• Geomechanics and Engineering
• /
• 제34권3호
• /
• pp.221-231
• /
• 2023

Biopolymer stabilization is a sustainable alternative to traditional techniques that cause a lesser negative impact on the environment during production and application. The study aims to minimize the biopolymer dosages by sizing the bio-additives to the nanoscale. This study combines the advantages of bio and nanomaterials in geotechnical engineering applications and attempts to investigate the behaviour of a low viscous biopolymer, nano sodium carboxymethyl cellulose (nCMC), to treat organic soil. Soil is treated with 0.25%, 0.50%, 0.75% and 1.00% of nano-bio additive, and its effect on the plastic behaviour, compaction characteristics, strength, hydraulic conductivity (HC) and compressible nature are investigated. The strength increased by 1.68 times after 90 days of curing at a dosage of 0.5% nCMC through the formation of gel threads connecting the soil particles that stiffened the matrix. The viscosity of 1% nCMC increased exponentially, deterring fluid flow through the voids and reduced the HC by 0.85 times after curing for 90 days. Also, beyond the optimum dosage of 0.50%, the nCMC forms a film around the soil particles that inhibits the inter-particle cohesion causing a reduction in strength. Experimental results show that nCMC can effectively substitute conventional additives to stabilize the soil.

• 한국가시화정보학회지
• /
• 제21권3호
• /
• pp.75-84
• /
• 2023

In this study, we conducted analysis of bubble dynamics and flow of liquid phase change material(PCM) using shadowgraphy and particle image velocimetry(PIV). Characteristics of internal flow varied depending on locations of injection when solid PCM was liquefied from heated vertical wall. When bubbles rose immediately, they exhibited elliptical shape and zigzag trajectory. In contrast, when bubbles rose after merging at the bottom of solid PCM, with equivalent diameter for the inter-wall distance of 0.64 or greater, they showed a jellyfish shape and strong rocking behavior. It was observed by the PIV that the small ellipse bubbles made most strong flow inside the liquid PCM. Furthermore, the flow velocity was highest in the case of front injection, as the directions of temperature gradients and bubble-driven flow were aligned. The results underscore the significant influence of injection location on various characteristics, including bubble size, shape, rising path of bubbles, and internal flow.

• Geomechanics and Engineering
• /
• 제15권4호
• /
• pp.1017-1027
• /
• 2018

To explore the influence of coal thickness on the mechanical behavior and the failure characteristics of rock-coal-rock (RCR) mass, the experimental investigation of uniaxial compressive tests was conducted first and then a systematic numerical simulation by particle flow code (PFC2D) was performed to deeply analyze the failure mechanical behavior of RCR specimens with different coal thicknesses in conventional compression tests. The overall elastic modulus and peak stress of RCR specimens lie between the rock and the coal. Inter-particle properties were calibrated to match the physical sample strength and the stiffness response. Numerical simulation results show that the deformation and strength behaviors of RCR specimens depend not only on the coal thickness, but also on the confining pressure. Under low confining pressures, the overall failure mechanism of RCR specimen is the serious damage of coal section when the coal thickness is smaller than 30 mm, but it is shear failure of coal section when the coal thickness is larger than 30 mm. Whereas under high confining pressures, obvious shear bands exist in both the coal section and the rock section when the coal thickness is larger than 30 mm, but when the coal thickness is smaller than 30mm, the failure mechanism is serious damage of coal section and shear failure of rock section.

• 한국대기환경학회지
• /
• 제21권4호
• /
• pp.439-458
• /
• 2005

An automated analysis system for water soluble constituents in $PM_{2.5}$ has been developed. The system consists of a high capacity multi tube diffusion scrubber (MTDS), a low temperature particle impactor (LTPI), and two ion (anion and cation) chromatography (IC) systems. Atmospheric particles have been collected by passing sample air through a thermostated MTDS followed by a LTPI. This system allows simultaneous measurements of soluble ions in $PM_{2.5}$ at 30 minutes interval. At the air sampling flow rate of 1.0L/min, the detection limits of the overall system are in the order of tens of $ng/m^3$. This system has been successfully used for the measurement of particulate components of Seoul air from April 2003 to January 2004. $SO_4^{2-},\;NO_3^-,\;NH_4^+,\;NO_2^-,\;Cl^-,\;Na^+,\;K^+,\;Ca^{2+},\;and\;Mg^{2+}$ are the major ionic species for $PM_{2.5}$ at Seoul. Among them, $SO_4^{2-},\;NO_3^-\;and\;NH_4^+$ are the most abundant ions, contributed up to $86\%$ of the total and the concentrations were higher than those in any other urban sites in the world except for Chinese cities. There are high pollutant episodes which contribute about $15\~20\%$ of annual average values of the major ions. During the episode, the all parcels were transported from the asian continent and $PM_{2.5}$ were significantly neutralized. This suggests that aged and long range transported pollutants caused the high pollutant episodes. They showed a distinct daily and seasonal variations:they showed a peak in the early morning caused by the night-time accumulation of particulate matters. Atmospheric reactions including gas-to-particle reactions and inter-particle reactions and meteorological parameters including relative humidity and ambient temperature were described with related to the $PM_{2.5}$ 5 concentrations. All of the ionic species showed higher concentrations during the spring than those for summer and winter.

• Bulletin of the Korean Chemical Society
• /
• 제33권2호
• /
• pp.553-558
• /
• 2012

A simple new method was developed for the determination of betaine in Fructus Lycii using hydrophilic interaction liquid chromatography with evaporative light scattering detection (HILIC-ELSD). Good chromatographic separation and reasonable betaine retention was achieved on a Kinetex HILIC column ($2.1{\times}100mm$, $2.6{\mu}m$) packed with fused-core particle. The mobile phase consisted of (A) acetonitrile and (B) 10 mM ammonium formate (pH 3.0)/acetonitrile (90/10, v/v). It was used with gradient elution at a flow rate of 0.7 mL/min. The column temperature was set at $27.5^{\circ}C$ and the injection volume was $10{\mu}L$. The ELSD drift tube temperature was $50^{\circ}C$ and the nebulizing gas (nitrogen) pressure was 3.0 bar. Stachydrine, a zwitterionic compound, was used as an internal standard. Calibration curve over $10-250{\mu}g/mL$ showed good linearity ($R^2$ > 0.9992) and betaine in the 70% methanol extract of Fructus Lycii was well separated from other peaks. Intraand inter-day precision ranged from 1.1 to 3.0% and from 2.4 to 5.3%, respectively, while intra- and inter-day accuracy ranged from 100.0 to 107.0% and from 94.3 to 103.9%, respectively. The limit of quantification (LOQ) was $10{\mu}g/mL$ and the recoveries were in the range of 98.2-102.7%. The developed HILIC-ELSD method was successfully applied to quantitatively determine the amount of betaine in fourteen Fructus Lycii samples from different locations, demonstrating that this method is simple, rapid, and suitable for the quality control of Fructus Lycii.

• Bulletin of the Korean Chemical Society
• /
• 제32권8호
• /
• pp.2648-2656
• /
• 2011

A simple HPLC-DAD method was developed and validated to determine B group vitamin content (thiamine, riboflavin, nicotinamide, pantothenic acid, pyridoxine and folic acid) in supplemented food samples, i.e., infant formula, cereal, low-calorie food, a multi-vitamin pill and a vitamin drink. In this study, the most significant advantages were simultaneous determination of the six B group vitamins in various food matrices and a small number of sample treatment steps that required only an organic solvent, acetonitrile. Moreover, this method prevents reduction of column durability, because the mobile phase does not contain ion-pairing reagents. Analytes were separated on a Develosil RPAQUEOUS $C_{30}$ (4.6 mm ${\times}$ 250 mm, 5 ${\mu}M$ particle size) column with a gradient elution of acetonitrile and 20 mM phosphate buffer (pH 3.0) at a flow rate between 0.8 and 1.0 mL/min. Detection was performed at 275 nm, except for that of pantothenic acid (205 nm). The calibration curves for all six vitamins showed good linearity with correlation coefficients ($r^2$) higher than 0.995. The developed method was validated with respect to linearity, intra- and inter-day accuracy and precision, limit of quantification (LOQ), recovery and stability. The method showed good precision and accuracy, with intra- and inter-assay coefficients of variation less than 15% at all concentrations. The recovery was carried out according to the standard addition procedure, with yields ranging from 89.8 to 104.4%. This method was successfully applied to the determination of vitamin B groups in supplemented food products.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
• /
• pp.434-435
• /
• 2012

Plasma enhanced chemical vapor deposition (PECVD) silicon dioxide thin films have many applications in semiconductor manufacturing such as inter-level dielectric and gate dielectric metal oxide semiconductor field effect transistors (MOSFETs). Fundamental chemical reaction for the formation of SiO2 includes SiH4 and O2, but mixture of SiH4 and N2O is preferable because of lower hydrogen concentration in the deposited film [1]. It is also known that binding energy of N-N is higher than that of N-O, so the particle generation by molecular reaction can be reduced by reducing reactive nitrogen during the deposition process. However, nitrous oxide (N2O) gives rise to nitric oxide (NO) on reaction with oxygen atoms, which in turn reacts with ozone. NO became a greenhouse gas which is naturally occurred regulating of stratospheric ozone. In fact, it takes global warming effect about 300 times higher than carbon dioxide (CO2). Industries regard that N2O is inevitable for their device fabrication; however, it is worthwhile to develop a marginable nitrous oxide free process for university lab classes considering educational and environmental purpose. In this paper, we developed environmental friendly and material cost efficient SiO2 deposition process by substituting N2O with O2 targeting university hands-on laboratory course. Experiment was performed by two level statistical design of experiment (DOE) with three process parameters including RF power, susceptor temperature, and oxygen gas flow. Responses of interests to optimize the process were deposition rate, film uniformity, surface roughness, and electrical dielectric property. We observed some power like particle formation on wafer in some experiment, and we postulate that the thermal and electrical energy to dissociate gas molecule was relatively lower than other runs. However, we were able to find a marginable process region with less than 3% uniformity requirement in our process optimization goal. Surface roughness measured by atomic force microscopy (AFM) presented some evidence of the agglomeration of silane related particles, and the result was still satisfactory for the purpose of this research. This newly developed SiO2 deposition process is currently under verification with repeated experimental run on 4 inches wafer, and it will be adopted to Semiconductor Material and Process course offered in the Department of Electronic Engineering at Myongji University from spring semester in 2012.

• 대한안전경영과학회지
• /
• 제13권4호
• /
• pp.109-116
• /
• 2011

This study examined into property of flour dust explosion to get the basic data for safety of industry by protecting accident of dust explosion. The experiment was conducted to know the effect of distance between explodes in the experiment device, effect of flour dust concentration, effect of humidity, effect of explosion pressure to the dust concentration and effect of inactive substance additive. The study indicated that explosion was happened effectively at the optimum distance 100mm or less in inter-polar distance, and minimum ignition energy was measured at 6mm. The data of feed concentration to the probability of explosion showed that the smaller the particle diameter was, the larger probability of explosion was, and the higher the dust concentration was, the more increased the pressure of explosion was, but more than upper limit of dust concentration, then the explosion of pressure decreased. For the effect of humidity, the more it contained water, the more decreased the ignition energy of dust was, so increased minimum explosive concentration, and effective water content was minimum 10% or more. Inactive substance additive was effective in adding more than 15% CaCO3 and CaO as substance inhibiting dust explosion, in which CaCO3 was more effective than CaO. the analysis of the flame of dust explosion was performed by high-speed video camera, it showed the size of flame bacame smaller in order that sub feed, main feed, wheat powder. As a result, sub feed was expected to be less dangerous than others.

• 한국지구과학회지
• /
• 제30권6호
• /
• pp.734-743
• /
• 2009

본 연구는 부산지역의 먼지 농도와 황사발원지의 기후학적 요소를 주기분석 함으로써 부산지역의 먼지농도 주기에 영향을 주는 기후학적 조건, 특히 황사 발생과의 관련성에 대하여 고찰하였다. 부산지역에서 관측된 먼지 농도 시계열 자료를 이용한 단일스펙트럼분석을 수행한 결과 배출량이나 강수 효과 등에 의해 나타난 일반적인 주기(1년, 7일) 이외에, 상대적으로 3-4년 주기가 우세하게 나타났으며, 먼지 농도와 부산지역의 기상자료 및 황사발원지에서의 풍속과의 교차스펙트럼 분석을 통한 주기 분석을 수행해 본 결과, 3-4년 주기일 때 먼지농도와 풍속, 기압은 양의 상관관계, 기온, 상대습도와는 각각 음의 상관관계가 나타났다. 이는 황사 발생 조건과 잘 부합되는 것으로 나타나, 3-4년의 먼지 농도 주기는 황사의 장거리 수송과 관련이 있는 것으로 판단된다. 또한 황사 발생은 발원지의 지표 상태에 따라 발생빈도가 달라지므로, 여러 기후학적 요소들 중 황사발원지에서의 강수량과의 주기 분석을 수행해 본 결과, 발원지에서의 강수량 그 자체보다는 발원지에서의 가뭄지수(EDI)의 시계열이 우리나라 먼지 농도의 3-4년 주기와 더 연관이 있는 것으로 나타났고 이는 기후학적으로 황사 발원지에서의 지표건조 특성의 변동성과 연관이 있는 것으로 나타났다.

• 한국환경보건학회지
• /
• 제30권2호
• /
• pp.140-148
• /
• 2004

To evaluate the acute effects of fine particles on pulmonary function, a longitudinal study was conducted. This study was carried out for the schoolchildren (3rd and 6th grades) living in Beijing, China. Each child was provided with a mini-Wright peak flow meter and a preformatted health symptom diary for 40 days, and was trained on their proper use. Participants were instructed to perform the peak flow test three times in standing position, three times a day (9 am, 12 pm, and 8 pm), and to record all the readings along with the symptoms (cold, cough, and asthmatic symptoms) experienced on that day. Daily measurement of fine particles (PM$_{10}$ and PM$_{2.5}$) was obtained in the comer of the playground of the participating elementary school for the same period of this longitudinal study. The relationship between daily peak expiratory flow rate (PEFR) and fine particle levels was analyzed using a mixed linear regression models including gender, height, the presence of respiratory symptoms, and daily average temperature and relative humidity as extraneous variables. The total number of students participating in this longitudinal study was 87. The range of daily measured PEFR was 253-501$\ell$/min. In general, the PEFR measured in the morning was lower than the PEFR measured in the evening (or afternoon) on the same day. The daily mean concentrations of PM$_{10}$ and PM$_{2.5}$ over the study period were 180.2$\mu\textrm{g}$/㎥ and 103.2$\mu\textrm{g}$/㎥, respectively. The IQR (inter-quartile range) of PM$_{10}$ and PM$_{2.5}$ were 91.8$\mu\textrm{g}$/㎥ and 58.0$\mu\textrm{g}$/㎥. During the study period, the national ambient air quality standard of 150$\mu\textrm{g}$/㎥ (for PM$_{10}$) was exceeded in 23 days (57.5%). The analysis showed that an increase of 1$\mu\textrm{g}$/㎥ of PM$_{10}$ corresponded to 0.59$\mu\textrm{g}$/㎥ increment of PM$_{2.5}$. Daily mean PEFR was regressed with the 24-hour average PM$_{10}$ (or PM$_{2.5}$) levels, weather information such as air temperature and relative humidity, and individual characteristics including gender, height, and respiratory symptoms. The analysis showed that the increase of fine particle concentrations was negatively associated with the variability in PEFR. The IQR increments of PM$_{10}$ or PM$_{2.5}$ (at 1-day time lag) were also shown to be related with 1.54 $\ell$/min (95% Confidence intervals: 0.94-2.14) and 1.56$\ell$/min (95% CI: 0.95-2.16) decline in PEFR.R.ine in PEFR.ine in PEFR.