• Title/Summary/Keyword: injection temperature

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Lean Combustion Characteristics with Hydrogen Addition in a LPG Fuelled Spark Ignition Engine (LPG엔진에서 수소연료 보조분사에 의한 희박연소특성 연구)

  • Oh, Seung-Mook;Kim, Chang-Up;Kang, Kern-Yong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.2
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    • pp.114-120
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    • 2006
  • The basic effects of hydrogen addition for engine performance and emission were investigated in single cylinder research engine. Seven commercial injectors were tested to choose a suitable injector for hydrogen injection prior to its engine implementation. The hydrogen fuel leakage and flow rate were evaluated for each injector and KN3-1(Keihin, CO.) showed the best performance for hydrogen fuel. At the higher excess air ratio(${\lambda}=1.7$, 2.0), the better combustion stability was found with hydrogen addition even though its effect was small at lower excess air ratio (${\lambda}=1.0$, 1.3). Stable operation of the engine was even guaranteed at ${\lambda}=2.0$, if the amount of hydrogen gas was near 15% of total energy. In the lean region, ${\lambda}>1.3$, thermal efficiency was improved slightly while it was not clearly observed at ${\lambda}=1.0$, 1.3. It is considered that, in some cases, high temperature environment due to hydrogen combustion caused further heat loss to surroundings. Except for ${\lambda}=1.0$, with larger amount of hydrogen addition, CO was reduced drastically but it was emitted more at the leaner region. Nitric oxides(NOx) was increased a little more with hydrogen addition at ${\lambda}=1.0$, 1.3. However, at ${\lambda}>1.3$ its relative amount of emission was low. In addition, the amount of NOx was continuously decreased with hydrogen addition, but, at ${\lambda}=2.0$ the amount of NOx was lowered to 1/100 of that of ${\lambda}=1.0$. THC emission was significantly increased as air/fuel ratio was raised to leaner region due to misfire and partial burn.

Numerical Investigation of Factors affecting Photoresist Stripping Process on the ITO Surface using the Spray Method (노즐 분사 방식의 ITO 표면 포토레지스트 박리과정 요인의 수치해석)

  • Kim, Joon Hyun;Lee, Joon Hyuck;Kang, Tae Seong;Joo, Gi-Tae;Kim, Young Sung;Jeong, Byung Hyun;Lee, Dae Won
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.26 no.2
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    • pp.158-165
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    • 2017
  • This study investigated spraying factors applicable to stripper usage. Cyclodextrine, as environment-friendly material, was included in the stripper composition. An efficient spray technology was applied for the Photoresist strip. For industrial applications, stripping requires a temperature below $50^{\circ}C$, a strip time within 50 s, and chemically stable activation. Spraying factors were organized considering many conditions-orifice diameter, working pressure (inlet speed), spray distance, and spray angle. For commercial practicability, the flow rate was limited to 3 L/min. The nozzle parameters were nozzle orifice diameter of 1.8-2.2 mm, spray distance of 40-60 mm, and injection speed of 0.7-1.2 m/s. Through the thermal spray movement of the fluid, the thermal boundary layer for a chemical reaction just above the ITO-glass surface and momentum region for sufficient agitation (above 4 m/s) was achieved.

A Study of $NO_x$ Reduction in Stage Combustion (단계적 연소의 $NO_x$ 저감에 대한 연구)

  • 채재우;전영남;이운영
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.6
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    • pp.1556-1571
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    • 1993
  • Nitrogen oxides ($NO_x$) are air pollutants which are generated from the combustion of fossil fuels. Stage combustion is an effective method to reduce $NO_x$ emissions. The effects of $NO_x$ reduction by stage combustion in a pilot scale combustor(6.6kW) have been investigated using propane gas flames laden with NH$_{3}$ as Fuel-N. The results in this study are follows; (1) $NO_x$ emissions are dependent on the reducing environment of fuel-rich zone regardless of total air ratio. The maximum $NO_x$ reduction is at the stoichiometric ratio of 0.8 to 0.9 in the reducing zone. (2) $NO_x$ reduction is maximum when burnout air is injected at the point where the oxygen in reducing zone is almost consumed. (3) $NO_x$ reduction is dependent upon the temperature of reducing zone with best effect above 950.deg. C in the reducing zone. (4) The fuel stage combustion is more effective to reduce $NO_x$ formation in the wide range of stoichiometric ratio than two stage combustion. (5) The results of this study could be utilized mainly in a design strategy for low $NO_x$ emission from the combustion of high fuel-nitrogen in energy sources ratio than as an indication of the absolute levels of $NO_x$ which can be achieved by stage combustion techniques in large scale facilities.

Quantitative Determination of the Thirteen Marker Components in Banhasasim-Tang Decoction Using an Ultra-Performance Liquid Chromatography Coupled to Electrospray Ionization Tandem Mass Spectrometry (LC-MS/MS를 이용한 반하사심탕 물 추출물 중 13종 성분의 함량분석)

  • Seo, Chang-Seob;Shin, Hyeun-Kyoo
    • Korean Journal of Pharmacognosy
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    • v.47 no.1
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    • pp.62-72
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    • 2016
  • Banhasasim-tang is a well-known traditional Korean herbal formula and has been used clinically for the treatment of gastric disease, including acute and chronic gastritis, diarrhea and gastric ulcers in Korea. In this study, an ultra-performance liquid chromatography-electrospray ionization-mass spectrometer method was developed for the quantitative determination of the 13 marker constituents, homogentisic acid (1), 3,4-dihydroxybenzaldehyde (2), spinosin (3), liquiritin (4), baicalin (5), ginsenoside Rg1 (6), liquiritigenin (7), wogonoside (8), ginsenoside Rb1 (9), baicalein (10), glycyrrhizin (11), wogonin (12), and 6-gingerol (13) in Banhasasim-tang decoction. Separation of the compounds 1-13 was using an UPLC BEH $C_{18}$ ($100{\times}2.1mm$, $1.7{\mu}m$) column and column oven temperature was maintained at $45^{\circ}C$. The mobile phase consisted of 0.1% (v/v) formic acid in water (A) and acetonitrile (B) by gradient elution. The injection volume and flow rate were $2.0{\mu}L$ and 0.3 mL/min, respectively. Calibration curves of the compounds 1-13 were showed with $r^2$ values ${\geq}0.9908$. The limit of detection and limit of quantification values of the compounds 1-13 were 0.04-1.11 ng/mL and 0.13-3.33 ng/mL, respectively. Among the these compounds, the compounds 1-3 were not detected, while the compounds 4-13 were detected in the ranges of $3.20-107,062.98{\mu}g/g$ in Banhasasim-tang sample.

General Pharmacology of SB-31$\circledR$ (SB-31$\circledR$의 일반약리작용)

  • 박우규;천혜경;권경자;윤여생;신화섭;공재양
    • Biomolecules & Therapeutics
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    • v.5 no.4
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    • pp.369-375
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    • 1997
  • General pharmacological effects of SB-31$^{R}$, the extracts of Pulsatilla koreana, were investigated in mice, rats and guinea-pigs. Intravenous injection of SB-31 (3 and 6 ml/kg) produced almost no effect on central nervous system no effects on the general symptom and behaviors of mice, spontaneous locomotor activity, pentobarbital- induced sleeping time , rotared performance , electroshock and pentylenetertrazole -induced seizures, acetic acid-induced writhing and normal body temperature in mice. SB-31 showed little effects on the spontaneous movement of the isolated ileum and contraction induced by agonists in isolated ileum, suggesting no influence on autonomic nervous system. Administration of SB-31 also did not show any effect on blood pressure in conscious rats. However, a slight decrease in heart rate was observed at high doses (6 and 10 ml/kg) of SB-31 in conscious rats. Similarly, a slight increase in respiratory rate was observed at 6 m1/kg of SB-31 in anesthetized rats. SB-31 did not produce any effect at the dose of 3 ml/kg, but showed a tendency to increase the urinary volume at 6 ml/kg, and produced a decrease in urinary excretions of N $a_{+}$and $K_{+}$at 6 ml/kg. However, transport capacity within the gastrointestinal tract and the secretion of the gastric juice were not influenced by 6 ml/kg of SB-31. In conclusion, these results suggest that SB-31 did not pro-duce any acute effects on the central nervous system, autonomic nervous system, respiratory and circulatory systems, digestive system and kidney function at the dose of below 3 ml/kg.ml/kg.

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Combustion and Spray Characteristics of Jet in Crossflow in High-Velocity and High-Temperature Crossflow Conditions (고온고속기류 중에 수직 분사되는 액체제트의 연소 및 분무특성)

  • Yoon, Hyun Jin;Ku, Kun Woo;Kim, Jun Hee;Hong, Jung Goo;Park, Cheol Woo;Lee, Choong Won
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.1
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    • pp.67-74
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    • 2013
  • A jet in a crossflow (JICF) has been extensively studied because of its wide applications in technological systems, including fuel injection into a ram-combustor. However, in the case of insufficient mixing performance of the liquid jet into the crossflow, the flame in a ram-combustor is unstable. In this study, the nonuniform flame and combustion instabilities due to lack of mixing performance were experimentally investigated. By performing correlations to predict the penetration height and break-up point, the spray and mixing characteristics of JICF have been studied. In particular, the improved correlations of penetration height are proposed in two distinctive domains depending on the X/d location of the crossflow.

Simultaneous Determination of Haloperidol and Its Metabolite, Reduced Haloperidol, in Plasma by Gas Chromatography Using Nitrogen Phosphorous Selective Detection (Gas Chromatography-Nitrogen Phosphorous Selective Detection을 이용한 혈장중 Haloperidol 및 대사체인 Reduced Haloperidol의 동시정량)

  • Park, Kyoung-Ho;Lee, Min-Hwa;Shim, Chang-Koo;Lee, Myung-Gull;Park, Jong-Sei
    • Journal of Pharmaceutical Investigation
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    • v.22 no.3
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    • pp.197-204
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    • 1992
  • A gas chromatographic method using nitrogen phosphorous selective detection was developed for simultaneous determination of haloperidol and its metabolite, reduced haloperidol, in human plasma. Combelen was used as internal standard, The method involved extraction and trimethylsilylation followed by the injection of $2-4\;{\mu}l$ of benzene layer, which was used to dissolve the trimethylsilylated derivatives of haloperidol and reduced haloperidol, onto SE-54 column [5% phenyl methyl silica fused capillary column, $16m{\times}0.22\;mm$ $(I.D.){\times}0.33\;{\mu}m$ (coated thickness)]. The temperature of column oven was programmed from $200^{\circ}C\;to\;300^{\circ}C$ at the increase rate of $10^{\circ}C/min and also the temperatures of injector and detector were set at $300^{\circ}C$. Helium was used as carrier gas and its flow rate was maintained at 30 ml/min. The detection was conducted with nitrogen phosphorous selective detector. The retention times for combelen, reduced haloperidol and haloperidol were found to be 9.14, 9.75 and 9.99 min, respectively. The detection limits for haloperidol and reduced haloperidol in human plasma were both 0.2 ng/ml. The coefficients of variation of the intra-assay were generally low (below 9.8%). The mean absolute recoveries of added haloperidol and reduced haloperidol from plasma were 72% and 84%, respectively. No interferences from endogenous substances were found.

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The Microdetermination of Ascorbic acid in Blood by Gas-Liquid Chromatography (혈액중(血液中) Ascorbic acid 의 Gas-Liquid Chromatography 에 의(依)한 미량정량(微量定量))

  • Lee, Joong-Hee
    • Applied Biological Chemistry
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    • v.18 no.1
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    • pp.52-55
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    • 1975
  • A microdetermination of Ascorbic acid (AsA) in blood by Gas-Liquid Chromatography (GLC) was studied. AsA was applied on GLC after the conversion into trimethylsilyl derivative (TMS) and the GLC was available for the only reduced form of AsA. A calibration curve is made by GLC of TMS-AsA as the internal standard of n-docosane. The minimum amount of AsA required for the determination was 0.5ml of 1 mg% pyridine solution. Prior to the conversion of AsA in serum into TMS derivative, serum was lyophilized and then it was allowed to stand at room temperature with TMS reagents for 48 hr. On injection of the supernates of TMS derivative to GLC the peak corresponding to AsA was not detected. Its reason why the concentration of AsA in serum is $0.5mg{\sim}0.8mg%$ in general, and it is less than minimum concentration of GLC. In case of L-AsA 1 mg was added to 1ml of serum, which was followed by lyophilization, silylation and GLC. The recorvery of AsA added was 98 percentage.

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Degasser for Products Produced Using Research to Improve the Quality (제품생산 시 탈가스 장치를 이용한 품질향상에 관한 연구)

  • Kang, Seog Joo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.8
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    • pp.4713-4716
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    • 2014
  • Several methods that have been used to manage a degasing process in recent years, such as an injection method that uses aluminum molten metal powder and chemicals, and the input method that supplies argon and nitrogen, or chlorine gas using a gas blow-tube. On the other hand, these methods have some problems, and it is a difficult process to handle pollution due to the production of considerable toxic gases, such as chlorine and fluoride gas, irregular effects, and lowering work efficiency due to the excessive processing time. The problems that are most fatal are the production of considerable sludge due to a reaction of aluminum molten metal with chemicals, loss of metals, and the decreasing life of refractory materials. To solve these problems, this study developed a technology that is related to continuous casting of molten aluminum metal and monolithic degasing apparatus.

Estimation of FDS Prediction Performance on the Operation of Water-Mist (미세물분무 작동에 대한 FDS 예측 성능 평가)

  • Ko, Gwon Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.8
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    • pp.4809-4814
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    • 2014
  • The aim of the present study was to estimate the prediction performance of a FDS (Fire Dynamic Simulator) to simulate the fire behaviors and suppression characteristics by operating a water-mist. Rosin-Rammler/log-normal distribution function was used to determine the initial droplet distribution of water-mist and the effects of its model constant were considered. In addition, the simulation models were validated by a comparison of the predicted fire suppression characteristics with water-mist injection pressures to the previous experiments, and the thermal flow behaviors and gaseous concentration variations were analyzed. The results showed that water-mists with the same mean diameter were affected by the characteristics of the droplet size distribution, which have different size and velocity distributions at the downstream location. The fire simulations conducted in this study determine the initial droplet size distribution tuned to the base of the spray characteristics measured by previous experiments. The simulation results showed good agreement with the previous measurements for temperature variations and fire suppression characteristics. In addition, it was confirmed that the FDS simulation with a water-mist operation supplies useful details on estimations of the thermal flow fields and gaseous concentration under water mist operation conditions.