• Title/Summary/Keyword: interaction energy.

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Hydrophilic surface formation of polumer treated by ion assisted reaction and its applications (이온빔보조 반응법을 이용한 고분자 표면의 친수성처리와 그 응용)

  • Cho, J.;Choi, S. C.;Yun, K.H.;Koh, S. K.
    • Journal of the Korean Vacuum Society
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    • v.8 no.3B
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    • pp.262-268
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    • 1999
  • Polycarbonate (PC) and Polymethylmethacrylate (PMMA) surface was modified by ion assisted reaction (IAR) technique to obtain the hydrophilic functional groups and improve the wettability. In conditions of ion assisted reaction, ion beam energy was changed from 500 to 1500eV, and ion dose and oxygen gas blown rate were fixed $1\times10^{16}$ ions/$\textrm{cm}^2$ and 4ml/min, respectively. Wetting angle of water on PC and PMMA surface modified by $Ar^+$ ion without blowing oxygen at 4ml/mon showed $5^{\circ}$ and $10^{\circ}$. Changes of wetting angle with oxygen gas and $Ar^+$ ion irradiation were explained by considering formation of hydrophilic group due to a reaction between irradiated polymer chain by energetic ion irradiation and blown oxygen gas. X-ray photoelectron spectroscopy analysis shows that hydrophilic groups such as -C-O, -(C=O)- and -(C=O)-O- are formed on the surface of polymer by chemical interaction. The polymer surface modification using ion assisted reaction only changed the surface physical properties and sept the bulk properties. In comparison with other modification methods, the surface modification by IAR treatment was chemically stable and enhanced the adhesion between metal and polymer surface. The applications of various kinds of polymer surface modification methods, metal and polymer surface. The applications of various kinds of polymer surface modification could be appled to the new materials about hydrophilic surface properties by IAR treatment. The adhesion between metal film and polymer measured by Scotch tape test whether the hydrophilic surfaces could improve the adhesion strength or not.

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The impact of urbanization on per capita CO2 emissions (도시화가 1인당 탄소 배출에 미치는 영향)

  • Hwang, Minsup;Lee, Eungkyoon
    • Journal of Environmental Impact Assessment
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    • v.25 no.5
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    • pp.307-318
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    • 2016
  • This research examines the impacts of urban population growth on per capita $CO_2$ emissions with particular focus on the interaction effect between urbanization and income levels. Employing the Panel Fixed Effects model together with the Pooled LS and Panel GLS models, the research reported here analyzes the relevant data on 84 countries. The statistical results show a nonlinear(an inverted-U) relationship between urbanization and per capita $CO_2$ emissions; that is, while the urban agglomeration leads to increases in per capita $CO_2$ emissions for low income countries, this adverse impact does not hold true for high income countries. The research findings can contribute to addressing broad issues of urban compactness and patterns of energy consumption that should be considered by those concerned about the sustainable urban development.

A Study on the Architectural Application of Biological Patterns (생물학적 패턴의 건축적 적용에 관한 연구)

  • Kim, Won Gaff
    • Korean Institute of Interior Design Journal
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    • v.21 no.2
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    • pp.35-45
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    • 2012
  • The development of digital media made the change of architectural paradigm from tectonic to the surface and pattern. This means the transition to the new kind of materiality and the resurrection of ornament. This study started as an aim to apply biological pattern to architectural design from the new perception of pattern. Architectural patterns in the early era appeared as ladders, steps, chains, trees, vortices. But since 21st century, we can find patterns in nature like atoms and molecular structures, fluid forms of dynamics and new geometrical pattern like fractal and first of all biological patterns like viruses and micro-organisms, Voronoi cells, DNA structure, rhizomes and various hybrids and permutations of these. Pattern became one of the most important elements and themes of contemporary architecture through the change of materiality and resurrection of ornament with the new perception of surface in architecture. One of the patterns that give new creative availability to the architectural design is biological pattern which is self-organized as an optimum form through interaction with environment. Biological patterns emerge mostly as self-replicating patterns through morphogenesis, certain geometrical patterns(in particular triangles, pentagons, hexagons and spirals). The architectural application methods of biological patterns are direct figural pattern of organism, circle pattern, polygon pattern, energy-material control pattern, differentiation pattern, parametric pattern, growth principle pattern, evolutionary ecologic pattern. These patterns can be utilized as practical architectural patterns through the use of computer programs as morphogenetic programs like L-system, MoSS program and genetic algorithm programs like Grasshoper, Generative Components with the help of computing technology like mapping and scripting.

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Analysis of landing mission phases for robotic exploration on phobos mar's moon

  • Stio, A.;Spinolo, P.;Carrera, E.;Augello, R.
    • Advances in aircraft and spacecraft science
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    • v.4 no.5
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    • pp.529-541
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    • 2017
  • Landing phase is one of the crucial and most important phases during robotic aerospace explorations. It concerns the impact of the landing module of a spacecraft on a celestial body. Risks and uncertainties of landing are mainly due to the morphology of the surface, the possible presence of rocks and other obstacles or subsidence. The present work quotes results of a computational analysis direct to investigate the stability during the landing phase of a lander on Phobos, a Mars Moon. The present study makes use of available software tools for the simulation analyses and results processing. Due to the nature of the system under consideration (i.e., large displacements and interaction between several systems), multibody simulations were performed to analyze the lander's behavior after the impact with the celestial body. The landing scenario was chosen as a result of a DOE (Design of Experiments) analysis in terms of lander velocity and position, or ground slope. In order to verify the reliability of the present multibody methodology for this particular aerospace issue, two different software tools were employed in order to emphasize two different ways to simulate the crash-box, a particular component of the system used to cushion the impact. The results show the most important frames of the simulations so as to provide a general idea about how lander behaves in its descent and some trends of the main characteristics of the system. In conclusion, the success of the approach is demonstrated by highlighting that the results (crash-box shortening trend and lander's kinetic energy) are comparable between the two tools and that the stability is ensured.

Development of an Emissions Processing System for Climate Scenario Inventories to Support Global and Asian Air Quality Modeling Studies

  • Choi, Ki-Chul;Lee, Jae-Bum;Woo, Jung-Hun;Hong, Sung-Chul;Park, Rokjin J.;Kim, Minjoong J.;Song, Chang-Keun;Chang, Lim-Seok
    • Asian Journal of Atmospheric Environment
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    • v.11 no.4
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    • pp.330-343
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    • 2017
  • Climate change is an important issue, with many researches examining not only future climatic conditions, but also the interaction of climate and air quality. In this study, a new version of the emissions processing software tool - Python-based PRocessing Operator for Climate and Emission Scenarios (PROCES) - was developed to support climate and atmospheric chemistry modeling studies. PROCES was designed to cover global and regional scale modeling domains, which correspond to GEOS-Chem and CMAQ/CAMx models, respectively. This tool comprises of one main system and two units of external software. One of the external software units for this processing system was developed using the GIS commercial program, which was used to create spatial allocation profiles as an auxiliary database. The SMOKE-Asia emissions modeling system was linked to the main system as an external software, to create model-ready emissions for regional scale air quality modeling. The main system was coded in Python version 2.7, which includes several functions allowing general emissions processing steps, such as emissions interpolation, spatial allocation and chemical speciation, to create model-ready emissions and auxiliary inputs of SMOKE-Asia, as well as user-friendly functions related to emissions analysis, such as verification and visualization. Due to its flexible software architecture, PROCES can be applied to any pregridded emission data, as well as regional inventories. The application results of our new tool for global and regional (East Asia) scale modeling domain under RCP scenario for the years 1995-2006, 2015-2025, and 2040-2055 was quantitatively in good agreement with the reference data of RCPs.

Two Flavonoid-Based Compounds from Murraya paniculata as Novel Human Carbonic Anhydrase Isozyme II Inhibitors Detected by a Resazurin Yeast-Based Assay

  • Sangkaew, Anyaporn;Samritsakulchai, Nawara;Sanachai, Kamonpan;Rungrotmongkol, Thanyada;Chavasiri, Warinthorn;Yompakdee, Chulee
    • Journal of Microbiology and Biotechnology
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    • v.30 no.4
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    • pp.552-560
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    • 2020
  • Human carbonic anhydrase (CA) isozyme II has been used as protein target for disorder treatment including glaucoma. Current clinically used sulfonamide-based CA inhibitors can induce side effects, and so alternatives are required. This study aimed to investigate a natural CA inhibitor from Murraya paniculata. The previously developed yeast-based assay was used to screen 14 compounds isolated from M. paniculata and identified by NMR analysis for anti-human CA isozyme II (hCAII) activity. Cytotoxicity of the compounds was also tested using the same yeast-based assay but in a different cultivation condition. Two flavonoid candidate compounds, 5, 6, 7, 8, 3', 4', 5'-heptamethoxyflavone (4) and 3, 5, 7, 8, 3', 4', 5'-heptamethoxyflavone (9), showed potent inhibitory activity against hCAII with a minimal effective concentration of 10.8 and 21.5 μM, respectively, while they both exhibited no cytotoxic effect, even at the highest concentration tested (170 μM). The results from an in vitro esterase assay of the two candidates confirmed their hCAII inhibitory activity with IC50 values of 24.0 and 34.3 μM, respectively. To investigate the potential inhibition mechanism of compound 4, in silico molecular docking was performed using the FlexX and SwissDock software. This revealed that compound 4 coordinated with the Zn2+ ion in the hCAII active site through its methoxy oxygen at a distance of 1.60 Å (FlexX) or 2.29 Å (SwissDock). The interaction energy of compound 4 with hCAII was -13.36 kcal/mol. Thus, compound 4 is a potent novel flavonoid-based hCAII inhibitor and may be useful for further anti-CAII design and development.

On the Effect of Tube Attenuation on Measuring Water Vapor Flux Using a Closed-path Hygrometer (폐회로 습도계를 이용한 수증기 플럭스 관측시관의 감쇠 효과에 관하여)

  • Hong Jinkyu;Kim Joon;Choi Taejin;Yun Jin-il;Tanner Bert
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.2 no.3
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    • pp.80-86
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    • 2000
  • Eddy covariance method is widely used in measuring vertical fluxes of mass and energy between the atmosphere and the biosphere. In this method, scalar concentration is measured with either open-path or closed-path sensors. For the latter, fluctuations of scalar concentration are attenuated as the sample travels through a long tube, resulting in flux loss. To quantify this tube attenuation, water vapor concentrations measured with both closed-path and open-path sensors were analyzed. Our statistical analysis showed that the power spectral density obtained from the closed-path sensor was different from that from the open-path sensor in the frequency range of > 0.5 Hz. The loss of water vapor flux due to tube attenuation was < 5% during midday. At nighttime, however, the flux loss increased significantly because of the low wind speeds and the weak turbulence sources. Theoretical calculation for the tube attenuation showed a small bias in high frequency range probably because of the interaction of sticky water vapor with a tube wall.

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Frequency Response of Turbulent Flow to Momentum Forcing in a Channel with Wall Blowing (질량분사가 있는 채널 내부 난류 유동의 외부교란에 대한 주파수 특성)

  • Na, Yang;Lee, Chang-Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.38 no.1
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    • pp.64-72
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    • 2010
  • Due to the interaction between main oxidizer flow and the wall injected flow resulting from the regression process, a specific time characteristics identified in the frequency spectrum of streamwise velocity is generated in the hybrid rocket motor. In order to understand the response of the turbulent flow to two different types of external momentum forcing, LES analysis was conducted without considering the combustion. It turns out that both concentrated and distributed forcings do not lead to the disastrous resonance phenomenon. Energy contents are enhanced due to the added momentum but the peak frequency was not modified in the turbulent flow near the end of the rocket motor. Natural frequency of the flow system should be taken into account to further pursue the instability issue by using external forcing.

Digestate residues analysis under elevated heat regime by using DNS method

  • Hanif, Mohamad Haziq;Kamaruddin, Mohamad Anuar;Norashiddin, Faris Aiman;Zawawi, Mohd Hafiz
    • Advances in environmental research
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    • v.9 no.1
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    • pp.55-64
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    • 2020
  • The problems with unsorted municipal waste are always associated with disposal issues as it requires a large area for landfilling or high energy used for incineration. In recent years, an autoclaving technique has been considered a promising approach which could minimize the volume of organic waste from being directly disposed or incinerated. In this work, an attempt was done to study the saccharification potential of organic residues under elevated temperature Thermal treatment involving hot water bath was applied to treat the organic residue ranging from 60℃ to 100℃ for 30 and 60 minutes. The result obtained showed an increasing trend for the concentration of glucose and carbohydrate. However, the result for lignocellulose content which contains various component includes extractive, holocellulose, hemicellulose, cellulose and lignin show variation. Based on the thermal treatment carried out, the result indicated that the trend of glucose and carbohydrate content. The highest percentage of glucose that can be obtained 978.602 ㎍/ml which could be obtained at 90℃ at 60 minutes. The carbohydrate also shows an increasing trend with 0.234 mg/ml as the highest peak achieved at 80℃ for 30 minutes treatment. However, it was found that the lignocellulose content varies with temperature and time. The statistical analysis was carried out using two-ways ANOVA shows an interaction effect between the independent variables (temperature and contact time) and the saccharification effects on the food wastes. The result shows a variation in the significant effect of independent variables on the changes in the composition of food waste.

Tower-based Flux Measurement Using the Eddy Covariance Method at Ieodo Ocean Research Station (이어도해양과학기지에서의 에디 공분산 방법을 이용한 플럭스 관측)

  • Lee, Hee-Choon;Lee, Bang-Yong;Kim, Joon;Shim, Jae-Seol
    • Ocean and Polar Research
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    • v.26 no.2
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    • pp.145-154
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    • 2004
  • Surface energy and $CO_2$ fluxes have been measured over an ocean at Ieodo Ocean Research Station of KORDI since May 2003. Eddy covariance technique, which is a direct flux measurement, is used to quantitatively understand the interaction between the ocean surface and the atmospheric boundary layer. Although fluxes were continuously measured during the period from May 2003 to February 2004, the quality control of these data yielded <20% of data retrieval. The atmospheric stability did not show any distinct dirunal patterns and remained near-neutral to stable from May to June but mostly unstable during fall and winter in 2003. Sensible heat flux showed a good correlation with the difference between the sea water temperature and the air temperature. The maximum fluxes of sensible heat and latent heat were $120Wm^{-2}$ and $350Wm^{-2}$ respectively, with an averaged Bowen ratio of 0.2. The ocean around the tower absorbed $CO_2$ from the atmosphere and the uptake rates showed seasonal variations. Based our preliminary results, the daytime $CO_2$ flux was steady with an average of $-0.1 mgCO_2m^{-2}s^{-1}$ in summer and increased in winter. The nighttime $CO_2$ uptake was greater and fluctuating, reaching up to $-0.1 mgCO_2m^{-2}s^{-1}$ but these data require further examination due to weak turbulent mixing at nighttime. The magnitude of $CO_2$ flux was positively correlated with the half hourly changes in horizontal mean wind speed. Due to the paucity of quality data, further data collection is needed for more detailed analyses and interpretation.