• Title/Summary/Keyword: interface treatment

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Effect of and R Phase on the Pitting Corrosion in Super Duplex Stainless Steel (슈퍼 2상 스테인리스강의 공식에 미치는 R상의 영향)

  • Lee, Byung-Chan;Oh, Eun-Ji;Kang, Chang-Yong
    • Korean Journal of Materials Research
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    • v.24 no.11
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    • pp.610-616
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    • 2014
  • In this study, we investigated the precipitation behavior of the R-phase precipitated at the initial stage of aging and its effect on the pitting corrosion of 25%Cr-7%Ni-4%Mo super duplex stainless steel. The R-phase in super duplex stainless steel was mainly precipitated at the interface of ferrite/austenite phases and inside of the ferrite phase during the initial stage of aging, and it was transformed into the ${\sigma}$-phase with an increase in aging time. The ferrite phase was decomposed into a new austenite phase and ${\sigma}$-phase. The R phase was an intermetallic compound, which represented a lower Ni and higher Mo than the matrix, and also had a higher Mo and Cr concentration than the ${\sigma}$ phase. With an increasing aging time, the pitting potential $E_p$ was increased slowly by the precipitation of the R-phase, and it was then steeply decreased by the precipitation of the ${\sigma}$-phase. The R-phase was decreased the pitting potential, but its effect was smaller than effect of ${\sigma}$-phase.

The Air/water Interface Characteristics of Maleate Copolymer LB Films (말레에이트계 공중합체 I-l3막의 공기/물에서의 계면 특성)

  • 신훈규;권영수;이범종;장정수;배진호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.220-223
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    • 1995
  • Stable polyion-complexed polymeric monolayrers were prepared by spreading perfluoroalkyl monomaleatd copolymers. C$_2$F$\_$8/MA-VE$_2$ and C$_2$F$\_$8/Mv-VE$_3$ on aqueous poly(allylamine) subphase. The monolayer properties have been studied by the surface pressure-area($\pi$-A) isotherms. The C$_2$F$\_$8/MA-VE$_3$containing longer oligoethyleneglycol pendant showed more expaned monolayer phase than the C$_2$F$\_$8/MA-VE$_2$ The polyion-complexed monolayers were transferable on various substrates, and the resulting Langmuir-Blodgett(LB) films were characterized b ET-IR spectroscopy and scanning electron microscopy(SEM) Two-dimensional crosslinking to from a polymer network was achieved by amide formation through heat treatment under vacuum with concurrent removel of perfluoroalkyl tails. SEM observation of this film ona porous membrane filter showed that the four layer film was sufficiently stable to cover the filter pore size of 0.1$\mu\textrm{m}$. The C$_2$F$\_$8/MA-VE$_3$revealed better covering capability than the C$_2$F$\_$8/MA-VE$_2$Immersion of this film in water or in benzend did not cause any change in its appearance and in FT-IR spectra.

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Increase of Grb2 and Ras Proteins and Expression of Growth Factors in LPS Stimulated Odontoblast-like Dental Pulp Cells

  • Jeong, Soon-Jeong;Jeong, Moon-Jin
    • Applied Microscopy
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    • v.43 no.1
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    • pp.27-33
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    • 2013
  • Inflammatory cells express the inflammatory cytokines and growth factors induced by lipopolysaccharide (LPS). Odontoblasts are located at the pulp-dentin interface and extend their cell processes far into the dentin where they are the first cells to encounter microorganisms or their products. Therefore, this study examined the expression of some growth factors related to the signal pathway, such as growth factor receptor binding protein 2 (Grb2)-Ras in odontoblast-like dental pulp cells, after a treatment with LPS. After 60 minutes, the mRNA and protein expression levels of Grb2 and Ras were higher in the LPS-treated cells than in the control cells. The level of vascular endothelial growth factor (VEGF) and basic fibroblast growth factor (bFGF) mRNA expression was increased significantly to a level similar to that of Grb2 and Ras at 60 minutes. The platelet-derived growth factor-AA (PDGF-AA) mRNA level was expressed strongly in the odontoblast like dental pulp cells without an association with LPS stimulation. Scanning electron microscopy revealed many extensions of the cytoplasmic processes and the number of processes increased gradually at 30, 60 and 90 minutes after LPS stimulation. From these results VEGF and bFGF expression might be induced through the Grb2-Ras signal transduction pathway in LPS treated odontoblasts.

Preparation and Interface Properties of Colloidal Silica (콜로이드 실리카의 제조 및 계면특성)

  • Lee, Han Chul;Kim, Jong Hyub;Chang, Yoon Ho
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.386-390
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    • 2006
  • Colloidal silica which has high surface area and excellent surface properties are chemically stable inorganic materials and used for various applications in industry. Silica sol was prepared from sodium silicate solution by acid neutralization method and ion exchange treatment to remove sodium ions. Through the experimental analysis for controlling factors of particle growth rate, such as temperature, pH, and aging time, the uniform size distribution of silica sol could be obtained. The size distribution and shape of silica sol was measured by TEM and dynamic light scattering method. Zeta potential change and gelling phenomena of silica sol and its rheological properties also investigated.

Mechanical Properties of Electro-Discharge-Sintered Porous Titanium Implants (전기방전소결에 의해 제조된 다공성 Titanium 임플란트의 기계적 특성)

  • Hyun, C.Y.;Huh, J.K.;Lee, W.H.
    • Korean Journal of Materials Research
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    • v.16 no.3
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    • pp.173-177
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    • 2006
  • Porous surfaced Ti implant compacts were fabricated by electro-discharging-sintering (EDS) of atomized spherical Ti powders. Powders of $50-100{\mu}m$ in diameter were vibratarily settled into a quarts tube and subject to a high voltage and high density current pulse in Ar atmosphere. Single pulse of 0.7 to 2.0 kJ/0.7 gpowder, from 150, 300, and $450{\mu}F$ capacitors was applied in less than $400{\mu}sec$ to produce twelve different porous-surfaced Ti implant compacts. The solid core formed in the center of the compact shows similar microstructure of cp Ti which was annealed and quenched in water. Hardness value at the solid core was much higher than that at the particle interface and particles in the porous layer, which can be attributed to both heat treatment and work hardening effects induced by EDS. Compression tests were made to evaluate the mechanical properties of the EDS compacts. The compressive yield strength was in a range of 12 to 304MPa which significantly depends on input energy. Selected porous-surfaced Ti-6Al-4V dental implant compacts with a solid core have much higher compressive strengths compared to the human teeth and sintered Ti dental implants fabricated by conventional sintering process.

Dynamic simulation of squeezing flow of ER fluids using parallel processing

  • Kim, Do-Hoon;Chu, Sang-Hyon;Ahn, Kyung-Hyun;Lee, Seung-Jong
    • Korea-Australia Rheology Journal
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    • v.11 no.3
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    • pp.233-240
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    • 1999
  • In order to understand the flow behavior of Electrorheological (ER) fluid, dynamic simulation has been intensively performed for the last decade. When the shear flow is applied, it is easy to carry out the simulation with relatively small number of particles because of the periodic boundary condition. For the squeezing flow, however, it is not easy to apply the periodic boundary condition, and the number of particles needs to be increased to simulate the ER system more realistically. For this reason, the simulation of ER fluid under squeezing flow has been mostly performed with some representative chains or with the approximation that severely restricts the flow geometry to reduce the computational load. In this study, Message Passing Interface (MPI), which is one of the most widely-used parallel processing techniques, has been employed in a dynamic simulation of ER fluid under squeezing flow. As the number of particles used in the simulation could be increased significantly, full domain between the electrodes has been covered. The numerical treatment or the approximation used to reduce the computational load has been evaluated for its validity, and was found to be quite effective. As the number of particles is increased, the fluctuation of the normal stress becomes diminished and the prediction in general was found to be qualitatively In good agreement with the experimental results.

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Stepwise Ni-silicide Process for Parasitic Resistance Reduction for Silicon/metal Contact Junction

  • Choi, Hoon;Cho, Il-Whan;Hong, Sang-Jeen
    • Transactions on Electrical and Electronic Materials
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    • v.9 no.4
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    • pp.137-142
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    • 2008
  • The parasitic resistance is studied to silicon/metal contact junction for improving device performance and to lower contact/serial resistance silicide in natural sequence. In this paper constructs the stepwise Ni silicide process for parasitic resistance reduction for silicon/metal contact junction. We have investigated multi-step Ni silicide on SiGe substrate with stepwise annealing method as an alternative to compose more thermally reliable Ni silicide layer. Stepwise annealing for silicide formation is exposed to heating environment with $5^{\circ}C/sec$ for 10 seconds and a dwelling for both 10 and 30 seconds, and ramping-up and the dwelling was repeated until the final annealing temperature of $700\;^{\circ}C$ is achieved. Finally a direct comparison for single step and stepwise annealing process is obtained for 20 nm nickel silicide through stepwise annealing is $5.64\;{\Omega}/square$ at $600\;^{\circ}C$, and it is 42 % lower than that of as nickel sputtered. The proposed stepwise annealing for Ni silicidation can provide the least amount of NiSi at the interface of nickel silicide and silicon, and it provides lower resistance, higher thermal-stability, and superior morphology than other thermal treatment.

Effect of Annealing Atmosphere on the La2O3 Nanocrystallite Based Charge Trap Memory

  • Tang, Zhenjie;Zhao, Dongqiu;Hu, Huiping;Li, Rong;Yin, Jiang
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.2
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    • pp.73-76
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    • 2014
  • $Pt/Al_2O_3/La_2Si_5O_x/SiO_2/Si$ charge trap memory capacitors were prepared, in which the $La_2Si_5O_x$ film was used as the charge trapping layer, and the effects of post annealing atmospheres ($NH_3$ and $N_2$) on their memory characteristics were investigated. $La_2O_3$ nanocrystallites, as the storage nodes, precipitated from the amorphous $La_2Si_5O_x$ film during rapid thermal annealing. The $NH_3$ annealed memory capacitor showed higher charge storage performances than either the capacitor without annealing or the capacitor annealed in $N_2$. The memory characteristics were enhanced because more nitrogen was incorporated at the $La_2Si_5O_x/SiO_2$ interface and interfacial reaction was suppressed after the $NH_3$ annealing treatment.

Development of the replaced Eco-friendly SIS with GIS for 25.8kV class (25.8kV $SF_6$가스절연 스위치기어(GIS)를 대체한 친환경 고체절연 스위치기어(SIS) 개발)

  • Ma, Ji-Hoon;Zheng, Meng-Lei;Yoo, Lyun;Won, Sung-Yoen;Lee, Seog-Won;Kim, Young-Keun
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1219_1220
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    • 2009
  • In recent years, the companies of electric power equipment for MV, HV class trend to develop that the eco-friendly insulated(solid, eco-gas, air etc.) switchgear replace with existent SF6 gas insulated switchgear by environmental problems such as global warming and soon. This paper introduces the Solid Insulated Switchgear(SIS) which is the epoxy of eco-friendly insulation material. The characteristic of SIS to introduce in this paper is as following. 1) Eco-friendly. (SF6 gas free) 2) The structure of flexible system. (Expansion) 3) The optimum design. (The Analysis of electrical & mechanical) 4) An Interface treatment between epoxy and insert. (Molding technology) This paper described about some technology for development of SIS.

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Development of Distributed Generic Simulator (GenSim) through Invention of Simulated Network (simNetwork)

  • Koo, Cheol-Hea;Lee, Hoon-Hee;Cheon, Yee-Jin
    • Journal of Astronomy and Space Sciences
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    • v.28 no.3
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    • pp.241-252
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    • 2011
  • A simulated network protocol provides the capability of distributed simulation to a generic simulator. Through this, full coverage of management of data and service handling among separated simulators is achieved. The distributed simulation environment is much more conducive to handling simulation load balancing and hazard treatment than a standalone computer. According to the simulated network protocol, one simulator takes on the role of server and the other simulators take on the role of client, and client is controlled by server. The purpose of the simulated network protocol is to seamlessly connect multiple simulator instances into a single simulation environment. This paper presents the development of a simulated network (simNetwork) that provides the capability of distributed simulation to a generic simulator (GenSim), which is a software simulator of satellites that has been developed by the Korea Aerospace Research Institute since 2010, to use as a flight software validation bench for future satellite development.