• Title/Summary/Keyword: inorganic material

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Removal of Nitrogen Using by SOD Process in the Industrial Wastewater Containing Fluoride and Nitrogen from the Zirconium Aolly Tubing Production Factory of the Nuclear Industry (원자력산업 지르코늄합금 튜브 생산공장에서 배출되는 불소.질소 함유 폐수의 황산화탈질을 이용한 질소처리)

  • Cho, Nam-Chan;Moon, Jong-Han;Ku, Sang-Hyun;Noh, Jae-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.11
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    • pp.855-859
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    • 2011
  • The main pollutants from zirconium alloy tubing manufacturing process in nuclear industry are nitrate ($NO_3-N$) and fluoride (F-)Nitric acid, and hydrofluoric acid is used for acid pickling. The process for the removal of nitrate and fluoride is composed of 1st chemical coagulation, SOD (Sulfur Oxidation Denitrification) process using sulfur-oxidizing denitrification, and 2nd chemical coagulation. The characteristic of the wastewater treatment is an application of SOD process. The SOD Process is highly received attention because it is significantly different from existing processes for sulfur denitrification. A JSC (JeonTech-Sulfur- Calcium) Pellet is unification of sulfur and alkalinity material. According to result of SOD process in wastewater treatment plant, the removal efficiency of T-N was over 91% and the average concentration of T-N from influent was 147.55 mg T-N/L and that from effluent was 12.72 mg T-N/L. Therefore, SOD process is a useful to remove nitrogen from inorganic industrial wastewater and a new development of microbial activator was shown to be stable for activation of autotrophic bacteria.

ELECTRON MICROSCOPIC STUDY OF RESIN-DENTIN HYBRID ZONE PRODUCED BY THE MOISTENING OF ACID CONDITIONED DENTIN SURFACE (산 표면처리 후 상아질 표면의 습윤이 하이브리드층 형성에 관한 전자현미경적 연구)

  • Lee, Kwang-Won;Lee, Myung-Jong
    • Restorative Dentistry and Endodontics
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    • v.20 no.2
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    • pp.463-486
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    • 1995
  • The effect of moistening and air-drying of acid-conditioned dentin before priming on the formation of resin-dentin hybrid zone was investigated, Freshly extracted human molars were used and divided at random into 5 groups, Groups 1 - 3 consisted of specimens conditioned with 10 % phosphoric acid for 20 seconds; Group 1 served as a control in which the conditioned dentin was simply blot-dried with a damp facial tissue; Group 2 was air dried for 30 seconds ; Group 3 was air dried for 30 seconds and immediately remoistened for 10 seconds with air-water syringe. and then the specimen was blot-dried with a damp facial tissue. Groups 4-5 were not acid conditioned ; In group 4, the smear layer on the dentin was blot dried before primer placement; Group 5 was air dried only for 30 seconds, The acetone-based primer and bonding agent of All Bond 2 (Bisco. Inc., USA) and composite resin (Z-100, 3M Dental products, USA) were applied for acid conditioned dentin and non-conditioned dentin. The morphologic ultrastructure of resin-dentin hybrid zone was examined by the use of SEM and TEM. and the existence of inorganic material and analysis of Ca/P weight-percent ratio in the resin-dentin hybrid zone were revealed by the EDAX, The results were as follows : 1. In the moistened specimens from acid-conditioned groups, the resin penetrated about 3-$4{\mu}m$ into dentin and the denatured collagen smear layer was not present at the surface. The resin tag was formed to a thickeness of 3-$4{\mu}m$ at the upper part of dentinal tubule and compactively connected to each other by means of many lateral branching. 2. In the air-dried specimens from acid-conditioned groups, the resin penetrated about 2.0-$2.5\;{\mu}m$ into dentin and an upper thin black layer to a thickness of 30-35nm was identified between adhesive resin and demineralized collagen layer. The resin tag to have a diameter of $2.5{\mu}m$ was formed at the upper part of dentinal tubule. However the funnel shape of the tag was not notable compared to the moistened specimens. 3. In the remoistened specimens from acid conditioned groups, the resin penetrated about 2.0-$2.5{\mu}m$ into dentin and an upper black layer was not present. The resin tag at the upper part of dentinal tubule was formed less than $2{\mu}m$ and was weakly connected to each other by means of few lateral branching. 4. In the non-conditioned groups, the smear layer was formed to a thickness of $0.5{\mu}m$ at dentin surface. However, the resin-dentin hybrid zone was not identified by TEM. The evidence of resin penetration into intertubular and intratubular dentin did not show. 5. All the acid-conditioned groups showed that the detected calcium and phosphorus weight percent ratios at the $2{\mu}m$ upper portion from the resin-dentin interface into the resin were much higher than that at the $2{\mu}m$ lower portion from the resin-dentin interface to dentin. (P<0.01).

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A study on the hydraulic characteristics of the geosynthetic clay liners(GCL) with humic substances of leachate on the landfill. (폐기물 매립지의 침출수의 휴믹물질에 의한 토목합성수지 점토라이너의 수리학적 특성에 관한 연구)

  • 한영수;이재영
    • Journal of Soil and Groundwater Environment
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    • v.7 no.1
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    • pp.33-40
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    • 2002
  • The study was performed to evaluate the effect of landfill leachate on the hydraulic conductivity of Geosynthetic Clay Liner (GCL) with two types of leachate. GCL used in waste landfills have a significant ability as a barrier material, however, they also have a potential danger when exposed to some organic and inorganic leachate as well as humic materials. In this study, swelling tests and hydraulic conductivity tests were performed to evaluate the effect of humic materials and landfill leachate on the hydraulic characteristics of the GCL. The result of swelling tests showed that the amount of humic materials and high electronic conductivity caused a decrease of the swelling of bentonite. This is expected to increase the hydraulic conductivity of GCL. The increasing of hydraulic conductivity observed for GCL permeated with 0-leachate was significantly higher than that of Y-leachate. This result shows that humic materials are obviously affecting with the increasing of hydraulic conductivity of GCL.

Combustion Characteristics of Bamboo Charcoal Boards (대나무숯 성형보드의 연소특성)

  • Park, Sang-Bum;Park, Joo-Saeng
    • Journal of the Korean Wood Science and Technology
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    • v.40 no.1
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    • pp.19-25
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    • 2012
  • The fire retardant bamboo charcoal (BC) boards were manufactured for interior building materials in this study, The BC boards were manufactured by mixing and pressing of the bamboo charcoal, expanded vermiculite, and inorganic binder. The combustion behaviors of the BC boards were investigated using a cone calorimeter at an incident heat flux of 50 kW/$m^2$. Three building materials (plywood, BC board of Japan, and gypsum board) were used to observe the burning behaviors of weight loss, total heat release rate, and maximum heat release rate. Surface test and toxicity evaluation of the BC board were also conducted. The weight loss of the BC board (12.0%) was lower than the nonflammable gypsum board (15.6%) after burning of 10 min. Total heat release of the BC was 3 MJ/$m^2$ (KS standard 8 MJ/$m^2$) and total heat release rate of the BC was 20 kW/$m^2$ (KS standard 200 kW/$m^2$). Therefore, the BC boards were adjustable for the third-grade flame retardant building materials. External appearance change and mouse toxicity were not found in the BC boards after the combustion test.

Behaviors of Ionic Conductivity with Temperature for High-Temperature PEMFC Containing Room Temperature ionic Liquids Under Non-humidified Condition (상온 이온액을 이용한 고온 무수 PEMFC용 고정화 액막의 온도에 따른 이온전도도 거동)

  • Kim, Beom-Sik;Byun, Yong-Hoon;Park, You-In;Lee, Sang-Hak;Lee, Jung-Min;Koo, Kee-Kahb
    • Membrane Journal
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    • v.16 no.4
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    • pp.268-275
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    • 2006
  • Novel SILEMs were prepared by multi-stage phase separation process combined by the low temperature phase separation (LTPS) and the high temperature phase separation (HTPS) using room temperature ionic liquids (RTILs) which have a high ionic conductivity. PVDF and imidazolium series ionic liquids were used as membrane material and electrolyte, respectively. To study the ion conducting properties, the SILEMs were tested using LCR meter at temperature controlled from 30 to $130^{\circ}C$. Under humid conditions, with increasing temperature from 30 to $100^{\circ}C$, the ion conductivity of the cast $Nafion^{(R)}$ membrane increased linearly, but then started to decrease after $100^{\circ}C$. However, in the case of the SILEMs, with increasing operating temperature, the ion conductivity increased. Also, the ion conductivity behaviors of the SILEMs were almost same, regardless of humidity. The ion conductivity of the SILEMs was $2.7{\times}10^{-3}S/cm$ and increased almost linearly up to $2.2{\times}10^{-2}S/cm$ with increasing temperature to $130^{\circ}C$. The effects of an inorganic filler on the physical properties of the SILEMs were studied using the $SiO_2$. The addition of $SiO_2$ could improve the mechanical strength of the SILEMs, though the ionic conductivity was decreased slightly.

Development of Standard Analysis Methods for Physical Properties on Korean bedsoil 1. Particle density and Bulk density (우리나라 상토의 물리적 표준분석법 설정 연구 1. 입자밀도 및 용적밀도)

  • Kim, Lee-Yul;Cho, Hee-Kee
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.6
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    • pp.327-334
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    • 2002
  • Method of besoil analysis were difficult to be applied universally since the use and the source material of bedsoils are diverse from country to country. Korean Standard Methods for Bedsoil Analysis was developed to measure the particle and bulk density. Fifty-three samples for horticultural bedsoil and nine samples for paddy rice bedsoil in the current market were collected. Particle density was measured by electrical pyconometer with He gas, and bulk density by the sandbox method, free fall method, plunger compaction method, free fall and plunger method, and sample weight compaction method. While the use of glass pycnometer which measures particle density to fill blank space with water was inappropriate due to floating organic and calcined inorganic materials in the water, the electrical pycnometer with gas type was suitable considering speed and accuracy. For bulk density, the sandbox method recommended as European Standard Method was more reasonable in principle than other methods. However, this method requires expensive apparatus and intricate process. Plunger compaction method was proposed as standard method, since it had higher consistence with the sandbox method than other methods, as well as an advantage of easy and prompt measurement. Particle density of bedsoil ranged $1.48{\sim}2.67Mg\;m^{-3}$(mean $1.93Mg\;m^{-3}$) for horticultural bedsoil and $2.33{\sim}2.67Mg\;m^{-3}$ (mean $2.43Mg\;m^{-3}$) for paddy rice bedsoil by the electrical pycnometer with He gas. Bulk density of bedsoil ranged $0.11{\sim}0.40Mg\;m^{-3}$ (mean $0.22Mg\;m^{-3}$) for horticultural bedsoil and $0.84{\sim}1.26Mg\;m^{-3}$(mean $1.01Mg\;m^{-3}$) for paddy rice bedsoil by plunger compaction method.

Analysis of General Ingredient and Amino Acid Contents in Silkworm Feces with Different Extracting Methods and Collecting Time (추출 방법 및 채취 시기를 달리한 잠분추출물의 일반성분 및 아미노산 함량 분석)

  • Sohn, Bong-Hee;Chung, Wan-Tae;Kang, Pil-Don;Ryu, Kang-Sun;Jung, I-Yeon;Kim, Yong-Soon;Kim, Kee-Young;Kim, Mi-Ja;Chung, In-Sick
    • Journal of Sericultural and Entomological Science
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    • v.49 no.2
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    • pp.43-46
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    • 2007
  • Analysis of general ingredients and amino acid content in dried silkworm feces which were extracted with hot water, EtOH, MeOH for developing new income source of rearing farm, seeking high additive value material and industrialization of silkworm feces. In the analysis of general ingredient content by extracting solution, raw protein and ash contents were increased with MeOH, EtOH, hot water. And raw fat showed higher contents by the order of EtOH > MeOH > hot water. The inorganic matter content showed a little difference among collection times of silkworm feces. Hot water was most effective extracting solution for total amino acid, and no significant difference between EtOH and MeOH. According to the time, there were no significant difference in amino acid contents. When extracted with hot water, Glu content was highest content and order of others is Asp > Gly > Ala > Leu > Thr > Ser among 18 amino acids.

Effects of CellCaSi and Inorganic Additives on Phosphorus Removal in Water (규산질다공체와 무기첨가물의 수중 인 제거 효과)

  • Park, Myung-Hwan;Han, Myung-Soo;Lee, Seog-June;Ahn, Chi-Yong;Yoon, Byung-Dae;Oh, Hee-Mock
    • Korean Journal of Ecology and Environment
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    • v.35 no.3 s.99
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    • pp.213-219
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    • 2002
  • The CellCaSi, a porous silicate material, was tested for the removal of phosphorus (P as phosphate) in water. The effect of the CellCaSi was investigated on the basis of both particle size (under 1,2, and 4 mm) and added amount (0, 1, 2.5, 5, and 10 g/1) of the CellCaSi. The removal efficiency of phosphorus was highest with a particle size of under 1 mm and also increased with an increasing amount of the CellCaSi. The pH change showed little effect on the phosphorus removal of the CellCaSi. The calcium ion was eluted from the CellCaSi into the water, while the aluminium and iron were not. The eluted calcium ion was combined with dissolved phosphorus and then precipitated. The highest removal efficiency of phosphorus was obtained by the combined addition of the CellCaSi, calcium chloride, and ferric chloride. That is, the phosphorus concentrations of 0.10 and 1.0 mg/1 decreased to 0.03 and 0.47 mg/l by the addition of the CellCaSi (1 g/l), calcium ion (30 mg/l), and ferric ion (1 mg/l) at day 8 after treatment. The water qualities at the end of the experiment were as follows: pH was 8.1 and conductivity was 318 ${\mu}$S/cm (a registered maximum conductivity of 500${\mu}$S/cm for raw and potable wafers).

Study on Synthesis of 68GeO2 and Behavior of 68Ga3+ for Generator Column (Generator 컬럼용 68GeO2 합성 및 68Ga3+의 거동에 관한 연구)

  • Kim, Gun Gyun;Lee, Jun Young;Kim, Sang Wook;Hur, Min Gu;Yang, Seung Dae;Park, Jeong Hoon
    • Journal of Radiation Industry
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    • v.10 no.4
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    • pp.189-192
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    • 2016
  • $^{68}Ga$ has emerged as a promising candidate for non-invasive diagnostic imaging within Positron Emission Tomography (PET) because of its advantageous radiochemical characteristics ($t_{1/2}=68min$, ${\beta}^+$ yield ~89%). $^{68}Ga$ forms a stable chelation with various ligands and it is possible to be quickly and easily study using a $^{68}Ge/^{68}Ga$ generator. Commercial $^{68}Ge/^{68}Ga$ generators are chromatographic system using the inorganic materials such as alumina and tin dioxide which are employed as column matrixes for $^{68}Ge$. In this study, we tried out to make $^{68}Ge/^{68}Ga$ generator system with the $^{68}GeO_2$ microstructures for column matrix. $^{68}Ge$ tends to have stable bond with oxide as $^{68}GeO_2$ microstructures. The $^{68}GeO_2$ has been synthesized by hydrolysis of $GeCl_4$ (sol-gel method) and characterized by X-ray diffraction and scanning electron microscope for geometrical analysis. The stability of $GeO_2$ was tested using eluents with diverse solvents(water, ethanol and 0.1 N HCl). The radioactivity of $^{68}Ga^{3+}$ in eluate through $GeO_2$ was measured to prove a function as column material for a generator.

Compressive Strength Evaluation of Concrete with Mixed Plastic Waste Aggregates Filled with Blast Furnace Slag Fine Powder (무기충진재를 혼입한 복합 폐플라스틱 골재를 활용한 콘크리트 압축강도 특성)

  • Lee, Jun;Kim, Kyung-Min;Cho, Young-Keun;Kim, Ho-Kyu;Kim, Young-Wook
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.253-259
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    • 2021
  • Plastic wastes generated from household waste are separated by mixed discharge with foreign substances, and recycling is relatively low. In this study, the effect of the ratio and content of mixed plastic waste coarse aggregate(MPWCA)s and mixed plastic waste fine aggregate(MPWFA)s filled with blast furnace slag fine powder on the slump and compressive strength of concrete was evaluated experimentally. The MPWCAs were found to have a similar fineness modulus, but have a single particle size distribution with a smaller particle size compared to coarse aggregates. However, the MPWFAs were found to have a single particle size distribution with a larger fineness modulus and particle size compared to fine aggregates. Meanwhile, the effect of improving the density and filling pores by the blast furnace slag fine power was found to be greater in the MPWFA compared to the MPWCA. As the amount of the mixed plastic waste aggregate(MPWA)s increased, the slump and compressive strength of concrete decreased. In particular, the lower the slump and compressive strength of concrete was found to decrease the greater the amount of MPWFA than MPWCA when the amount of MPWA was the same. This is because of the entrapped air and voids formed under the angular- and ROD-shaped aggregates among the MPWFAs. On the other hand, the addition of the admixture and the increase in the unit amount of cement were found to be effective in improving the compressive strength of the concrete with MPWAs.