• Journal of Korean Society of Water and Wastewater
• /
• v.28 no.1
• /
• pp.83-89
• /
• 2014

The aim of this study is to investigate the sorption/ion exchange of radioactive nuclides such as $Cs^+$ and $Sr^{2+}$ by synthetic Na-micas. In order to prepare Na-micas, two natural micas (phlogopite and biotite) were used as precursor materials. XRD, SEM, and EDS analyses were used to examine material characterization of synthetic Na-micas. Analyses of materials revealed that Na-micas were successfully obtained from natrual micas by K removal treatment. On the other hand, single solute (Cs or Sr) and bi-solute (Cs/Sr) sorption experiments were carried out to determine sorption capacity of Na-micas for Cs and Sr under different pH and ionic strength conditions. Uptake of Cs and Sr by micas in bi-solute system was lower than in single-solute system. Additionally, Langmuir and Langmuir competitive models were applied to describe sorption isotherm of Na-micas. bi-solute system was well described by Langmuir competitive models. For the results obtained in this study, Na-micas could be promising sorbents to treat multi-radioactive species from water and groundwater.

• Membrane and Water Treatment
• /
• v.6 no.2
• /
• pp.127-139
• /
• 2015

Rejection of ionic solutes by reverse osmosis (RO) and nanofiltration (NF) membranes is controlled mainly by electrochemical interaction as well as pore size, but it is very difficult to directly evaluate such electrochemical interaction. In this work, we used an inverse HPLC method to investigate the interaction between ionic solutes and poly (m- phenylenediaminetrimesoyl) (PPT), a polymer similar to the skin layer of polyamide RO and NF membranes. Silica gel particles coated with PPT were used as the stationary phase, and aqueous solutions of the ionic solutes were used as the mobile phase. Chromatographs obtained for the ionic solutes showed features typical of exclusion chromatographs: the ionic solutes were eluted faster than water (mobile phase), and the exclusion intensity of the ionic solute decreased with increasing solute concentration, asymptotically approaching a minimum value. The charge density of PPT was estimated to be ca. 0.007 mol/L. On the basis of minimum exclusion intensity, the exclusion distances between a salt and neutralized PPT was examined, and the following average values were obtained: 0.49 nm for 1:1 salts, 0.57 nm for 2:1 salts, 0.60 nm for 1:2 salts, and 0.66 nm for 2:2 salts. However, $NaAsO_2$ and $H_3BO_3$, which are dissolved at neutral pH in their undissociated forms, were not excluded.

• Proceedings of the Membrane Society of Korea Conference
• /
• 2000.11a
• /
• pp.71-74
• /
• 2000

• Membrane Journal
• /
• v.13 no.1
• /
• pp.29-36
• /
• 2003

A characterization of the permeation and separation using single salt solution was carried out with charged composite membranes. Various charged composite membranes were fabricated by blending an ionic polymer with a nonionic polymer in different ratios. In this study, sodium alginate, chitosan and poly(vinyl alcohol) were employed as anionic, cationic and nonionic polymers, respectively. The permeation and separation behaviors of the aqueous salt solutions have been investigated through the charged composite membranes with various charge densities. As the content of the ionic polymer increased in the membrane, the hydrophilicity of the membrane increased, and pure water flux and the solution flux increased correspondingly, indicating that the permeation performance through the membrane is determined mainly by its hydrophilicity. Electrostatic interaction between the charged membrane and ionic solute molecules, that is, Donnan exclusion, was observed to be attributed to salt rejection to a greater extent, and molecular sieve mechanism was effective for the separation of salts under a similar electrostatic circumstance of solutes.

• Bulletin of the Korean Chemical Society
• /
• v.24 no.1
• /
• pp.55-59
• /
• 2003

This work is focused on analyzing ion-pair interactions and showing the effect of solvent induced inter-atomic attractions in various dielectric environments. To estimate the stability of ion-pairs, SCI-PCM ab initio MO calculations were carried out. We show that the solvent-induced attraction or ‘cavitation' energy of the ion-pair interactions in solution that arises mainly from the stabilization of the water molecules by the generation of an electrostatic field. In fact, even the strong electrostatic interaction characteristic of ion-pair interactions in the gas phase cannot overcome the destabilization or reorganization of the water molecules around solute cavities that arise from cancellation of the electrostatic field. The solvent environment, possibly supplemented by some specific solvent molecules, may help place the solute molecule in a cavity whose surroundings are characterized by an infinite polarizable dielectric medium. This behavior suggests that hydrophobic residues at a protein surface could easily contact the side chains of other nearby residues through the solvent environment, instead of by direct intra-molecular interactions.

• Membrane Journal
• /
• v.11 no.1
• /
• pp.22-28
• /
• 2001

Various charged homogeneous membranes were fabricated by blending of ionic polymer with a non-ionic polymer with different ratios. In this study. sodium alginate, chitosan and poly(vinyl alcohol) were employed as anionic. cationic and non-ionic polymers, respectively. The permcation and separation behaviors of aquCOll::; salt solutions have been investigated through the charged membranes. As the content of ionic polymer increases in the membrane, the hydrophilicity of the membrane increases and pure water flux as well as solution flux increases correspondingly, indicating that the permeation performance through the membrane is cletemunecl mainly by its hydrophilicity-, Electrostatic interaction between the charged membrane and ionic solute molecules, that is. Donnan exclusion was observed to be attributed to salt rejection to a great deal of extent, and molecular sieve mechanism was effective [or the separation of the salt solution under a similar electrostatic circumstance of solutes.

• Economic and Environmental Geology
• /
• v.45 no.5
• /
• pp.525-533
• /
• 2012

Snowmelt from seasonal snow covers can be significant in many environments of northern and alpine areas. Water flow and chemical transport resulting from snowmelt have been studied for an understanding of contributions to watersheds or catchments. A Mobile-Immobile water Model (MIM) was developed to describe the movement of ionic tracers through a snowpack by Lee et al. (2008a) and Lee et al. (2008b). To validate the model used in the studies, mass balance calculations of the model were conducted and comparisons were made between model results and analytical solutions in this work. Mass balance was calculated based on the fact that change in total mass within a snowpack with time is equal to sum of any change in the flux of water or ionic tracers into and out of the snowpack. Calculations of both water and ionic mass show almost perfect agreement between changes of two water and solute mass fluxes. Comparisons between model results and analytical solutions including wave velocity and effective saturation show almost perfect agreement.

• Membrane and Water Treatment
• /
• v.13 no.2
• /
• pp.63-72
• /
• 2022

Choline chloride-glycerol (1:2 mol), a natural deep eutectic solvent (NADES) is examined as a draw solution in forward osmosis (FO) for dewatering application. The NADES is easy to prepare, low in toxicity and environmentally benign. A polyamide thin film composite membrane was used. Characterization of the membrane confirmed porous membrane structure with good hydrophilicity and a low structural parameter (722 ㎛) suitable for FO application. A dilute solution of 20% (v/v) NADES was enough to generate moderate water flux (14.98 L m^-2h^-1) with relatively low reverse solute flux (0.125 g m^-2h^-1) with deionized water feed. Application in dewatering industrial wastewater feed showed reasonably good water flux (11.9 L m^-2h^-1) which could be maintained by controlling the external concentration polarization and fouling/scaling mitigation via simple periodic deionized water wash. In another application, clarified sugarcane juice could be successfully concentrated. Recovery of the draw solute was accomplished easily by chilling utilizing thermo responsive phase transition property of NADES. This study established that low concentration NADES can be a viable alternative as a draw solute for dewatering of wastewater and other heat sensitive applications along with a simple recovery process.

• Korean Membrane Journal
• /
• v.5 no.1
• /
• pp.54-60
• /
• 2003

The rejection properties and flux rates of silica nanoparticles in ultrafiltration membranes has been investigated. Cross-flow permeation experiments were conducted using polycarbonate track-etch flat membranes with pore sizes of 30 and 50 nm, and a silica nanoparticle solute with particle sizes of 5 and 18 nm with narrow size distributions. The fluxes and rejection factors were investigated at various particle concentrations, cross-flow velocities, pH, and ionic strengths of solution. Even though the size of the silica nanoparticles was much smaller than that of the membrane pores, the observed rejection rates were very high compared with those for a similar-sized polymer (dextran). The observed rejection rate decreased with increasing ionic strength, which implies that the transport mechanism of the silica nanoparticles is significantly influenced by electrostatic repulsion between particles and membranes.

• Korean Chemical Engineering Research
• /
• v.43 no.2
• /
• pp.266-271
• /
• 2005

This paper studied succinic acid recovery from organic acid mixture by using mono-polar membrane electrodialysis. Current efficiency, solute recovery efficiency, energy consumption, and separation factor were measured at various pHs and concentration ratios. The separation factor of succinic acid could be interpreted in terms of ionization degree, molecular weight, ionic conductance, average charge, and initial feed composition.