• 제목/요약/키워드: interaction energy.

검색결과 1,946건 처리시간 0.029초

YAlO3:Tbx3+에서 발광소멸 곡선을 이용한 에너지 전달에 관한 연구 (A Study on the Energy Transfer of YAlO3:Tbx3+ using Decay Curves)

  • 김광철;최진수
    • 반도체디스플레이기술학회지
    • /
    • 제14권1호
    • /
    • pp.13-17
    • /
    • 2015
  • $YAlO_3:Tb{_x}^{3+}$ has been synthesized by a combustion process and the concentration x of Tb was varied from 0.001 and 0.05 mol% per mole of YAlO3. The energy transfer of $^5D_3{\rightarrow}^7F_6$(385nm) and $^5D_4{\rightarrow}^7F_5$(544nm) transitions on the $YAlO_3:Tb{_x}^{3+}$(x =0.001, 0.05) have been investigated by using decay curves. The energy transfer mechanism was explained by Inokuti and Hirayama model. The results of calculation and fitting showed that values of n are 6.11(x=0.01) and 6.13(x=0.005). These indicate that the energy transfer mechanism between $Tb^{3+}$ ions is dipole-dipole interaction.

INVESTIGATION ON MATERIAL DEGRADATION OF ALLOY 617 IN HIGH TEMPERATURE IMPURE HELIUM COOLANT

  • Kim, Dong-Jin;Lee, Gyeong-Geun;Jeong, Su-Jin;Kim, Woo-Gon;Park, Ji-Yeon
    • Nuclear Engineering and Technology
    • /
    • 제43권5호
    • /
    • pp.429-436
    • /
    • 2011
  • The corrosion of materials exposed to high temperature helium in a very high temperature reactor is caused by interaction with the impurities in the helium. This interaction then induces high temperature mechanical deterioration. By considering the effect of the impurity concentration on material corrosion, a long-term coolant chemistry guideline can be determined for the range of impurity concentration at which the material is stable for a long time. In this work, surface reactions were investigated by analyzing the thermodynamics and the experimental results for Alloy 617 exposed to controlled impure helium at $950^{\circ}C$. Moreover, the surfaces were examined for the Alloy 617 crept in air and in uncontrolled helium, which was explained by possible surface reactions.

Effects of Molecular Attraction and Orientations in the Vibration-Vibration Energy Exchange

  • Ree, Jong-Baik;Chung, Keun-Ho
    • Bulletin of the Korean Chemical Society
    • /
    • 제7권2호
    • /
    • pp.124-129
    • /
    • 1986
  • The effects of molecular attraction and orientations for the energy mismatch variance, vibrational energy level and double-quantum transition, in the vibration-vibration energy exchange, have been considered. The contribution of molecular attraction increases the exchange rate of the purely repulsive interaction, in general, significantly, but which becomes smaller as the temperature is increased. As the energy mismatch is increased, its contribution is also increased, but which is small. However, its contribution for the double-quantum transition is very paramount. At each orientation, the exchange rate constants have been calculated and compared with the results for rotational average, and it is found that the exchange rate is a strong function of the orientation angles of colliding molecules. We have also discussed about the system having the strong interaction such as the hydrogen bond, and it is found that for this system the preferred orientation should be considered in order to calculate the exchange rates.

Kerr Medium에서의 단독 빔의 간섭에 관한 시뮬레이션 (Simulation of Solitary Beam Interaction in Kerr Media)

  • 심형관
    • 한국시뮬레이션학회논문지
    • /
    • 제12권2호
    • /
    • pp.75-89
    • /
    • 2003
  • This paper describe numerical experiments with solitary beams in a self focusing Kerr medium with fast response. Through formal analogies, it compare this results on the phase sensitivity of beam collision with known predictions about one dimensional soliton interaction. For incoherent oblique beam interaction, there occurs a non-periodic coupled-mode type transfer of energy, resulting in complete transmission each beam through the other one.

  • PDF