• Textile Coloration and Finishing
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• v.32 no.4
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• pp.226-231
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• 2020

This study investigated effect of particle sizes of polymer binders for digital textile printing(DTP) pigment inks on touch of fabrics. The polymer binders were synthesized via miniemulsion polymerization of methyl methacrylate(MMA), butyl acrylate(BA), N-ethylolacrylamide(NEA) and methacrylic acid(MAA). The prepared binders were applied to black pigment inks and those black pigment inks were used to dye cotton fabrics. Then, color strength, rubbing fastness, stiffness, surface and bending properties of the dyed fabrics were investigated. Depending on the particle size of the polymer binder used, color strength, friction fastness, stiffness, surface and bending properties change. Generally, the larger the particle size of the polymer binder, the softer properties.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.206.1-206.1
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• 2014

최근 전자 장비의 금속 전도성 패턴 제작에 있어서 직접적인 프린트가 가능한 프린팅 기술이 기존의 복잡한 photolithography 를 대체할 기술로 주목 받고 있다. 이와 함께 금속 전도성 패턴 제작에 사용되는 고가의 전도성 물질인 Ag ink 및 paste 를 저가의 Cu ink 및 paste 로 대체하기 위한 연구가 진행되고 있다. 하지만 일반적으로 copper 는 대기 중 에서 쉽게 산화되어 높은 저항을 야기시킨다. 따라서 Cu ink 또는 paste 를 제작할 때 copper nanoparticles 을 유기 용매에 분산하여 inert atmosphere에서 합성하거나 [1] copper ink 또는 paste 를 substrate 에 프린트하여 reduction atmosphere 에서 소성시킨다 [2]. 이번 연구에서 Cu paste 를 유리 기판에 screen printing 하여 혼합가스(질소 95%, 수소 5%)와 질소 가스 분위기에서 소성하여 Cu 전극의 소성 거동과 전기적 특성을 분석하였다. 4-point probe를 통해 소성된 Cu 전극의 저항을 측정하여 전도도를 조사하였으며 Thermal Gravimetric Analysis (TGA), Fourier Transform Infrared(FTIR)를 통해 소성된 Cu 전극의 유기물 분해가 전도도에 미치는 영향을 분석하고 Field Emission Scanning Electron Microscopy (FESEM)과 High Resolution Transmission Electron Microscopy (HRTEM)을 통해 Cu nanoparticles 의 grain growth가 전도도에 미치는 영향을 조사하였다.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.47 no.5
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• pp.141-146
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• 2015

This study was carried out to elucidate the partial substitutability of SB latex with environmental-friendly coating binders for coated paper. Starch-based biobinder, ethylene vinyl acetate and acryl-based binder were evaluated for this purpose. Several combinations of above binders were applied to top layer coating, and properties of coating colors and printability were evaluated. When 20% and 30% of SB latex were substituted by acryl-based synthetic binder, ethylene vinyl acetate and biobinder, the brightness, whiteness and opacity of coated paper were similar to those obtained from SB latex. Ink set and stiffness of coated paper manufactured through 20% and 30% substitution of SB latex by biobinder and EVAc were improved, but dry- and wet-pick strength were decreased. The research works on the improvement of dry- and we-pick strength, mechanical stability and rheological properties at high shear condition should be continued for the commercial application of biobinder, EVAc and acryl-based binder.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.42 no.1
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• pp.26-34
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• 2010

Effects of drying condition (IR radiation) on the optical properties and the printability of coated paper were elucidated at various latex sizes and low and high coating color concentrations. It was found that the smaller latex provided better rheology and higher dry and wet pick strength than the larger one. The high solids coating resulted in higher paper gloss and smaller roughness than the low solids coating, even though the clay addition was reduced by 20 parts in the high solids coating. Increasing IR radiation prohibited binder migration into the base paper. Thus it improved binder distribution and decreased pores in the coated layer, resulting in the increased dry and wet pick strength and the improved printing gloss. On the other hand, the color trapping and ink set-off was impaired with increasing IR radiation. Print mottle index passed through a maximum with increasing IR radiation.

• Textile Coloration and Finishing
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• v.35 no.4
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• pp.196-205
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• 2023

Water-dispersed pigment is on-going study for without air pollution in the textile and print industry. Primer treatment is essential for the substrate to improve the printing quality of eco-friendly water-dispersed pigment ink. Otherwise in the case of untreated primer, the water-dispersed pigment ink will dry onto the surface and cause defective images. This study was conducted on film substrate coating (primer) to fix eco-friendly water-dispersed pigment ink on film substrate. The drying, bleeding, and color strength of the pigment ink were examined depending on the composition and mixing ratio of the coating solution. The mixing ratio of silica gel in the coating film is increased to 0, 0.5, 1, 2 and 3 and results that DK-1-3 of silica gel ratio of 1 showed the lowest bleeding such as 52%, the letter thickness of 0.76mm and DK-1-5 of SG ratio of 3 showed the highest bleeding such as 304%, the letter thickness of 2.02mm. The mixing ratio of SPA in the coating film is increased to 2.5, 5, 7.5, SPA ratio of 7.5 has a bleeding ratio of 9% and letter thickness of 0.544mm. It showed the closest value to 0.5mm. According to the result, the optimal mixing ratio of binder, polymer coagulant, silica gel is 100:7.5:1.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.4.1-4.1
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• 2011

Recently, circuit printing technology has been considered as a promising alternative to conventional PCB fabrication, for it can greatly reduce the manufacturing costs. Even though printed circuit has many advantages over typical subtractive technology such as fewer processes, it has some disadvantages. The major problems are low adhesion and poor resolution. Efforts to overcome these problems have been mainly focused on ink developments with a limited success. And surface treatments showed some improvements. Therefore, various plasma treatments and primer coatings on plastic substrates have been tested. Plasma treatments using hydrocarbon gases including methane and propane improved the pattern quality of the inkjet printed circuit, which are further improved upon heating of substrate. On the other hand, there is little effect on the adhesion, which is improved only by a special primer coating. The adhesion of inkjet printed circuit has been increased more than 10 times upon treatment. As for the screen printed circuits, the overall effects are less significant since there is some organic binder in the ink. Nonetheless, the treatment has strong positive effects on pattern quality and adhesion. The adhesion of 1 kgf/cm2, which is comparable with those of the conventional PCB circuits, is possible through primer coating for both screen and inkjet printed circuits. The resulting circuit also showed good thermal, mechanical and electrical properties.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2011.04a
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• pp.327-338
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• 2011

This study was carried in order to manufacture the high quality coated paper. High quality includes not only properties of coated paper but also final print quality. In this study, new acrylic-styrene emulsion was polymerized in laboratory and compared with styrene-butadiene latex. Low-shear viscosity of coating color was decreased with increasing acrylic-emulsion dosage. WRV was increased with addition and decreased with substitution of acrylic-emulsion. Paper gloss, brightness and whiteness were increased and PPS and opacity was slightly decreased with acrylic-emulsion. Ink gloss was increased with using No. 3 acrylic-emulsion due to lower ink setting properties. However No.1, 2 emulsion shows opposite situation. Surface strength of coated paper was increased with using No. 3 acrylic-emulsion These results indicate that high quality coated paper can be manufactured with using No. 3 acrylic-emulsion.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.47 no.5
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• pp.127-133
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• 2015

Recent worldwide trends are to develop the environmental friendly chemicals and processes in order to reduce the global warming and climate change phenomena. One of similar efforts in paper industry is to substitute the petroleum-based SBR latex by starch-based biobinder. The disadvantage of biobinder found through laboratory scale study was the lower dry pick strength than SBR latex. The objective of this study is to confirm the substitutability of SBR latex with biobinder through mill trial. Although biobinder itself gave lower dry pick strength, it was found that the use of SBR latex and biobinder mixture (50:50) could improve the dry pick strength. The introduction of biobinder into coating binder system improved the opacity of coated paper. Optical properties (brightness and whiteness), ink trapping, print gloss and mottling level of paper coated with biobinder system were similar to those of SBR latex.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.43 no.1
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• pp.17-22
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• 2011

The conventional coated paper has many functional problems for printed RFID tag. This study was carried out in order to evaluate the effect of coating color components on conductivity of printed coated paper. It has been well known that the efficiency of printed RFID tag is influenced by surface properties of substrate. The required properties for suitable substrate of printed RFID tag are high smoothness and waterproof property. In this study high grammage base paper surface sized with PVA was used. Coated paper was manufactured with five different formulations. Types of coating pigments and dosage of latex were varied. It was obtained high smoothness and also less binder demand with clay than GCC. On the other hand, suitable surface resistance and smoothness of coated paper for RFID tag was obtained with 20% of latex. Besides it shows the possibility of using coated paper for printed RFID tag.

• Korean Journal of Chemical Engineering
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• v.35 no.12
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• pp.2430-2441
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• 2018

Selenium (Se)-rich binary Cu-Se and In-Se nanoparticles (NPs) were synthesized by a modified heat-up method at low temperature ($110^{\circ}C$) using the gum exudates from a cherry blossom tree. Coating of CISe absorber layer was carried out using Se-rich binary Cu-Se and In-Se NPs ink without the use of any external binder. Our results indicated that the gum used in the synthesis played beneficial roles such as reducing and capping agent. In addition, the gum also served as a natural binder in the coating of CISe absorber layer. The CISe absorber layer was integrated into the solar cell, which showed a power conversion efficiency (PCE) of 0.37%. The possible reasons for low PCE of the present solar cells and the steps needed for further improvement of PCE were discussed. Although the obtained PCE is low, the present strategy opens a new path for the fabrication of eco-friendly CISe NPs solar cell by a relatively chief non-vacuum method.