonionic surfactant on suspending power was small. Generally the suspending power was gradually increased with decreasing the particle size. Hence the suspending power was inversely related to the particle size.

Preparation and Characterization of Novel Temperature and pH Sensitive (NIPAM-co-MAA) Polymer Microgels and Their Volume Phase Change with Various Salts (pH 감응성 NIPAM-co-MAA 고분자 마이크로젤의 제조 및 분석과 염 종류에 따른 부피상 변화)

  • Khan, Mohammad Saleem;Khan, Gul Tiaz;Khan, Abbas;Sultana, Sabiha
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.794-801
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    • 2013
  • Novel microgels of N-isopropylacrylamide (NIPAM)-co-methacrylic acid (MAA) (NIPAM-co-MAA) with different contents of N,N-methylene bis acrylamide (MBA) were prepared by emulsion polymerization technique and were studied by Fourier transform infrared spectroscopy (FTIR), dynamic light scattering (DLS) and zeta potential measurement. Effect of pH, temperature and different salts concentration on the microgel particles was investigated. DLS results have shown that the hydrodynamic radius of the microgel increased upon increasing pH and decreased upon increasing temperature. The swelling/deswelling behaviors as determined by DLS showed the ionic repulsions of the carboxyl group of the methacrylic acid and hydrophobic interaction of NIPAM. The effect of various salts on volume phase transition temperature (VPTT) was also investigated. Upon increasing salt concentration, VPTT became broad and shifted to a lower temperature. Electrophoretic mobility measurements showed an increase with increasing pH and temperature at a constant ionic strength.

Effects of Ionic Strength in the Medium on Sample Preconcentration Utilizing Nano-interstices between Self-Assembled Monolayers of Gold Nanoparticles

  • Nguyen, Ngoc-Viet;Wu, Jian-Sheng;Jen, Chun-Ping
    • BioChip Journal
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    • v.12 no.4
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    • pp.317-325
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    • 2018
  • This paper investigated the effects of ionic strength in the medium on a preconcentrator for a protein sample with low concentration. The preconcentration chip was designed and fabricated using a polydimethylsiloxane replica through standard lithophotography. A glass substrate is silanized prior to functionalizing the nanoparticles for self-assembly at a designed region. Due to the overlap of electrical double layers in a nanofluidic channel, a concentration polarization effect can be achieved using an electric field. A nonlinear electrokinetic flow is induced, resulting in the fast accumulation of proteins in front of the induced ionic depletion zone, so called exclusion-enrichment effect. Thus, the protein sample can be driven by electroosmotic flow and accumulated at a specific location. The chip is used to collect fluorescein isothiocyanate-labeled bovine serum albumin (FITC-BSA) diluted in phosphate-buffered saline (PBS) buffer solution. Different concentrations of the buffer media were studied herein. Fluorescence intensity images show that the buffer concentration of 4 mM is more appropriate than all the other ones. The sample of FITC-BSA with an initial concentration of $10{\mu}M$ in the 4 mM PBS solution increases its concentration at the desired region by up to 50 times within 30 min, demonstrating the results in this investigation.

The Influence of Aqueous Ionic, Condition on the Adsorption Features of Fluoride Ion on Waste Oyster Shell (수중 이온 환경이 폐굴껍질에 대한 불소 이온의 흡착 양상에 미치는 영향)

  • Lee, Jin-Sook;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.23 no.3
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    • pp.314-318
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    • 2007
  • The feasibility of the employment of waste oyster shell as an adsorbent for fluoride ion has been tested by considering the effect ionic condition on the adsorption of fluoride ion on oyster shell. The adsorption capacity of oyster shell for fluoride ion was found not to be significantly influenced by the ionic strength of aqueous environment. The existence of complexing agent such as nitrilotriacetic acid in wastewater decreased the adsorbed amount of fluoride ion by forming a stable complex of $CaT^-$ and the adsorption reaction of fluoride ion on oyster shell was examined to be endothermic. The coexisting heavy metal ionic adsorbate in wastewater hindered the adsorption of fluoride ion, however, its adsorbed amount was increased as the particulate size of adsorbent was decreased. Finally, a serial adsorption column test has been conducted for a practical application of adsorption process and the breakthrough of the column adsorption was observed in 22 hours under the experimental condition.

SYNCHRONIZATION OF UNIDIRECTIONAL RING STRUCTURED IDENTICAL FITZHUGH-NAGUMO NETWORK UNDER IONIC AND EXTERNAL ELECTRICAL STIMULATIONS

  • Ibrahim, Malik Muhammad;Jung, Il Hyo
    • East Asian mathematical journal
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    • v.36 no.5
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    • pp.547-554
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    • 2020
  • Synchronization of unidirectional identical FitzHugh-Nagumo systems coupled in a ring structure under ionic and external electrical stimulations is investigated. In this network, each neuron is only connected and transmit signals to its next neuron via synaptic strength called gapjunctions. Adaptive control theory and Lyapunov stability theory are used to propose a unique control scheme with necessary and sufficient conditions which guarantee the synchronization of the neuronal network. Finally, the effectiveness of the proposed scheme is shown through numerical simulations.

Ionic Impurities and Dielectric Breakdown of XLPE (이온성 불순물과 폴리에틸렌의 절연파괴특성)

  • 윤종복;서광석;변재동;한재홍;김상준
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.58-61
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    • 1997
  • Effects of ionic impurities on the dielectric breakdown of the crosslinked polyethylene (XLPE) were studied using aqueous electrolytes. It was found that the AC breakdown strength of XLPE decreases considerably when the ions are present in the electrodes composed of aqueous electrolyte. Details of results were described.

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Hypsochromic Shifts in Retinochrome Absorption Spectra in the Presence of Nitrate

  • Takemori, Nobuaki;Mizukami, Taku;Tsujimoto, Kazuo
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.264-266
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    • 2002
  • The absorption wavelength of the protonated retinal Schiff base can be controlled by the surrounding environment. An external anion is related to fine adjustment of the absorption wavelength. The addition of anion to retinochrome solution caused blue shift in spectra. The increase of the shift was dependent on the ion concentration. The large shift value was obtained as 20 nm at the saturated concentration of nitrate. The shift intensity for the nitrate addition exceeded that of chloride. Seemingly, it depends on the ionic strength or lyotropic character of the anion. However, neither of sulphate nor gluconate ion showed remarkable blue shift. These phenomena were accounted for with (1) delocalization of the positive charge in the conjugated polyene system, (2) ionic bonding strength between the counter ion (glutamate) and the proton, and/or (3) interaction of the added anion with the proton on Schiff base.

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Radionuclide Sorption in the Geosphere: Role of Single Minerals (지하매질에서의 방사성핵종흡착: 단일광물의 역할)

  • Cho, Young-Hwan;Hyun, Sung-Pil;Hahn, Pilsoo
    • Proceedings of the Mineralogical Society of Korea Conference
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    • 2001.06a
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    • pp.40-40
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    • 2001
  • The sorption behavior of Cs(I), Sr(II), and U(VI) on representative single minerals(oxide and clay) and rocks were comparatively studied by using batch type sorption experiment. The effects of pH, ionic strength and the sorption mechanism were also discussed. It was found that mineral structure played as a main factor governing the sorption characteristics of Cs(I), Sr(II). The sorption of Cs(I) and Sr(II) on minerals showed ionic strength-dependency, which is a indirect sign of weak binding between metal cation and mineral surfaces. However, the sorption behavior of U(VI) was quite different compared with that of Cs(I), and Sr(II). Fe-oxide minerals showed strong tendency for U(VI) sorption, dominating the sorption in the composite/mixture systems. The surface characteristics which arise from mineral structure, and the affinity of metal ions to the sorption sites of minerals are the key to understand the role of minerals in the radionuclide sorption.

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Examination of an Algerian Clay in the Retention of Zinc Ions Charged in Brackish Water

  • Fadel, Ammar;Nacef, Saci
    • Korean Chemical Engineering Research
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    • v.55 no.5
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    • pp.685-689
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    • 2017
  • We studied the removal of zinc ions from synthetic brackish water by an adsorption method using natural Algerian Bentonite (NAB). The effect of the main physico chemical parameters-contact time, pH, temperature, ionic strength, clay weight and initial metal ion concentrations on the removal of $Zn^{+2}$-were investigated. The results showed that equilibrium was attained within 10 min of stirring time. The retention capacity of $Zn^{+2}$ increased with the increase of pH, the adsorbent dose and ionic strength. A modelization study showed that the adsorption follows Langmuir isotherm, while its kinetics was pseudo-second-order. Based on the results, it was concluded that NAB, which is natural and available, could be used as an alternative for the removal of zinc from saline aqueous solutions.