• 제목/요약/키워드: ion migration

검색결과 191건 처리시간 0.032초

Cd으로 오염된 토양의 EK 정화시 Humic acid가 미치는 영향

  • 구한모;김정환;한상재;김수삼
    • 한국지하수토양환경학회:학술대회논문집
    • /
    • 한국지하수토양환경학회 2001년도 추계학술발표회
    • /
    • pp.131-134
    • /
    • 2001
  • This research was carried out to evaluate the effects of humic acid on contaminated kaoline with cadmium when electrokinetic remediation. Electrokinetic remediation test was performed depending on humic acid concentrations(0.005, 0.01, 0.05, 0.083, 0.1, 0.5, 5.0mg/g) in contaminated kaoline with cadmium and time(4, 8, 12days). In the absence of humic acid, Cd at the anode showed the highest concentration while Cd concentrations were lower as the concentration of humic acid increased. The removal of Cd to the anode reservoir was increased with increasing humic acid concentration by electroosmosis or ion migration.

  • PDF

ANODICALLY-BONDED INTERFACE OF GLASS TO ALUMINIUM

  • Takahashi, Makoto;Nishikawa, Satoru;Chen, Zheng;Ikeuchi, Kenji
    • 대한용접접합학회:학술대회논문집
    • /
    • 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
    • /
    • pp.65-69
    • /
    • 2002
  • An Al film deposited on the Kovar alloy substrate was anodically-bonded to the borosilicate glass, and the bond interfaces was closely investigated by transmission electron microscopy. Al oxide was found to form a layer ~l0 nm thick at the bond interface, and fibrous structure of the same oxide was found to grow epitaxially in the glass from the oxide layer. The fibrous structure grew with the bonding time. The mechanism of the formation of this fibrous structure is proposed on the basis of the migration of Al ions under the electric field. Penetration of Al into glass beyond the interfacial Al oxide was not detected. The comparison of the amount of excess oxygen ions generated in the alkali depletion layer with that incorporated in the Al oxide suggests that the growth of the alkali-ion depletion layer is controlled by the consumption of excess oxygen to form the interfacial Al oxide.

  • PDF

PROPERTIES OF THE CRYSTALLINE POLYIMIDE FILM DEPOSITED BY IONIZED CLUSTER BEAM

  • Whang, Chung-Nam
    • 한국재료학회:학술대회논문집
    • /
    • 한국재료학회 1992년도 추계학술발표강연 및 논문개요집
    • /
    • pp.6-6
    • /
    • 1992
  • Ionized cluster beam deposition (ICBD) technique has been employed to fabricate high-purity crystalline polyimide (PI) film. The pyromellitic dianhydride (PMDA) and oxydianiline (ODA) were deposited using dual ICB sources, Fourier trans forminfraredspectroscopy (FT-IR), X-ray photoemission spectroscopy (XPS), and Transmission electron microscopy (TEM)study show that the bulk and surface chemical properties and the crystalline structure are very sensitive to the ICBD conditions such as cluster ion acceleration voltage and ionization voltage, At optimum ICBD conditions, the PI films have a maximum imidization, negligible impurities(∼1% isoimide), and a good crystalline structure probably due to the high surface migration energy and surface cleaning effect. These characteristics are superior to those of films deposited by other techniques such as colvent cast, vapowr deposition, or sputtering techniques.

  • PDF

셀룰로오스 기반 Electro-Active Paper (EAPap)를 이용한 변형률 센서 응용 (Strain Sensor Application using Cellulose Electro-Active Paper (EAPap))

  • 장상동;이상우;김주형;김재환
    • 한국소음진동공학회:학술대회논문집
    • /
    • 한국소음진동공학회 2009년도 춘계학술대회 논문집
    • /
    • pp.462-465
    • /
    • 2009
  • Cellulose based electro-active paper (EAPap) is a new smart material that has a potential to be used in biomimetic actuator and sensor. Beside of the natural abundance, cellulose EAPap is fascinating with its biodegradability, lightweight, high mechanical strength and low actuation voltage. An actuating mechanism of EAPap is revealed to be the combination of ion migration effect and piezoelectricity. EAPap can generate the electrical current and voltage when the mechanical stress applied due to its electro-mechanical characteristics. In this paper, we investigated the feasibility of EAPap as a mechanical strain sensor.

  • PDF

PCB 절연체에서 전하 형성과 수분 흡수의 영향 (Influence of Water Absorption and Charge Formation in PCB)

  • 구정현;최용성;이경섭
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2008년도 제39회 하계학술대회
    • /
    • pp.2307-2308
    • /
    • 2008
  • We observed internal space charge behavior for two types of epoxy composites under dc electric fields to investigate the influence of water at high temperature. In the case of glass/epoxy specimen, homocharge is observed at water-treated specimen, and spatial oscillations become clearer in the water-treated specimens. Electric field in the vicinity of the electrodes shows the injection of homocharge. In aramid/epoxy specimens, heterocharge is observed at water-treated specimens, i.e. negative charge accumulates near the anode, while positive charge accumulates near the cathode. Electric field is enhanced just before each electrode. In order to further examine the mechanism of space charge formation, we have developed a new system that allows in situ space charge observation during ion migration tests at high temperature and high humidity. Using this in situ system.

  • PDF

생체모방 종이작동기(electro-active paper)의 전기기계적인 구동 시뮬레이션 (Electromechanical Simulation of Cellulose Based Biomimetic Electro-Active Paper)

  • 장상동;김재환;김흥수
    • 한국소음진동공학회논문집
    • /
    • 제17권12호
    • /
    • pp.1179-1183
    • /
    • 2007
  • Electro-Active paper(EAPap) is a new smart material that has a potential to be used in biomimetic actuator and sensor. It is made by cellulose that is abundant material in nature. EAPap is fascinating with its biodegradability, lightweight, large displacement, high mechanical strength and low actuation voltage. Actuating mechanism of EAPap is known to be the combined effects of ion migration and piezoelectricity. However, the electromechanical actuation mechanisms are not yet to be established. This paper presents the modeling of the actuation behavior of water infused cellulose samples and their composite dielectric constants calculated by Maxwell-Wagner theory. Electro-mechanical forces were calculated using Maxwell stress tensor method. Bending deflection was evaluated from simple beam model and compared with experimental observation, and which result in good correlation with each other.

Analysis of Inorganic Anions in Various Drinking Waters by Capillary Electrophoresis

  • Choi, One-Kyun;Cho, Jae-Sun
    • 분석과학
    • /
    • 제8권4호
    • /
    • pp.835-841
    • /
    • 1995
  • The quantitation of inorganic anions in various drinking waters were investigated using capillary electrophoresis(CE) and the results were compared with ion chromatography(IC). With CE, in contrast to IC, was demonstrated rapid analysis, good efficiency, a low detection limit and the low comsumption of a solvent and samples. CE analysis was used 5 mM sodium chromate(pH 8.0) containing 20 mM tetraalkylammoniumbromide at -25kV applied voltage with indirect UV detection at 254 nm. This results in exceedingly short analysis time within 3 min. with efficiencies approaching 200,000 theoretical plates. The coefficients of variants of migration time are less than 0.8% and those of peak area are less than 2.3%. Detection limits for quantitative determination were 300 ppb-50 ppm level. These optimum conditions are applicable to various samples without pretreatment.

  • PDF

Streaming potential and groundwater contamination

  • Baker Simon S.;Cull James P.
    • 지구물리와물리탐사
    • /
    • 제7권1호
    • /
    • pp.41-44
    • /
    • 2004
  • Measurements of streaming potential can provide a means for the detection and quantification of contaminants in groundwater prior to remediation. However, laboratory determinations of specific electrolyte properties are required for an adequate analysis of the hydraulic gradient in complex situations. Data obtained for the King River in Tasmania confirm a linear relationship linking streaming potential data and hydraulic gradients. Laboratory samples at low concentration (0.001M KCl) indicate values in the range 20-80 mV/cm of water pressure, while for higher concentrations (0.01M KCl) values are less than 25 mV/cm. Similar ion concentrations are observed in the King River, consistent with field correlations indicating values for streaming potential close to 15 mV/cm. In-situ fluid samples are required for more detailed analysis of local anomalies that may be associated with variations in recharge and migration of contaminants.

Adsorption of Ammonia on Municipal Solid Waste Incinerator Bottom Ash Under the Landfill Circumstance

  • Yao, Jun;Kong, Qingna;Zhu, Huayue;Zhang, Zhen;Long, Yuyang;Shen, Dongsheng
    • Korean Chemical Engineering Research
    • /
    • 제53권4호
    • /
    • pp.503-508
    • /
    • 2015
  • The adsorption characteristics of ammonia on MSWI bottom ash were investigated. The effect of the variation of the landfill environmental parameters including pH, anions and organic matter on the adsorption process was discussed. Results showed that the adsorption could be well described by pseudo-second-order kinetics and Langmuir model, with a maximum adsorption capacity of 156.2 mg/g. The optimum adsorption of ammonia was observed when the pH was 6.0. High level of ion and organic matter could restrict the adsorption to a low level. The above results suggested that MSWI bottom ash could affect the migration of ammonia in the landfill, which is related to the variation of the landfill circumstance.

Temperature effect on multi-ionic species diffusion in saturated concrete

  • Damrongwiriyanupap, Nattapong;Li, Linyuan;Limkatanyu, Suchart;Xi, Yunping
    • Computers and Concrete
    • /
    • 제13권2호
    • /
    • pp.149-171
    • /
    • 2014
  • This study presents the mathematical model for predicting chloride penetration into saturated concrete under non-isothermal condition. The model considers not only diffusion mechanism but also migration process of chloride ions and other chemical species in concrete pore solution such as sodium, potassium, and hydroxyl ions. The coupled multi-ionic transport in concrete is described by the Nernst-Planck equation associated with electro-neutrality condition. The coupling parameter taken into account the effect of temperature on ion diffusion obtained from available test data is proposed and explicitly incorporated in the governing equations. The coupled transport equations are solved using the finite element method. The numerical results are validated with available experimental data and the comparison shows a good agreement.