• Bulletin of the Korean Chemical Society
• /
• 제8권5호
• /
• pp.376-380
• /
• 1987

The cyclobutane forming photocycloaddition reaction of 5(E)-styryl-1,3-dimethyluracil with some olefins occurs on the 5,6-double bond of uracil ring rather than the expected central double bond via an intermediate, probably the photochemical Diels-Alder type adduct. This intermediate formed on short term irradiation of 5(E)-styryl-1,3-dimethyluracil and 2,3-dimethyl-2-butene solution is converted into the $C_4$-cycloadduct on the prolonged irradiation. Quantum yield of the intermediate formation is not linear with the concentration of 2,3-dimethyl-2-butene probably due to the secondary reaction accompanied with the complex reaction kinetics. The intermediate is formed from the lowest excited singlet state.

• Bulletin of the Korean Chemical Society
• /
• 제8권1호
• /
• pp.27-30
• /
• 1987

Photocycloaddition of 1,4,5,8-tetraazaphenanthrene to olefins proceeds through a biradical triplet-state intermediate as proven by the photoproduct stereochemistry, quantum yield measurements, sensitization, quenching, and fluorescence and phosphorescence quenching studies.

• Geomechanics and Engineering
• /
• 제7권3호
• /
• pp.317-333
• /
• 2014

The study of the mechanical behavior of rockfill materials under three-dimensional loading conditions is a current research focus area. This paper presents a microscale numerical study of rockfill deformation and strength characteristics using the Combined Finite-Discrete Element Method (FDEM). Two features unique to this study are the consideration of irregular particle shapes and particle crushability. A polydisperse assembly of irregular polyhedra was prepared to reproduce the mechanical behavior of rockfill materials subjected to axial compression at a constant mean stress for a range of intermediate principal stress ratios in the interval [0, 1]. The simulation results, including the stress-strain characteristics, relationship between principal strains, and principal deviator strains are discussed. The stress-dilatancy behavior is described using a linear dilatancy equation with its material constants varying with the intermediate principal stress ratio. The failure surface in the principal stress space and its traces in the deviatoric and meridian plane are also presented. The modified Lade-Duncan criterion most closely describes the stress points at failure.

• Bulletin of the Korean Chemical Society
• /
• 제17권12호
• /
• pp.1127-1131
• /
• 1996

[FeⅡ2(N-Et-HPTB)Cl2]BPh4(1), where N-Et-HPTB is the anion of N,N,N',N'-tetrakis(N-ethyl-2-benzimidazolylmethyl)-2-hydroxy-l,3-diaminopropane, has been synthesized to model dioxygen binding to the diferrous centers of proteins. 1 has a singly bridged structure with a μ-alkoxo of N-Et-HPTB and contains two five-coordinate iron(Ⅱ) centers with two chloride ligands as exogenous ligands. 1 exhibits an electronic spectrum with a λmax at 336 nm in acetone. 1 in acetone exhibits no EPR signal at 4 K, indicating diiron(Ⅱ) centers are antiferromagnetically coupled. Exposure of acetone solution of 1 to O2 at -90 ℃ affords an intense blue color intermediate showing a broad band at 586 nm. This absorption maximum of the dioxygen adduct(1/O2) was found in the same region of μ-l,2-peroxo diiron(Ⅲ) intermediates in the related complexes with pendant pyridine or benzimidazole ligand systems. However, this blue intermediate exhibits EPR signals at g = 1.93, 1.76, and 1.59 at 4 K. These g values are characteristic of S = 1/2 system derived from an antiferromagnetically coupled high-spin Fe(Ⅱ)Fe(Ⅲ) units. 1 is the unique example of a (μ-alkoxo)diferrous complex which can bind dioxygen and form a metastable mixed-valence intermediate. At ambient temperature, most of 1/O2 intermediate decays to form a diamagnetic species. It suggests that the dacay reaction of the intermediate might be bimolecular, implying the formation of mixed-valence tetranuclear species in transition state.

• ETRI Journal
• /
• 제35권1호
• /
• pp.173-176
• /
• 2013

Existing symmetric cryptography-based solutions against pollution attacks for network coding systems suffer various drawbacks, such as highly complicated key distribution and vulnerable security against collusion. This letter presents a novel homomorphic subspace message authentication code (MAC) scheme that can thwart pollution attacks in an efficient way. The basic idea is to exploit the combination of the symmetric cryptography and linear subspace properties of network coding. The proposed scheme can tolerate the compromise of up to r-1 intermediate nodes when r source keys are used. Compared to previous MAC solutions, less secret keys are needed for the source and only one secret key is distributed to each intermediate node.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
• /
• pp.390-391
• /
• 2006

A high Tc superconducting with a nominal composition of $Bi_2Sr_2Ca_2Cu_3O_y$ was prepared by the citarte method. The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at $400^{\circ}C$ and calcination at $840^{\circ}C$ for 4h, the (001)peak of the high Tc phase was cleary observed. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important factor in determining whether it is easy to form the high Tc phase or not, because the nucleation bafflers of the two superconducting phase may be altered by the variation of the crystal structures of those Intermediate phase.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 한국소성가공학회 2004년도 제5회 압연심포지엄 신 시장 개척을 위한 압연기술
• /
• pp.368-377
• /
• 2004

A mathematical model was developed for the prediction of the average temperature and RDT(RM Delivery temperature) in a roughing mill. The model consisted of three parts as follows (1) The intermediate numerical model calculated the deformation and heat transfer phenomena in the rolling: region by steady state FEM and the heat transfer phenomena in the interpass region by unsteady state FEM (2) The Off-line prediction model was derived from non-linear regression analysis based on the results of intermediate numerical model considering the various rolling conditions, (3) Using the heat flux in rolling region, temperature profile along thickness direction was calculated. For validation of the presented model, the rolling force per pass and RDT measued in on-line process was compared with those of model and the results showed close agreement with the existing data. In order to demonstrate the effectiveness of the proposed model, the various rolling conditions was tested.

• Proceedings of the KIEE Conference
• /
• 대한전기학회 2005년도 추계학술대회 논문집 전기물성,응용부문
• /
• pp.77-78
• /
• 2005

A high Tc superconducting with a nominal composition of $Bi_{2}Sr_{2}Ca_{2}Cu_{3}O_{Y}$ was prepared by the citarte method. The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at $400^{\circ}C$ and calcination at $840^{\circ}C$ for 4h, the (001)peak of the high Tc phase was cleary observed. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important factro in determining whether it is easy to form the high Tc phase or not, because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.

• Proceedings of the KIEE Conference
• /
• 대한전기학회 2005년도 추계학술대회 논문집 전기물성,응용부문
• /
• pp.79-80
• /
• 2005

The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important fact in determining whether it is easy to form the superconducting phase or not, because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.

• Proceedings of the KIEE Conference
• /
• 대한전기학회 2006년도 제37회 하계학술대회 논문집 C
• /
• pp.1335-1336
• /
• 2006

A high Tc superconducting with a nominal composition of YBCO wasprpared by the citarte method. The solid precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12h is not in the amorphous state as expected but in a crystalline state. X-ray diffraction peaks of nearly the same angular position as the peaks of high Tc phase were observed in the precursor. After pyrolysis at $400^{\circ}C$ and calcination at $840^{\circ}C$ for 4h, the (001)peak of the high Tc phase was cleary observed. Experimental results suggest that the intermediate phase formed before the formation of the superconducting phase may be the most important factro in determining whether it is easy to form the high Tc phase or not, because the nucleation barriers of the two superconducting phase may be altered by the variation of the crystal structures of those intermediate phase.