• Title/Summary/Keyword: ion absorption

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Spectral Characteristics Visible and Near-infrared of Metamorphic Rocks (변성암의 분광특성)

  • 조민조;강필종;이봉주
    • Korean Journal of Remote Sensing
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    • v.8 no.1
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    • pp.1-13
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    • 1992
  • The study is to analize the spectral characteristics of metamorphic rocks by their spectral reflectance curves obtained from CARY 17-D Spectrophotometer. Coarse grained rocks generally show strong absorption at 1.4 and 1.9 $\mu\textrm{m}$ due to preserved water inclusion in quartz of feldspar. The basic rocks show a broad absorption due to Fe$^{++}$ ion rich in mafic minerals. Strong absorption near 2.0$^+\mu\textrm{m}$ suggests existence of carbonate or clay minerals.

MICROSTRUCTURAL STUDY OF $Fe_{1-x}Ti_x$ ALLOYS FORMED BY ION BEAM MIXING

  • Jeon, Y.;Lee, Y.S.;Choi, B.S.;Woo, J.J.;Whang, C.N.
    • Journal of the Korean Vacuum Society
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    • v.6 no.S1
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    • pp.127-132
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    • 1997
  • Microstructure of the Fe-Ti system by ion beam mixing of multilayers at 300 K and 77 K has been studied in a wide composition range. The ion bombardment was carried out using $Ar^+$ ions at 80 keV. Using grazing angle x-ray diffraction we find that the lattice parameters of these bcc solid solutions are very close to that of $\alpha$-Fe. Extended x-ray absorption fine-structure spectroscopy have been performed to investgate the short-range order in the ion-beam-mixed state. The structure parameters, such as the interatomic distance and the coordination number are estmated from the Fe K-edge Fourier filtered EXAFS spectra. The interatomic distance is independent of the alloy concentration and it is almost constant. The study of x-ray absorption near-edge structure gives information on the individual $\rho$components of the partial densityof states of the conduction band of the Fe and Ti We also find that a charge transfer from Ti to Fe atoms takes place.

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The Fluorescent 7-Aminodipyrido[3,2-a:2',3'-c] phenazine(7-amino-dppz) Functionalized as an Europium Ion ($Eu^{3+}$) Sensor

  • Choi, Chang-Shik;Lee, Ki-Hwan
    • Rapid Communication in Photoscience
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    • v.1 no.2
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    • pp.31-33
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    • 2012
  • The Fluorescent 7-aminodipyrido[3,2-a:2',3'-c]phenazine (7-amino-dppz, 1) is functionalized as an europium ion ($Eu^{3+}$) sensor, which showed the effective emission quenching when europium cation is chelated to the bpy site of 1 compound. The complexation ratio indicated that the 1 compound forms a 1 : 1 complex with $Eu^{3+}$.

X-Ray Absorption Spectroscopic Study of 120 MeV $Ag^{9+}$ Ion-Irradiated N-Doped ZnO Thin Films

  • Gautam, Sanjeev;Lim, Weon Cheol;Kang, Hee Kyung;Lee, Ki Soo;Song, Jaebong;Song, Jonghan;Asokan, K.;Chae, Keun Hwa
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.315-315
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    • 2013
  • We report the electronic structure modification in the swift heavy ion (SHI) irradiated N-doped ZnO thin films prepared by RF sputtering from ZnO target in different ratio of Ar/$N_2$ gas mixture using highly pure $N_2$ gas. The different N-ZnO thin lms were then irradiated with 120 MeV Ag ion beam with different doses ranging from $1{\times}10^{11}$ to $5{\times}10^{12}$ ions/$cm^2$ and characterized by XRD and near edge X-ray absorption ne structure (NEXAFS) at N and O K-edges. The NEXAFS measurements provide direct evidence of O 2p and Zn 3d orbital hybridization and also the bonding of N ions with Zn and O ions. The minimum value of resistivity of $790{\Omega}cm$, a Hall mobility of $22cm^2V^-1s^-1$ and the carrier concentration of $3.6{\times}10^{14}cm^{-3}$ were yielded at 75% $N_2$. X-ray diffraction (XRD) measurements revealed that N-doped ZnO films had the preferential orientation of (002) plane for all samples, while crystallinity start decreasing at 32.5% $N_2$. The average crystallite size varies from 5.7 to 8.2 nm for 75% and then decreases to 7.8 nm for 80% $Ar:N_2$ ratio.

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Characterization and Bacteicidal Effect of Na_2O-Al_2O_3-SiO_2$ Glass System by $Na^+$$\longleftrightarrow$$Ag^+$ Ion Exchange ($Na^+$$\longleftrightarrow$$Ag^+$ 이온교환에 따른 Na_2O-Al_2O_3-SiO_2$ 계 유리의 특성 및 살균효과)

  • 이광희;최세영
    • Journal of the Korean Ceramic Society
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    • v.33 no.2
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    • pp.242-250
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    • 1996
  • Glasses of Na2O-Al2O3-SiO2 system were prepared and ion-exchange characteristics change of properties and bactericidal effects by Na+↔Ag+ ion exchange were studied. Parent glasses with three compositions of varying Na2O in the 20~30 wt% were ion-exchanged in the molten salt of 2 mol% AgNO3+98 mol% NaNO3 at 320~36$0^{\circ}C$ for 15~16min. Amount of ion exchange and penetration depth of Ag+ ion increased with Na2O content in the parent glass ion exchange temperature and time. After ion exchange densities and Vickers hardness of the glasses increased and the glasses showed yellow-brown color and as amount of ion exchange increased the color turned deep because partial reduction and agglomeration of Ag+ into Ag0 results in absorption of visible light. After ion exchange chemical durability of the glass to wter was enhanced compara-bly that weight loss and change of surface of the glass were not found for the leaching test in 5$0^{\circ}C$ K.I water for 240hrs. Bactericidal effect of ion exchanged glass on Staphylococcus aureus and E. coli was determined by microorganism test and bactericidal effect increased with amount of ion exchange and incubation time.

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Heavy Metal Absorption Properties of Sulfonated Polyethylene Terephthalate (Sulfonated Polyethylene Terephthalate의 중금속 흡착능)

  • Kang, Young-Goo;Kim, Dong-Hyun
    • Journal of the Korean Society of Safety
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    • v.18 no.4
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    • pp.92-97
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    • 2003
  • The purpose of this study is heavy metal absorption of recycled PET(poly ethylene terephatalate) NWF(non woven faric). The results of test are summarized as follows; Heavy metal abworption rates in Ni ions were higher then Zn and Cu ions, whereas heavy metal absorption rates by sulfonation times were not different. The heavy metal absorption times have a higher tendency from 60 min to 120 min. There were significant negative correlations among the amount used CSA(Chloro Sulfuric Acid) and the amount of absorption Zn(r = -0.33784, p < 0.05), Cu(r = -0.61177, p < 0.01) ions, whereas correlations between heavy metal absorption rates and sulfonation times were not significant. There were significant positive correlations among the amount of absorption Zn ions and the amount of absorption Ni(r = 96475, p < 0.014), Cu(r = 0.51614, p < 0.01) ions, likewise the positive correlations between the amount of absorption N ions and the amount of absorption Cu(r = 0.54766) ions were significant(p < 0.01).

Characteristics of Inorganic Ion Absorption of Strawberries Cultivated in Closed Hydroponic System with Different Substrates (고형배지를 이용한 순환식 딸기 수경재배에서 배지 종류별 무기이온 흡수 특성)

  • Jun, Ha-Joon;Hwang, Jin-Gyu;Liu, Shisheng;Jang, Mi-Soon
    • Journal of Bio-Environment Control
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    • v.20 no.1
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    • pp.33-39
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    • 2011
  • This experiment was carried out to understand the characteristics of inorganic ion uptake of strawberries to establish a labor saving, environmentally sound closed hydroponic system. Nitrate nitrogen is absorbed in the perlite and granule rockwood with the almost same rate and in the cocopeat with a little bit higher concentration. At the early growth stage, phosphate was absorbed in comparatively high rate, but it is gradually declining to $4me{\cdot}L^{-1}$ in the three treatments except for reused medium. Four treatments showed different absorption rates for potassium, respectively, however, it became $3{\sim}5me{\cdot}L^{-1}$ gradually. But there was few sign to absorb potassium in the reused medium. High concentration of calcium was absorbed in the cocopeat medium and the lowest absorption rate in the granule rockwool, and it turned out to be $2{\sim}3me{\cdot}L^{-1}$ absorption concentration rate in the perlite. All three treatments showed $1me{\cdot}L^{-1}$ at the average absorption concentration rate of magnesium. Iron showed high absorption rate but it showed steadily 1~2 ppm absorption rate. Results of this experiment will be utilized for developing the new substrates for strawberry closed hydroponic system.

-The Optical- and Ion-Induced Characteristics of a-$Se_{75}Ge_{25}$ Thin Film for Focused Ion Beam (FIB)- (집속이온빔 (FIB) 레지스트를 위한 비정질 $Se_{75}Ge_{25}$ 박막의 이온 및 광유기특성)

  • Lee, Hyun-Yong;Park, Tae-Sung;Kim, Jong-Bin;Lee, Young-Jong;Chung, Hong-Bay;Cho, Guang-Sup;Kang, Seung-Oun;Hwang, Ho-Jung;Park, Sun-Woo
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.843-846
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    • 1992
  • This thesis was investigated on optical-and ion-induced characteristics in positive(a-$Se_{75}Ge_{25}$) and negative (Ag/a-$Se_{75}Ge_{25}$) resists for focused-ion-beam microlithogaphy. The a-$Se_{75}Ge_{25}$ inorganic thin film shows an increase in optical absorption after exposure to$\sim$$10^{16}$ dose(ions/$cm^{2}$) of Ga ions. The observed shift in the absorption edge toward longer wavelengths is consistent with that in films exposed to band-gap photons ($\sim$$10^{20}$ photons/$cm^{2}$). But, ion induced shift is twice as much as that in film exposed to optical radiation. This result may be related with microstructural rearrangements with in the short range of SeGe network. Due to changes in the short range order, the chemical bonding may be affected, which results in increased chemical dissolution in ion-induced film. Also, this resist exhibits good thermal stability because of its high Tg(~220$^{\circ}C$). The composition of deposited film measured by AES is consistent with that of bulk.

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Determination of Metoclopramide by Flameless Atomic Absorption and Spectrophotometry (무염 원자흡광도법과 흡광광도법에 의한 제제중의 Metoclopramide의 정량)

  • 박만기;임병연;유경수;용군호
    • YAKHAK HOEJI
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    • v.22 no.1
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    • pp.27-32
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    • 1978
  • Metoclopramide reacts with ammonium cobaltothiocyanate to form a stable ion pair which has an absorption maximum of 625mm. The reaction product was insoluble in water but soluble in most organic solvents. 1,2-Dichlorethane was the best extracting solvent among the several organic solvents tested. Metoclopramide can be determinded not only by visible light spectrophotometry but also indirectly by estimation of cobalt in the organic phase by flameless atomic absorption spectrophotometry. Linear relationship was found between absorbance and concentration in the range of 10$^{-4/}$-10$^{-3}$M by spectrophotometry and 10$^{-5}$-10$^{-4}$M by flameless atomic absorption spectrophotometry. The coefficient of variation by spectrophotometry was 0.9% and that of flameless atomic absorption was 1.8%. There was no interference with excipients, pH, temperature and reaction time. With this method, it is possible to determine accurately metoclopramide and tertiary amines in pharmaceutical preparations.

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Spectroscopic Properties and Ligand Field Analysis of trans -Dibromo(2,2-dimethyl-1,3-diaminopropane)chromium(III) Moiety

  • Choi, Jong-Ha;Oh, In-Gyung;Lim, Woo-Taik;Ryoo, Keon-Sang;Kim, Dong-Il;Park, Yu-Chul
    • Bulletin of the Korean Chemical Society
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    • v.26 no.6
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    • pp.903-908
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    • 2005
  • The sharp-line absorption and emission spectra of $(H_{13}O_6)${$trans-[Cr(Me_2tn)_2Br_2]$}$_2Br_2(ClO_4)\;(Me_2$tn = 2,2-dimethyl-1,3-diaminopropane) have been measured between 13000 $cm^{-1}$ and 16000 $cm^{-1}$ at 5 K. The 298 K infrared and visible absorption spectra have also been measured. The nine electronic bands due to spin-allowed and spin-forbidden transitions were assigned. Using observed transitions, a ligand field analysis has been performed to probe the ligand field properties of coordinated atoms in the title chromium(III) complex ion. The zero-phonon line in the sharp-line absorption spectrum splits into two components by 286 $cm^{-1}$, and the large $^2E_g$ splitting can be reproduced by the modern ligand field theory. It is confirmed that nitrogen atoms of the Me2tn ligand have a strong $\sigma$-donor character, but the bromide has weak $\sigma$- and $\pi$-donor properties toward chromium(III) ion.