• Proceedings of the KIEE Conference
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• 1992.07b
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• pp.1005-1008
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• 1992

This paper deals with a method to Improve the input current waveform in a single phase Rectifier. This method is based on the sophisiticated utilization of the auxiliary circuit consisting of two SCRs and a interphase reacter and the condenser necessary for reducing the fluctuating voltage in output side. The basic theories of the proposed system is treated, and its validity is verified with simulation.

• Proceedings of the KIPE Conference
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• 1998.07a
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• pp.405-408
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• 1998

In this paper, a predictive current control of 12-pulse parallel connected dual converter system with interphase transfromer(IPT) is presented. Firstly, 12-pulse parallel connected dual converter system and the predictive current control of this system is discussed. And the validity of the presented system and the excellence of the predictive current control response is proved through the simyulation and experiment result.

• Journal of the Korean Electrochemical Society
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• v.17 no.2
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• pp.79-85
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• 2014

Silicon (Si) has been investigated as promising negative-electrode (anode) materials because its theoretical specific capacity of 4200 mAh/g for $Li_{4.4}Si$ is far higher than that of carbonaceous anodes in current commercial products. However, in practice, the application of Si to Li-ion batteries is still quite challenging because Si suffers from severe volume expansion and contraction and lead to a continuous solid electrolyte interphase (SEI)-filming process by cracking of Si. This process consumes the limited $Li^+$ source, builds up thick and unstable SEI layer on the Si active materials, and will eventually disable the cell. Since unstable SEI reduces electrochemical performance and thermal stability of the Si anode, the surface chemistry of the anode should be modified by using a functional additive. It is found that lithium bis(oxalato)borate (LiBOB) as an additive effectively protected the Si anode surface, improved capacity retention when stored at $60^{\circ}C$, and alleviated exothermic thermal reactions of fully lithiated Si anode.

• Proceedings of the KIEE Conference
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• 2005.11b
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• pp.83-86
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• 2005

최근 가공 송전선로 건설에 대한 인근 지역주민들의 반대에 부딪쳐, 불가피하게 가옥이 밀집된 주거지역을 우회하거나 토지 활용도가 낮은 산악지를 이용하여 선로를 건설하는 경우가 대부분이다. 이와 같이 경과지의 제한성으로 인해 때때로 국지적인 기상현상 발생 우려가 있는 지역에 불가피하게 송전선로를 건설하는 경우가 있으며, 이상기상 현상이 발생하는 11월말에서 3월초 사이에 경기북부 지역의 국지성 돌풍에 의해 갤로핑(Galloping)현상이 종종 발생되었다 갤로핑은 바람으로 인해 전력선이 횡진과 출렁임이 발생되는 현상을 말한다. 송전선로의 지지물에는 주로 철탑이 사용되고, 전력선은 ACSR 410mm 복도체가 주로 사용된다. 송전선로는 경제성과 계통의 안전성을 고려하여 수직배열로 2회선용 표준철탑을 사용한다. 갤로핑 현상은 바람에 의해 전력설에 심한 진동을 일으켜, 수직 배열된 전력선 상간 단락 또는 전력선과 가공지선간의 지락으로 고장전류가 생기고, 고장전류에 의한 보호계전기 동작으로 선로가 트립(Trip)되며, 이로 인한 전력공급 중단이 발생된다. 또한 전력선의 기계적인 진동에 의하여 전력선의 단선 또는 지지물의 파손으로 영구고장을 일으킬 수도 있다. 본 논문에서는 경기북부지역의 산악지에 설치된 154kV 송전선로에서 산비탈면을 타고 오르는 상승 바람에 의한 갤로핑 사례를 국내 최초로 현장에서 촬영한 동영상 자료를 토대로 소개하고, 갤로핑 발생시 송전선로에 미친 영향 등 검토 결과를 설명하였다. 전력선에 생긴 아크 흔적을 토대로 전력선간의 단락이 발생했던 지점을 실제로 관측할 수 있었다. 최근 갤로핑으로 인한 상간 단락 고상 방지론 목적으로 개발된 폴리머 상간스페이서(Interphase spacer)의 시공 사례를 소개하고, 현재까지 상간스페이서가 설치된 송전선로의 점검 결과를 소개하고자 한다.

• Composites Research
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• v.30 no.4
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• pp.247-253
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• 2017

In this study, the mechanical behavior and interface properties of boron nitride nanotube-poly(methyl methacrylate) nanocomposites are predicted using the molecular dynamics simulations and the double inclusion model. After modeling nanocomposite unit cell embedding single-walled nanotube and polymer, the stiffness matrix is determined from uniaxial tension and shear tests. Through the orientation average of the transversely isotropic stiffness matrix, the effective isotropic elastic constants of randomly dispersed microstructure of nanocomposites. Compared with the double inclusion model solution with a perfect interfacial condition, it is found that the interface between boron nitride nanotube and polymer matrix is weak in nature. To characterize the interphase surrounding the nanotube, the two step domain decomposition method incorporating a linear spring model at the interface is adopted. As a result, various combinations of the interfacial compliance and the interphase elastic constants are successfully determined from an inverse analysis.

• Journal of the Korean Chemical Society
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• v.33 no.6
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• pp.651-656
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• 1989

The catalytic effects of several phase-transfer catalysts (PTC) on the liquid-liquid heterogeneous nucleophilic displacement reaction of thiocyanate on benzyl chloride have been determined. Reactions followed a pseudo-first order dependency on the benzyl chloride concentration and the observed rate constant $(k_{obsd})$ were linearly related to the concentration of catalyst and varied with variables such as reaction temperature and solvent. The sequences of catalytic activity of the displacement were $NH_4Cl$ < BTMAC < 18-crown-6 < BTEAC < PEG < TBAC < CTMAB. Enthalpies and entropies of activation associated with the displacement were 15∼20 Kcal$mo^{l-1}$, -12∼-29 eu. respectively and the reaction occurs in the interphase comprising of microemulsion.

• Applied Chemistry for Engineering
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• v.16 no.4
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• pp.507-512
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• 2005

When carbon electrode is used as an anode in Li ion battery, passivation film forms on the electrode surface during the initial charge process due to so called Solid-Electrolyte Interphase (SEI). The passivation film formed by solvent decomposition during the initial charge process affects charge/discharge capacity. In this paper, 1 M $LiPF_6,EC:DEC$ (1 : 1, volume ratio) electrolyte with $Li_2CO_3$, at various temperatures, the electrochemical characteristics of passivation film formed on Kawasaki Mesophase Fine Carbon electrode surface were investigated by using chronopotentiometry, cyclic voltammetry, and impedance spectroscopy. Experimental observations indicated that as solvent decomposition occurred, the decomposition voltage was strongly dependent on ionic conductivity, which was low in the process at low temperature. The impedance of passivation film formed during the initial charge process, were dependent on the temperature.

• Nuclear Engineering and Technology
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• v.18 no.1
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• pp.9-16
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• 1986

Simulation of the system thermal-hydraulic parameters was carried out following the KNUl (Korea Nuclear Unit-1) loss of normal feedwater transient sequence occurred on November 14, 1984. Results were compared with the plant transient data, and good agreements were obtained. Some deviations were found in the parameters such as the steam flowrate and the RCS (Reactor Coolant System) average temperature, around the time of reactor trip. It can be expected since the thermal-hydraulic parameters encounter rapid transitions due to the large reduction of the reactor thermal power in a short period of time and, thereby, the plant data involve transient uncertainties. The analysis was performed using the RELAP5/MOD1/NSC developed through some modifications of the interphase drag and the wall heat transfer modeling routines of the RELAP5/MOD1/CY018.

• The Korean Journal of Zoology
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• v.33 no.1
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• pp.45-52
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• 1990

In order to determine whether maturation inhibiting activity(MIA) in the cytoplasm of growing follicular oocytes would suppress the cleavage of the embryonal cells, the growing oocytes were fused with the 2 or 4 cell blastomeres and then examined for the nuclear phase of the fused giant cells 24 hr after culture. A significant number of the giant cells(60%) composed of growing mouse oocyte and 2 cell mouse blastomere(1/2) in interphase has contained 2 nuclei 24 hr after culture and most of the giant cells (90%) composed of the growing oocyte and 4 cell blastomere(1/4) also contained 2 nuclei after culture. The unfused blastomeres or the isolated blastomeres cultured without fusion treatment cleaved one cell cycle under the same culture condition. In contrast, the nucleus of the growing oocytes was disintegrated and the chromosome condensed when fused with 2 cell blastomere in mitosis. The growing rat oocytes also suppressed the nuclear disintegration of the mouse embryonal cells during culture. The data presented here showed that MIA in the growing mammalian oocyte inhibited the cleavage of the embryonal cells in interphase stage, but not in milosis stage.

• Bulletin of the Korean Chemical Society
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• v.30 no.4
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• pp.783-786
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• 2009

Thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and ion chromatography(IC) were employed to analyze the thermal behavior of $Li_xCoO_2$ cathode material of lithium ion battery. The mass loss peaks appearing between 60 and 125 ${^{\circ}C}$ in TGA and the exothermic peaks with 4.9 and 7.0 J/g in DSC around 75 and 85 ${^{\circ}C}$ for the $Li_xCoO_2$ cathodes of 4.20 and 4.35 V cells are explained based on disruption of solid electrolyte interphase (SEI) film. Low temperature induced HF formation through weak interaction between organic electrolyte and LiF is supposed to cause carbonate film disruption reaction, $Li_2CO_3\;+\;2HF{\rightarrow}\;2LiF\;+\;CO_2\;+\;H_2O$. The different spectral DSC/TGA pattern for the cathode of 4.5 V cell has also been explained. Presence of ionic carbonate in the cathode has been identified by ion chromatography and LiF reported by early researchers has been used for explaining the film SEI disruption process. The absence of mass loss peak for the cathode washed with dimethyl carbonate (DMC) implies ionic nature of the film. The thermal behavior above 150 ${^{\circ}C}$ has also been analyzed and presented.