• 제목/요약/키워드: injection temperature

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Structural and electrical characteristics of IZO thin films deposited on flexible substrate (유연 기판 위에 증착된 IZO 박막의 구조적 및 전기적 특성)

  • Lee, B.K.;Lee, K.M.
    • Journal of the Semiconductor & Display Technology
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    • 제10권2호
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    • pp.39-44
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    • 2011
  • In this study, we have investigated the structural and electrical characteristics of IZO thin films deposited on flexible substrate for the OLED (organic light emitting diodes) devices. For this purpose, PES was used for flexible substrate and IZO thin films were deposited by RF magnetron sputtering under oxygen ambient gases (Ar, $Ar+O_2$) at room temperature. In order to investigate the influences of the oxygen, the flow rate of oxygen in argon mixing gas has been changed from 0.1sccm to 0.5sccm. All the samples show amorphous structure regardless of flow rate. The electrical resistivity of IZO films increased with increasing flow rate of $O_2$ under $Ar+O_2$. All the films showed the average transmittance over 85% in the visible range. The OLED device was fabricated with different IZO electrodes made by configuration of IZO/a-NPD/DPVB/$Alq_3$/LiF/Al to elucidate the performance of IZO substrate. OLED devices with the amorphous-IZO (a-IZO) anode film show better current density-voltage-luminance characteristics than that of OLED devices with the commercial crystalline-ITO (c-ITO) anode film. It can be explained that very flat surface roughness and high work function of a-IZO anode film lead to more efficient hole injection by reduction of interface barrier height between anode and organic layers. This suggests that a-IZO film is a promising anode materials substituting conventional c-ITO anode in OLED devices.

Electro-optical properties of organic EL device (유기 EL 소자의 전기-광학적 특성)

  • Kim, Min-Soo;Park, Lee-Soon;Park, Se-Kwang
    • Journal of Sensor Science and Technology
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    • 제6권4호
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    • pp.252-257
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    • 1997
  • Organic EL devices, which have the sing3e-layer structure of ITO(indium-tin-oxide) /PPV(poly(p-phenylene vinylene))/cathode and the double-layer structure of ITO/PVK (poly(N- vinylcarbazole)) /PPV/cathode, were fabricated and their electro-optical properties were investigated. Experimental results, in single-layer structure, shown that the increment of temperature for thermal conversion of PPV film from $140^{\circ}C$ to $260^{\circ}C$ decreases the maximum luminance from $118.8\;cd/m^{2}$(20V) to $21.14\;cd/m^{2}$(28V) and shift the maximum peak of EL spectrum from 500nm to 580nm. The lower the work function of cathode is, the more the luminance and injection current of device. In double-layer structure, as the concentration of PVK solution decreases from 0.5 wt% to 0.05 wt%, the luminance of device increases from $70.71\;cd/m^{2}$(32V) to $152.7\;cd/m^{2}$(26V).

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An Experimental Study on the Two Stage Ignition of Cool Flame and Hot Flame in HCCI Engine According to Fuel Composition (연료조성에 따른 HCCI 엔진의 냉염 및 열염의 2단연소 특성에 관한 실험적 연구)

  • 이기형;김형민;류재덕;이창식
    • Transactions of the Korean Society of Automotive Engineers
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    • 제12권1호
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    • pp.17-24
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    • 2004
  • As the environmental pollution becomes serious global problem, the regulation of emission exhausted from automobiles is strengthened. Therefore, it is very important to know how to reduce the NOx and PM simultaneously in diesel engines, which has lot of merits such as high thermal efficiency, low fuel consumption and durability. By this reason, the new concept called as Homogeneous Charge Compression Ignition(HCCI) engines are spotlighted because this concept reduced NOx and P.M. simultaneously. However, it is well known that HCCI engines increased HC and CO. Thus, the investigation of combustion characteristics which consists cool and hot flames for HCCI engines were needed to obtain the optimal combustion condition. In this study, combustion characteristics for direct injection type HCCI engine such as quantity of cool flame and hot flame, ignition timing and ignition delay were investigated to clarify the effects of these parameters on performance. The results revealed that diesel combustion showed the two-stage ignition of cool flame and hot flame, the rate of cool flame increase and hot flame decrease with increasing intake air temperature. On the other hand, the gasoline combustion is the single-stage ignition and ignition timing is near the TDC. In addition mixed fuel combustion showed different phenomenon, which depends on the ratio of gasoline component. Ignition timing of mixed fuel is retarded near the TDC and the ignition delay is increased according to ratio of gasoline.

Optimal Design of Fuel-Rich Gas Generator for Liquid Rocket Engine (액체로켓의 농후 가스발생기 최적설계)

  • Kwon, Sun-Tak;Lee, Chang-Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • 제32권5호
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    • pp.91-96
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    • 2004
  • An optimal design of the gas generator for Liquid Rocket Engine (LRE) was conducted. A fuel-rich gas generator in open cycle turbopump system was designed for 10ton in thrust with RP-1/LOx propellant. The optimal design was done for maximizing specific impulse of thrust chamber with constraints of combustion temperature and for matching the power requirement of turbopump system. Design variables are total mass flow rate to gas generator, O/F ratio in gas generator, turbine injection angle, partial admission ratio, and turbine rotational speed. Results of optimal design provide length, diameter, and contraction ratio of gas generator. And the operational condition predicted by design code with resulting configuration was found to maximize the objective function and to meet the design constraints. The results of optimal design will be tested and verified with combustion experiments.

STUDY OF CORRELATION BETWEEN WETTED FUEL FOOTPRINTS ON COMBUSTION CHAMBER WALLS AND UBHC IN ENGINE START PROCESSES

  • KIM H.;YOON S.;LAI M.-C.
    • International Journal of Automotive Technology
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    • 제6권5호
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    • pp.437-444
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    • 2005
  • Unburned hydrocarbon (UBHC) emissions from gasoline engines remain a primary engineering research and development concern due to stricter emission regulations. Gasoline engines produce more UBHC emissions during cold start and warm-up than during any other stage of operation, because of insufficient fuel-air mixing, particularly in view of the additional fuel enrichment used for early starting. Impingement of fuel droplets on the cylinder wall is a major source of UBHC and a concern for oil dilution. This paper describes an experimental study that was carried out to investigate the distribution and 'footprint' of fuel droplets impinging on the cylinder wall during the intake stroke under engine starting conditions. Injectors having different targeting and atomization characteristics were used in a 4-Valve engine with optical access to the intake port and combustion chamber. The spray and targeting performance were characterized using high-speed visualization and Phase Doppler Interferometry techniques. The fuel droplets impinging on the port, cylinder wall and piston top were characterized using a color imaging technique during simulated engine start-up from room temperature. Highly absorbent filter paper was placed around the circumference of the cylinder liner and on the piston top to collect fuel droplets during the intake strokes. A small amount of colored dye, which dissolves completely in gasoline, was used as the tracer. Color density on the paper, which is correlated with the amount of fuel deposited and its distribution on the cylinder wall, was measured using image analysis. The results show that by comparing the locations of the wetted footprints and their color intensities, the influence of fuel injection and engine conditions can be qualitatively and quantitatively examined. Fast FID measurements of UBHC were also performed on the engine for correlation to the mixture formation results.

The study on the variable orifice spray of the steam power plant desuperheater (화력발전설비의 과열증기저감용 가변오리피스 분사 특성)

  • Kim, Jeong-Sik;Kim, Kwang-Hee;Lee, Jong-Sun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • 제14권1호
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    • pp.63-68
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    • 2013
  • The steam power plant is becoming more important to supply a stable power lately. Desuperheater of the steam power plant facility plays a role in maintaining the proper superheat to avoid damage turbine power due to the superheated steam produced in the boiler. In this study, when the steam flows $530^{\circ}C$, 36.7 kg/s, 1.36 MPa in the 460mm pipe, variable orifice nozzle developed in Korea was carried out the performance analysis in coolant injection conditions of $150^{\circ}C$, 4.28 MPa. Findings, steam pipe coolant temperature was maintained at $446^{\circ}C$ and sprayed droplet size was verified by $50{\mu}m$ or less.

Experimental Study of Emission Characteristics for CNG Passenger Car (CNG 승용 자동차의 배출가스 특성에 관한 실험적 연구)

  • Kim, Hyun-jun;Lee, Ho-kil
    • Journal of the Korean Institute of Gas
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    • 제19권6호
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    • pp.34-39
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    • 2015
  • Recently, most of the energy consumed in vehicle is derived from fossil fuels. For this reason, the demand for clean, renewable and affordable alternative energy is forcing the automotive industry to look beyond the conventional fossil fuels. Natural gas represents today a promising alternative to conventional fuels for vehicles propulsion, because it is characterized by a relatively low cost, better geopolitical distribution than oil, lower environmental impact, higher octane number and a higher self ignition temperature. Above all, CNG is an environmentally clean alternative to the existing spark ignition engines with the advantages of minimum change. In this study was installed bi-fuel system that a conventional 2 liters gasoline engine was modified to run on natural gas by a gas injection system. Experiments were mainly carried on the optimization of an ECU control strategy affecting the emission characteristics of CNG/Gasoline bi-fule vehicle. The test results shown that CO2 emission in bi-fuel mode was reduced 16% compared to gasoline fuel in the NEDC mode. Also the amount of CO and HC emissions in bi-fuel and gasoline modes were found to equality. But Compared to gasoline, the bi-fuel mode resulted in higher NOx emissions.

Experimental Study of Hwangginaetak-san on Anti-inflammatory Effect (黃기內托散의 소염 작용에 관한 실험적 연구)

  • Hong, Sung-Jin;Sim, Seug-Yong;Kim, Kyung-Jun
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • 제17권2호
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    • pp.1-11
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    • 2004
  • Objective: Chronic otitis media is an inflammation and infection of the middle ear which is persistent. Chronic otitis media occurs when the eustachian tube becomes blocked repeatedly, multiple infections, ear trauma, or swelling of the adenoids. A chronic ear may be the result of an acute ear infection that does not clear completely, or the result of recurrent ear infections. A chronic ear infection may be more destructive than an acute ear infection because its effects are prolonged, and it may cause permanent damage to the ear. Methods : Experimental animals made use of 4-5 weeks age(weight 20-25g) ICR(male)mouse. In the breeding farm, the lighting time was controlled from 7:00 am until 7:00 pm, the temperature was controlled within $22{\pm}0.5{\circ}$ and water and food were not limited. The extracts which were extracted from Hwangginaetak-san devided low dose group( 1.0g/kg-HN) and high dose group(3.0g/kg-HN), they were intragastrically administered to the mouse of sample A and sample B prior to LPS I.P injection. Compared with inflammation induced group which were induced by LPS, we measured the WBC count, IL-6 level in plasma and TNF-${\alpha}$ level in plasma. Results: 1. Hwangginaetak-san decreased WBC count in inflammatory reaction induced by LPS 2. Hwangginaetak-san decreased IL-6 level in inflammatory reaction induced by LPS. 3. Hwangginaetak-san didn't decreased TNF-${\alpha}$ level in inflammatory reaction induced by LPS Conclusion: According to above results, Hwangginaetak-san was improved its suppression effect to the inflammatory reaction through WBC count and IL-6 level. So Hwangginaetak-san is considered to be used for treatment of chronic otitis media by controlling the WBC count and IL-6 level in plasma.

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Qualitative and Quantitative Analysis of Thirteen Marker Components in Traditional Korean Formula, Samryeongbaekchul-san using an Ultra-Performance Liquid Chromatography Equipped with Electrospray Ionization Tandem Mass Spectrometry

  • Seo, Chang-Seob;Shin, Hyeun-Kyoo
    • Natural Product Sciences
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    • 제22권2호
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    • pp.93-101
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    • 2016
  • For efficient quality control of the Samryeongbaekchul-san decoction, a powerful and accurate an ultra-performance liquid chromatography (UPLC) coupled with electrospray ionization (ESI) tandem mass spectrometry (MS) method was developed for quantitative analysis of the thirteen constituents: allantoin (1), spinosin (2), liquiritin (3), ginsenoside Rg1 (4), liquiritigenin (5), platycodin D2 (6), platycodin D (7), ginsenoside Rb1 (8), glycyrrhizin (9), 6-gingerol (10), atractylenolide III (11), atractylenolide II (12), and atractylenolide I (13). Separation of the compounds 1 - 13 was performed on a UPLC BEH $C_{18}$ column ($2.1{\times}100mm$, $1.7{\mu}m$) at a column temperature of $40^{\circ}C$ with a gradient solvent system of 0.1% (v/v) formic acid aqueous-acetonitrile. The flow rate and injection volume were 0.3 mL/min and $2.0{\mu}L$. Calibration curves of all compounds were showed good linearity with values of the correlation coefficient ${\geq}0.9920$ within the test ranges. The values of limits of detection and quantification for all analytes were 0.04 - 4.53 ng/mL and 0.13 - 13.60 ng/mL. The result of an experiment, compounds 2, 6, 12, and 13 were not detected while compounds 1, 3 - 5, and 7 - 11 were detected with 1,570.42, 5,239.85, 299.35, 318.88, 562.27, 340.87, 12,253.69, 73.80, and $115.01{\mu}g/g$, respectively.

Development of 68Ga-human serum albumin as a PET imaging agent for diagnosis of acute inflammation

  • Lee, Ji Youn;Kim, Hoyoung;Lee, Boeun;Kim, Young Ju;Lee, Yun-Sang;Jeong, Jae Min
    • Journal of Radiopharmaceuticals and Molecular Probes
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    • 제1권2호
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    • pp.104-108
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    • 2015
  • Human serum albumin (HSA) has potential for diagnosis and therapy in clinical setting. The purpose of experiments was to develop and evaluate $^{68}Ga$-HSA as a PET agent for diagnosis of acute inflammation. NOTA-HSA was synthesized by conjugating 2-(p-isothiocyanatobenzyl)-1,4,7-triazacyclononane-1,4,7-triacetic acid to HSA in 0.1 M sodium carbonate buffer (pH 9.5) and then purified using a PD-10 size-exclusion column. NOTA-HSA was labeled with $^{68}Ga$ at room temperature for 10 min, and 8.4% sodium hydrogen carbonate buffer was added for neutralization. $^{68}Ga$-NOTA-HSA was purified using alumina N plus light cartridge and $0.22{\mu}m$ syringe filter. Labeling efficiency and radiochemical purity were determined by ITLC-SG with 0.1 M citric acid. Biodistribution study was performed in a male BALB/c mice model of Carrageenan-induced acute inflammation. Animal PET study was performed in acute inflammation mice model after tail vein injection of $^{68}Ga$-HSA. This radiotracer showed high labeling efficiency (>99%) around pH 7. Biodistribution study showed higher inflamed footpad uptake than control footpad uptake. Animal PET study revealed 2 times higher uptake on inflamed footpad compared to control footpad. In these experiments, we developed $^{68}Ga$-HSA for acute inflammation PET imaging and evaluated it in a mouse disease model. The results demonstrated that $^{68}Ga$-HSA has potential as a PET imaging agent for diagnosis of acute inflammation.