• Title/Summary/Keyword: inorganic N

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Thermal Insulation and Flame Retardant Properties of Cement Based Super Light-weight Inorganic Thermal Insulation using 100㎛ Grade Glass Bubble (100㎛급 글라스 버블 혼입 시멘트계 초경량 무기 단열재의 단열 및 난연특성)

  • Son, Bae-Geun;Song, Hun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.642-649
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    • 2021
  • Energy saving standard for buildings are strengthened, the application of exterior insulation finishing system and thickness of insulation materials are increasing. Most buildings with exterior insulation finishing system is applied organic insulating material. Organic insulating material have workability, economic feasibility, reduction in construction cost, and excellent thermal insulation performance. However, Organic insulating material is very vulnerable to heat, so when a fire occurs, rapid fire spread and toxic gas are generated, causing many casualties. Inorganic insulating material can be non-combustible performance, but it is heavy and has low thermal insulation performance. Mineral wool has higher thermal insulation performance than other types of inorganic insulating material, but mineral wool is disadvantageous to workability and vulnerable to moisture. Glass bubble are highly resistant to water and chemically stable substances. In addition, the density of the glass bubble is very low and the particles are spherical, fluidity is improved by the ball bearing effect. Glass bubbles can be used with cement-based ino rganic insulating material to impro ve the weight and thermal insulatio n perfo rmance o f cement-based inorganic insulation. This study produced a inorganic insulating materials were manufactured using cement-based materials and glass bubble. In order to evaluate the insulation performance and flame retardant performance of cement-based super light-weight inorganic insulating materials using with glass bubble, insulation performance or flame retardant and non-combustible performance were evaluated after manufacturing insulating materials using micro cement and two types of glass bubbles. From the test result, Increasing the mixing ratio of glass bubbles improved the insulation performance of cement-based super light-weight inorganic insulating materials, and when the mixing ratio of glass bubbles was 10%, it sho wed sufficient flame retardant and no n-co mbustible perfo rmance.

The Theory and Application of Diffusive Gradient in Thin Film Probe for the Evaluation of Concentration and Bioavailability of Inorganic Contaminants in Aquatic Environments (박막분산탐침(diffusive gradient in thin film probe)의 수중 생물학적 이용가능한 중금속 측정 적용)

  • Hong, Yongseok
    • Journal of Korean Society on Water Environment
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    • v.29 no.5
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    • pp.691-702
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    • 2013
  • This review paper summarizes the theory, application, and potential drawbacks of diffusive gradient in thin film (DGT) probe which is a widely used in-situ passive sampling technique for monitoring inorganic contaminants in aquatic environments. The DGT probe employs a series of layers including a filter membrane, a diffusive hydrogel, and an ionic exchange resin gel in a plastic unit. The filter side is exposed to an aquatic environment after which dissolved inorganic contaminants, such as heavy metals and nuclides, diffuse through the hydrogel and are accumulated in the resin gel. After retrieval, the contaminants in the resin gel are extracted by strong acid or base and the concentrations are determined by analytical instruments. Then aqueous concentrations of the inorganic contaminants can be estimated from a mathematical equation. The DGT has also been used to monitor nutrients, such as ${PO_4}^{3-}$, in lakes, streams, and estuaries, which might be helpful in assessing eutrophic potential in aquatic environments. DGT is a robust in-situ passive sampling techniques for investigating bioavailability, toxicity, and speciation of inorganic contaminants in aquatic environments, and can be an effective monitoring tool for risk assessment.

A Study on Stability of Inorganic Binder for Application as Conservation Material for Stone Monuments (석조문화재 보수물질로의 적용을 위한 무기질 바인더 안정성 연구)

  • Kim, Dae Sik;Do, Jin Young;Cho, Hyen Goo
    • Journal of the Mineralogical Society of Korea
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    • v.27 no.4
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    • pp.251-262
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    • 2014
  • Inorganic binders were studied in order to apply a conservation material for stone monument. A pure inorganic binder and 3 species of inorganic binder which contain additives on the basis of a pure inorganic binder were selected as test samples. Through the application of inorganic binders on Geochang granite investigate their influences on stone. pH 4.0 and 5.6 acid solution, respectively were manufactured on the basis of the acidity of domestic rainfall. Alkaline water with pH 8.0 and deionized water with pH 6.85 were prepared as control group. Changes in weights of inorganic binders were not definite according to the acidity of water while weight losses in inorganic binder type were greater after reaction with the water. The compressive strengths of pure inorganic binder was largest before the test but its decrease rate were larger after reaction with the water. Water absorption rate of inorganic binders are 6.72 to $12.44kg/m^2{\cdot}t^{1/2}$ after reaction with the water. Such high absorption was considered that it forced water to move deep into inorganic binder and made the components of inorganic binder dissolve. Acidities of the water of pH 4.0, 5.6, 6.85 and 8.0, respectively were changed to pH 9.0-10.0 after reaction with the inorganic binders. Ion concentrations in the water changed after reaction with the inorganic binders and $Mg^{2+}$, and $K^+$ significantly increased, dissolved from the binder. The high concentration of ions detected showed that the binder reacted with water and formed white salts with high solubility such as $MgSO_4{\cdot}nH_2O$, $KNO_3$. Ion concentrations significantly decreased from the binder after treatment with consolidant and water repellent.

Heat Transfer Characteristics of the Spherical Capsule Storage System Using Paraffins

  • Cho, Keum-Nam;Choi, S. H.
    • International Journal of Air-Conditioning and Refrigeration
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    • v.6
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    • pp.113-123
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    • 1998
  • The present study is to investigate the effect of experimental parameters on the heat transfer characteristics of a spherical capsule storage system using paraffins. N-Tetradecane and mixture of n-Tetradecane 40% and n-Hexadecane 60% were used as paraffins. Water with inorganic material was also tested for the comparison. The experimental parameters were varied for the Reynolds number from 8 to 16 and for the inlet temperature from -7 to 2$^{\circ}C$. Measured local temperatures of spherical capsules in the storage tank were utilized to calculate charging and discharging times, dimensionless thermal storage amount, and the average heat transfer coefficients in the tank. Local charging and discharging times in the storage tank were significantly different. The effect of inlet temperature on charging time was larger than that on discharging time, but the effect of Reynolds number on charging time was smaller than that on discharging time. Charging time of paraffins was faster by 11~72% than that of water with inorganic material, but little difference of discharging time was found among them. The effect of Reynolds number on the dimensionless thermal storage was less during charging process and more during discharging process than the effect of inlet temperature. The effect of the inlet temperature and the Reynolds number on the average heat transfer coefficient of the storage tank was stronger during discharging process than during charging process. The average heat transfer coefficients of the spherical capsule system using paraffins were larger by 40% than those using water.

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Organic Wastewater Treatment by using Bamboo Charcoal (대나무 고온탄을 이용한 유기성 폐수처리)

  • Kim, Sun-Hwa;Kim, Hae-Jin;Kim, Joon-Tae
    • Journal of environmental and Sanitary engineering
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    • v.22 no.1 s.63
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    • pp.17-27
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    • 2007
  • This study was conducted the adsorption experiment way of organic wastewater (BOD, COD, TOC, T-N, T-P) by changing the carbonization temperature and the size of adsorbent to examine the adsorption capacity of Korean traditional charcoal which has similar characteristics to activated carbon of organic pollutants. Also, it was performed the basic experiment for pH and inorganic materials. As a result of observing Korean traditional charcoal with has the greatest inorganic contents which are the important factor of chemical adsorption. As the carbonization temperature was better high temperature charcoal than law temperature charcoal to adsorption capacity of pollutant and as the particle was minute (D size : $3.35mm{\sim}2.0mm$), it was most effective. The result of adsorption experiment of organic wastewater show that the elimination ratio of pollutants by bamboo high temperature charcoal was found as BOD(82.1%), COD(91.7%), TOC(52.4%), T-N(66.6%), T-P(83.2%) and it has most excellent adsorption capacity of organic pollutants.

Movement of Applied Nutrients through Soils by Irrigation -III. Effect of Soil Water on the Movement of Nitrogen (관수(灌水)에 의(依)한 시비양분(施肥養分)의 토양중(土壤中) 이동(移動)에 관(關)한 연구(硏究) -III. 토양수분(土壤水分) 조건(條件)에 따른 질소(窒素)의 이동(移動))

  • Ryu, Kwan-Shig;Yoo, Sun-Ho;Song, Kwan-Cheol
    • Korean Journal of Soil Science and Fertilizer
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    • v.27 no.3
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    • pp.232-237
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    • 1994
  • Field microplot(D 20cm, 1 85cm) experiment filled with Bonryang sandy loam soil(Typic Udifluvents) was conducted to obtain quantitative information on the movement of applied nitrogen under different soil moisture regimes and ladino clover cultivation. Urea applied to the soil was quickly transformed into $NH_4$-N which was slowly to $NO_3$-N which governed the downward movement of inorganic N applied in the soil. Downward movement of inorganic nitrogen was relatively slow in the early growing stages of ladino clover when $NH_4$-N form was the major inorganic nitrogen in the soil. In the later growing stages when $NO_3$-N was the major form, inorganic nitrogen moved rapidly with soil water. Favorable soil moisture condition increased downward movement and plant uptake of inorganic nitrogen. In the non irrigated bare soil 92% of applied nitrogen was leached downwards out of the microplots at the final harvest. Under the non-irrigated condition 57% of applied nitrogen was taken up by plants and 37% of nitrogen remained in the soil 5.5 months after sowing. Nitrogen uptake by plants in the microplots irrigated at 0.2 bar was 4.03g/microplot at the final harvest, which was more than the amount of nitrogen applied.

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Effects of Organic or Inorganic Acid Supplementation on Growth Performance, Nutrient Digestibility and White Blood Cell Counts in Weanling Pigs

  • Kil, D.Y.;Piao, L.G.;Long, H.F.;Lim, J.S.;Yun, M.S.;Kong, C.S.;Ju, W.S.;Lee, H.B.;Kim, Y.Y.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.2
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    • pp.252-261
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    • 2006
  • Four experiments were conducted to investigate the effect of organic or inorganic acid supplementation on the growth performance, nutrient digestibility, intestinal measurements and white blood cell counts of weanling pigs. In growth trial (Exp I), a total of 100 crossbred pigs ({$Landrace{\times}Yorkshire$}${\times}$Duroc), weaned at $23{\pm}2$ days of age and $7.25{\pm}0.10kg$ average initial body weight (BW), were allotted to 5 treatments by body weight and sex in a randomized complete block (RCB) design. Three different organic acids (fumaric [FUA], formic [FOA] or lactic acid [LAA]) and one inorganic acid (hydrochloric acid [SHA]) were supplemented to each treatment diet. Each treatment had 5 replicates with 4 pigs per pen. During 0-3 wk, average daily gain (ADG), average daily feed intake (ADFI) and feed efficiency (G/F ratio) were not significantly different among treatments. However, pigs fed LAA or SHA diet showed improved ADG by 15 or 13% respectively and 12% greater ADFI in both treatments compared to CON diets. Moreover, compared to organic acid treatments, better ADG (p = 0.07) and ADFI (p = 0.09) were observed in SHA diet compared to pigs that were fed the diet containing organic acids (FUA, FOA or LAA). However, during 4-5 wk, no differences in ADG, ADFI and G/F ratio were observed among treatments. Overall, ADG, ADFI and G/F ratio were not affected by acidifier supplementation. Although it showed no significant difference, pigs fed LAA or SHA diets showed numerically higher ADG and ADFI than pigs fed other treatments. In metabolic trial (Exp II), 15 pigs were used to evaluate the effect of acidifier supplementation on nutrient digestibility. The digestibility of dry matter (DM), crude protein (CP), crude fat (CF), crude ash (CA), calcium (Ca) and phosphorus (P) was not improved by acidifier supplementation. Although the amount of fecal-N excretion was not different among treatments, that of urinary-N excretion was reduced in acidsupplemented treatments compared to CON group (p = 0.12). Subsequently, N retention was improved in acid-supplemented groups (p = 0.17). In anatomical trial (Exp III), the pH and $Cl^-$ concentrations of digesta in gastrointestinal (GI) tracts were not affected by acidifier supplementation. No detrimental effect of intestinal and lingual (taste bud) morphology was observed by acidifier supplementation particularly in inorganic acid treatment. In white blood cell assay (Exp IV), 45 pigs were used for measuring white blood cell (WBC) counts. In all pigs after LPS injection, WBC counts had slightly declined at 2 h and kept elevating at 8 h, then returned to baseline by 24 h after injection of lipopolysaccharide (LPS). However, overall WBC counts were not affected by acidifier supplementation. In conclusion, there was no difference between organic and inorganic acidifier supplementation in weanling pigs' diet, however inorganic acidifier might have a beneficial effect on growth performance and N utilization with lower supplementation levels. Furthermore, inorganic acidifier had no negative effect on intestinal measurements and white blood cell counts in weanling pigs. These results suggested that inorganic acidifier might be a good alternative to organic acidifiers in weanling pigs.

Nb doped strontium titanate single crystal growth by floating zone method (Floating zone법에 의한 Nb를 첨가한 strontium titanate 단결정 성장)

  • Jeon, Byong-Sik;Cho, Hyun;Orr, Keun-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.3
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    • pp.215-222
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    • 1995
  • Nb doped strontium titanate single crystals were grown by the floating zone method. The doping amount of $Nb_2O_5$ was 0.2 wt %. Those crystals were grown in air and N z atmosphere and the growth rate was 5 mmlhr and rotation speed of upper and lower shaft was 30 rpm. The shapes of melt - feed rod interface depending on sintering temperatures were observed. In air atmosphere, the flow rate of air was 1.5 ${\ell}/min$ and in $N_2$ atmosphere, that of $N_2$ gas was 0.5 ${\ell}/min$. As grown crystals were analyseQ by XRD, Laue back - reflection and chemical etching. After annealing in $N_2$ atmosphere, resistivities of crystals were measured and the activation energies of each samples were calculated.

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Effects of Rice Straw Compost Application on Exchangeable Potassium in Long-term Fertilization Experiments of Paddy Soils

  • Kim, Myung-Sook;Park, Seong-Jin;Lee, Chang-Hoon;Ko, Byong-Gu;Yun, Sun-Gang
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.2
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    • pp.194-199
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    • 2016
  • In an experiment conducted at the research field of the National Institute of Agricultural Science, we investigated the effects of mineral fertilizer and rice straw compost on exchangeable potassium and K balances, and rice grain yield under a rice single system. The treatments were no fertilization (No fert.), inorganic fertilization (N), inorganic fertilizer (N, P, K) plus rice straw compost at rates of 7.5, 15.0, 22.5, and $30.0ton\;ha^{-1}$ (NPKC7.5, NPKC15.0, NPKC22.5, and NPKC30.0, respectively). The inorganic fertilizers(N, P, K) were added with standard fertilizer application rate in which nitrogen (N), phosphate ($P_2O_5$), and potassium ($K_2O$) were applied with $75{\sim}150kg\;ha^{-1}$, $70{\sim}86kg\;ha^{-1}$, $75{\sim}86kg\;ha^{-1}$, respectively. Exchangeable potassium for NPKC15.0 NPKC22.5, and NPK30.0 treatments was higher by $0.05{\sim}0.19cmol_c\;kg^{-1}$ than that of NPKC7.5 treatment. Increasing levels of rice straw compost resulted in an increase in the K balance from - $19.9kg\;ha^{-1}yr^{-1}$ (No fert.) to $41.9kg\;ha^{-1}yr^{-1}$ at NPKC22.5 treatment and $62.9kg\;ha^{-1}$ at NPKC30.0 treatment. Continuous application of rice straw compost with NPK fertilizers affected significantly the rice grain yields. The result of the study imply that the application of more than $22.5ton\;ha^{-1}$ of rice straw compost with NPK fertilizers are recommended as the best fertilization practice for enhancement of crop production and K supplying power of soil in the continuous rice cropping system.