• Title/Summary/Keyword: ion concentration

Search Result 2,954, Processing Time 0.031 seconds

Modeling of diffusion-reaction behavior of sulfate ion in concrete under sulfate environments

  • Zuo, Xiao-Bao;Sun, Wei;Li, Hua;Zhao, Yu-Kui
    • Computers and Concrete
    • /
    • v.10 no.1
    • /
    • pp.79-93
    • /
    • 2012
  • This paper estimates theoretically the diffusion-reaction behaviour of sulfate ion in concrete caused by environmental sulfate attack. Based on Fick's second law and chemical reaction kinetics, a nonlinear and nonsteady diffusion-reaction equation of sulfate ion in concrete, in which the variable diffusion coefficient and the chemical reactions depleting sulfate ion concentration in concrete are considered, is proposed. The finite difference method is utilized to solve the diffusion-reaction equation of sulfate ion in concrete, and then it is used to simulate the diffusion-reaction process and the concentration distribution of sulfate ion in concrete. Afterwards, the experiments for measuring the sulfate ion concentration in concrete are carried out by using EDTA method to verify the proposal model, and results show that the proposed model is basically in agreement with the experimental results. Finally, Numerical example has been completed to investigate the diffusion-reaction behavior of sulfate ion in the concrete plate specimen immersed into sulfate solution.

Effects of Salt in Soil Condition on Chlorophyll Fluorescence and Physiological Disorder in Panax ginseng C. A. Meyer (토양 염류 농도가 인삼 잎의 엽록소 형광반응 및 생리장해 발생에 미치는 영향)

  • Kim, Jang Uk;Hyun, Dong Yun;Kim, Young Chang;Lee, Jung Woo;Jo, Ick Hyun;Kim, Dong Hwi;Kim, Kee Hong;Sohn, Jae Keun
    • Korean Journal of Medicinal Crop Science
    • /
    • v.23 no.6
    • /
    • pp.446-453
    • /
    • 2015
  • Background : Excessively high concentration of sodium ion causednutrient deficiency and significantly decrease growth. This study was carried out to determine the limiting concentration range of sodium ion in the soil of ginseng field. Methods and Results : The growth of the ginseng cultivar Chunpoong reduced with increase in salinity, and the rate of growth reduction was higher in shoots than that of roots. Particularly, ginseng plants cultivated at high level of nitrate nitrogen or sodium may suffer delayed development and stunted growth. Chlorophyll damage occurred on the leaves of ginseng planted in relatively high levels (> $0.2cmol^+/kg$) of sodium ion, as determined by the fluorescence reaction. The incidence of physiological disorder in ginseng cultivated at 249 sites was correlated with the concentration of sodium ion in the soils. About 74% of ginseng fields in which physiological disorders occurred had concentrations of sodium ion in soil greater than $0.2cmol^+/kg$. In contrast, the concentration of sodium ions at 51 of 85 sites where no damage occurred was relatively ($0.05cmol^+/kg-0.15cmol^+/kg$). Conclusions : The concentration of sodium ion in soil of ginseng fields can be classified into three levels optimum (${\leq}0.15$), permissible allowance (0.15 - 0.2) and excessive (> 0.2).

Intercalation Voltage and Lithium Ion Conduction in Lithium Cobalt Oxide Cathode for Lithium Ion Battery (리튬 이온 전지용 리튬 코발트 산화물 양극에서의 삽입 전압과 리튬 이온 전도)

  • Kim, Dae-Hyun;Kim, Dae-Hee;Seo, Hwa-Il;Kim, Yeong-Cheol
    • Journal of the Korean Electrochemical Society
    • /
    • v.13 no.4
    • /
    • pp.290-294
    • /
    • 2010
  • We performed a density functional theory study to investigate the intercalation voltage and lithium ion conduction in lithium cobalt oxide for lithium ion battery as a function of the lithium concentration. There were two methods for the intercalation of lithium ions; the intercalation of a lithium ion at a time in the individual layer and the intercalation of lithium ions in all the sites of one layer after all the sites of another layer. The average intercalation voltage was the same value, 3.48 V. However, we found the former method was more favorable than the latter method. The lattice parameter c was increased as the increase of the lithium concentration in the range of x < 0.25 while it was decreased as increase of the lithium concentration in the range of x > 0.25. The energy barrier for the conduction of lithium ion in lithium cobalt oxide was increased as the lithium concentration was increased. We demonstrated that the decrease of the intercalation voltage and increase of the energy barrier as the increase of the lithium concentration caused lower output voltage during the discharge of the lithium ion battery.

Analysis of the Change of Amino Acids by Cadmium and Polyamine-Treatment in Spring Radish Young Cotyledons and Roots (무우 유식물의 자엽과 뿌리에서 Cadmium 이온과 Polyamine 처리에 의한 아미노산 변화의 분석)

  • Cho, Bong-Heuy;Park, Sun Young
    • Analytical Science and Technology
    • /
    • v.11 no.2
    • /
    • pp.135-138
    • /
    • 1998
  • The change of amino acids was analysed with cotyledons and roots of young spring radish by the treatment of $Cd^{2+}$ ion and $Cd^{2+}$ ion plus PA. The concentration of Asp was decreased by the treatment of $Cd^{2+}$ ion, but Ala, Phe, Val, Ile, Typ, Lys and Arg was increased in the cotyledons. The concentration of Lys and Arg was decreased by the treatment of $Cd^{2+}$ ion plus PA at the same time. The concentration of basic amino acids, His, Lys and Arg was increased by the treatment of $Cd^{2+}$ ion, and decreased by the treatment of $Cd^{2+}$ ion and $Cd^{2+}$ ion plus PA in the roots. Only the concentration of Pro was increased by the treatment of $Cd^{2+}$ ion plus PA. This results showed that Pro was induced against stress of PA, and assumed that the change of other amino acids concentration may be relation to the metabolism against stress.

  • PDF

A Study on the Ion Exchange and th Chemical Stability of Na-fluor-tetrasilicic Mica by $H^+$ions (나트륨형불소 4 규소운모의 $H^+$ 이온교환 및 화학적인 안정성에 관한 연구)

  • 송종택
    • Journal of the Korean Ceramic Society
    • /
    • v.22 no.1
    • /
    • pp.35-39
    • /
    • 1985
  • Synthetic mica $NaMg_{2.5}(Si_4O_{10})F_2 (Na-TSM)$ was treated with HCl solution and H-type exchange resin to investigate the chemical stability and the ion exchange by measuring the dissolution of chemical components and the exchanged $H^+$ ion. The replacement of $Na^+$ ion occurred in contact with HCl solution and H-type ion exchange resin at the surface of Na-TSM particles reached $Na^+$ ions at maximum value of 70~80%. $Mg^{2+}$ ion of octahedral layer became to dissolve from the pH2 solution and th amount of it dissolved in-creased almost proportional to $H^+$ ion concentration from around 0.02N $H^+$ ion equilibrium concentration. The crystalline structure of Na-TSM was destructed by dissolution of Mg2+ ion in cncentrated hydrochloric acid solution and resulted silica gel precipitation.

  • PDF

Determination of L-Dopa by Spectrofluorimetry Using Co-fluorescence Enhancer (보조 형광증가제를 이용한 L-Dopa의 형광분광법적 정량)

  • Lee, Sang Hak;Ahn, Jung Mi
    • Journal of the Korean Chemical Society
    • /
    • v.44 no.6
    • /
    • pp.541-546
    • /
    • 2000
  • Methods to determine L-dopa(L-3,4-dihydroxyphenylalanine) in aqueous solution by spectrofluorimetry based upon the ligand sensitized luminescence of Tb(III) ion L-dopa complex have been studied. Tb(III) ion and Lu(III) ion were used as ligand sensitized fluorescencer and co-fluorescence enhancer, respectively. The effects of excitation wavelength, pH, concentration of Tb(III) ion, concentration of Lu(III) ion and emission wavelength on the fluorescence intensity were investigated. The fluorescence intensity of the Tb(III) ion L-dopa complex was further increased with addition of Lu(III) ion. The calibration curve for L-dopa was linear over the range from 5.0 ${\times}$ $10^{-7}$ M to 1.0${\times}$ $10^{-4}$ M and the detection limit was 4.0 ${\times}$ $10^{-8}$ M under the optimal experimental conditions of 300 nm, 8.0, 1.0 ${\times}$ $10^{-4}$ M and 545 nm for excitation wavelength, pH, concentration of Tb(III) ion and emission wavelength, respectively. When Lu(III) ion was added to Tb(Ⅲ) ion L-dopa complex, the concentration range of linear response and detection limit were 1.0${\times}$$10^{-8}$ M to 2.0 ${\times}$ $10^{-4}$ M and 1.0 ${\times}$ $10^{-9}$ M, respectively under the optimal experimental conditions of 300 nm, 8.5, 1.0 ${\times}$ $10^{-5}$ M, 1.0 ${\times}$ $10^{-5}$ M, 545 nm for excitation wavelength, pH, concentration of Tb(III) ion, concentration of Lu(III) ion and emission wavelength, respectively.

  • PDF

Distribution of Negative Air Ion Concentration in Urban Neighborhood Park by Distance to Road - A Case of Yangjae Citizen's Forest, Seoul - (도로와의 거리에 따른 도시 근린공원의 음이온 농도 분포차이 - 서울시 양재 시민의 숲을 대상으로 -)

  • Lee, Hyunjin;Lee, Dong Kun;Kim, Bomi
    • Journal of Environmental Impact Assessment
    • /
    • v.27 no.2
    • /
    • pp.152-169
    • /
    • 2018
  • The purpose of this study was to analyze the effect of adjacentroads on the concentration of negative air ions in urban neighborhood park. The measured factors were negative air ion concentration, positive airion concentration, airtemperature,relative humidity, wind speed, green formation volume factor (GVZ) and distance from highway and general road. The mean negative air ion concentration was $206ea/cm^3$ and the positive air ion concentration was $416ea/cm^3$ in the influence zone of roads. On the other hand, the mean negative air ion was $339ea/cm^3$ and the positive air ion was $229ea/cm^3$ in the unaffected zone of roads, which are inner areas of the park. The difference of the negative air ion concentration according to the influence of the road was statistically significant. The negative air ion concentration model was presented by integrating the correlation analysis with the influence factors, and the explanatory power of the model was increased by adding the influence factor of the road.

Effect of Ca and BSA on Hydrogen Ion Concentration in Bovine Sperm Washed Solution (Ca과 BSA가 소 정자세척액내 수소이온농도에 미치는 영향)

  • 박영식;임경순
    • Korean Journal of Animal Reproduction
    • /
    • v.15 no.3
    • /
    • pp.201-205
    • /
    • 1991
  • This study was carried out to investigate the effects of Ca and BSA on hydrogen ion concentration in sperm washed solution. The results obtained were as follows : 1. The hydrogen concentration in 1st and 2nd sperm washed solutions was signifcinatly(p<0.01) higher when sperm was washed with SHPsolution containing 2mM Ca than when sperm washed with SHP solution or SHP solution containing 10mM Ca. 2. The hydrogen ion concentration in sperm washed solution was significnatly(p<0.05) higher when seprm was washed with SHP solution containing BSA-FAF than when sperm was washed with SHP solution or SHP solution containing BSA-V.

  • PDF

Effect of Chloride Ion-reducing Bacteria on the Chloride ion Concentration in Cement Mortars (염소이온 저감능 박테리아가 모르타르의 염소이온 농도에 미치는 영향)

  • Hwang, Ji-Won;Yoon, Hyun-Sub;Yang, Keun-Hyeok
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2022.04a
    • /
    • pp.49-50
    • /
    • 2022
  • This study examined the potential of halophilic bacteria in reducing the chloride ion concentration within the cement mortars exposed to chloride attack. As a result of the experiment, the compressive strength of mortar with Halomonas venusta showed an equivalent performance to that of counterpart mortars without bacteria. Also, the chloride ion concentration measured in mortars including Halomonas Venusta was 71% lower than that of the counterpart mortars without bacteria.

  • PDF

Electroconvective vortex on an Ion Exchange Membrane under Shear Flow (전단흐름 하에 이온교환막 위에서 발생하는 전기수력학적 와류)

  • Kwak, Rhokyun
    • Journal of the Korean Society of Visualization
    • /
    • v.16 no.1
    • /
    • pp.61-69
    • /
    • 2018
  • Ion exchange membrane can transfer only cation or anion in electrically conductive fluids. Recent studies have revealed that such selective ion transport can initiate electroconvective instability, resulting vortical fluid motions on the membrane. This so-called electroconvective vortex (a.k.a. electroconvection (EC)) has been in the spotlight for enhancing an ion flux in electrochemical systems. However, EC under shear flow has not been investigated yet, although most related systems operate under pressure-driven flows. In this study, we present the direct visualization platform of EC under shear flow. On the transparent silicone rubber, microscale channels were fabricated between ion exchange membranes, while allowing microscopic visualization of fluid flow and ion concentration changes on the membranes. By using this platform, not only we visualize the existence of EC under shear flow, its unique characteristics are also identified: i) unidirectional vortex pattern, ii) its advection along the shear flow, and iii) shear-sheltering of EC vortices.