• Title/Summary/Keyword: ionic conductor

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$CO_{2}$ sensing characteristics of solid electrolyte gas sensor with the sensing membrane prepared by the mixture of alkali metal carbonate and binder (알카리 금속 탄산염과 결착제의 혼합물을 감지물질로 하는 고체전해질 가스센서의 $CO_{2}$ 감응 특성)

  • Chai, Yu-Sug;Song, Kap-Duk;Kang, Bong-Hwi;Seo, Moo-Gyo;Lee, Duk-Dong
    • Journal of Sensor Science and Technology
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    • v.7 no.2
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    • pp.111-116
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    • 1998
  • The simple solid electrolyte carbon dioxide sensor with heaters were fabricated by using Li ionic conductor. Two Au electrodes were used for the reference and sensing electrode respectively. Two types of gas sensors, type ( I ) and type (II), were fabricated. Type ( I ) sensor was fabricated by the method of melting and crystallizing alkali metal carbonate at the temperature of $420{\sim}500^{\circ}C$. The sensing membrane of type (II) sensor was formed by the printing method on sensing electrode after metal carbonate was mixed with binder. The response characteristics of sensors fabricated for the carbon dioxide were investigated for a range of $CO_{2}$ concentration from 950 ppm to 9,950 ppm at operating temperature $420^{\circ}C$. Type ( I ) sensor and type (II) sensor showed the sensitivity of 62 mV/decade and 65 mV/decade respectively. The emf/decade of type (II) sensor tested at $420^{\circ}C$ almost followed the theoretical value of Nernst's equation and showed stable response characteristics with the fast response time of $15{\sim}20$ sec. Also type (II) sensor showed excellent stability and reproduction properties for 60 days.

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Performance Analysis of Pyrotechnic Devices on the Reliability of Thermal Batteries (열전지의 신뢰성에 미치는 파이로테크닉 부품의 특성분석)

  • Cheong, Hae-Won;Kang, Sung-Ho;Kim, Kiyoul;Cho, Jang-Hyeon;Ryu, Byungtae;Baek, Seung-Su
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.116-123
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    • 2019
  • Thermal batteries are also called molten-salt batteries as the electrolyte is mainly composed of molten salt. The molten-salt electrolyte is a solid that does not conduct electricity at room temperature, but when it is melted by a pyrotechnic heat source, it becomes an excellent ionic conductor. Thermal batteries are a kind of pyrotechnic battery because they operate only when the solid electrolyte is melted by the heat energy provided by pyrotechnic materials. Pyrotechnic components used in a thermal battery include heat sources, fuse strips, and an igniter. The reliability of these pyrotechnic components critically affects the reliability and performance of the battery that must supply electricity stably to guided munitions even under extreme environmental conditions. Different igniter types offer different advantages: notch-type igniters offer improved ignition probability, whereas film-type igniters offer improved safety. The addition of metal oxides to the heat paper could improve the burn rate, and the ignition reliability could be greatly improved by using it with a flame igniter at the same time. Using a two-step reduction process, high-purity Fe particles in coral form can be safely obtained.