• Title/Summary/Keyword: injection temperature

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On the Crystal Growth of Gap by Synthesis Solute Diffusion Method and Electroluminescence Properties. (합성용질확산법에 의한 GaP결정의 성장과 전기루미네센스 특성)

  • Kim, Seon-Tae;Mun, Dong-Chan
    • Korean Journal of Materials Research
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    • v.3 no.2
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    • pp.121-130
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    • 1993
  • The GaP crystals were grown by synthesis solute diffusion method and its properties were investigated. High quality single crystals were obtained by pull-down the crystal growing ampoule with velocity of 1.75mm/day. Etch pits density along vertical direction of ingot was increased from 3.8 ${\times}{10^4}$c$m^{-2}$ of the first freeze to 2.3 ${\times}{10^5}$c$m^2$ of the last freeze part. The carrier concentration and mobilities at room temperature were measured to 197.49cc$m^2$/V.sec and 6.75 ${\times}{10^{15}}$c$m^{-3]$, respectively. The temperature dependence of optical energy gap was empirically fitted to $E_g$(T)=[2.3383-(6.082${\times}{10^{-4}}$)$T^2$/(373. 096+TJeV. Photoluminescence spectra measured at low temperature were consist with sharp line-spectra near band-gap energy due to bound-exciton and phonon participation in band edge recombination process. Zn-diffusion depth in GaP was increased with square root of diffusion time and temperature dependence of diffusion coefficient was D(Tl = 3.2 ${\times}{10^3}$exp( - 3.486/$k_{\theta}$T)c$m^2$/sec. Electroluminescence spectra of p-n GaP homojunction diode are consisted with emission at 630nm due to recombination of donor in Zn-O complex center with shallow acceptors and near band edge emission at 550nm. Photon emission at current injection level of lower than 100m A was due to the band-filling mechanism.

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A Study on the Emissions Characteristics of a LPG Vehicle According to Various Test Modes and Ambient Conditions (다양한 시험모드와 환경조건에 따른 LPG 차량의 배출특성 연구)

  • Lee, Min-Ho;Ha, Jong-Han
    • Journal of the Korean Institute of Gas
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    • v.19 no.4
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    • pp.1-7
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    • 2015
  • As the interest on the air pollution is gradually rising up at home and abroad, automotive and fuel researchers have been working on the exhaust emission reduction from vehicles through a lot of approaches, which consist of new engine design, innovative after-treatment systems, using clean (eco-friendly alternative) fuels and fuel quality improvement. This research has brought forward various main issues : whether PM emissions should be regulated for diesel and gasoline vehicles and whether gasoline and LPG powered vehicles can be further neglected from PM emission inventories. Finally, the greenhouse gas regulation has been discussed including automotive emission regulation. The greenhouse gas and emissions of automotive had many problem that cause of ambient pollution, health effects. Based on various test modes and ambient conditions, this paper discusses the characteristics of LPG on exhaust emissions and greenhouse gases. Also, this paper assessed emission characteristics due to the test temperature. These test temperature were performed by dividing the temperature of the test mode and the lowest local temperature in winter. Through this study, the correlation of vehicle test mode and ambient condition, exhaust emission, greenhouse gas emission was analyzed.

Synthesis of Thermosensitive and Biodegradable Methoxy Poly(ethylene glycol)-Polycaprolactone and Methoxy Poly(ethylene glycol)-Poly(lactic acid) Block Copolymers (온도감응 및 생분해성 폴리에틸렌 글리콜-폴리카프로락톤과 폴리에틸렌 글리콜-폴리락타이드 공중합체의 합성)

  • 서광수;박종수;김문석;조선행;이해방;강길선
    • Polymer(Korea)
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    • v.28 no.3
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    • pp.211-217
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    • 2004
  • The sol to gel transition of aqueous solution of block copolymers consisting of methoxy poly (ethylene glycol) (MPEG) and biodegradable polyesters such as $\varepsilon$-caprolactone and L-lactide was investigated as a function of temperature. MPEG-PCL was prepared by ring opening polymerization of $\varepsilon$-caprolactone in the presence of HClㆍEt$_2$O as monomer activator at room temperature. Also, MPEG-PLLA was prepared by ring opening polymerization of L-lactide in the presence of stannous octoate at 115$^{\circ}C$. The properties of block copolymers were investigated by $^1$H-NMR, IR, and GPC as well as the observation of thermo sensitive phase transition in aqueous solution. As the hydrophobic block length increased, the sol to gel transition temperature increased and curve of that steepen to lower concentration. To confirm the gel formation at body temperature, we observed the formation of gel in the mice body after injection of 20 wt% aqueous solution of each block copolymer. After surging, we investigated the gelation in mice. The results obtained in this study confirmed the feasibility as biomaterials of injectable implantation for controlled release of drug and protein delivery.

Effect of Process Gas and Burner Gas Temperature on Reaction and Thermal Deformation Characteristics in a Steam Reformer (증기 개질기의 반응 및 열변형 특성에 미치는 공정가스와 버너가스 온도의 영향)

  • Han, Jun Hee;Kim, Ji Yoon;Lee, Jung Hee;Lee, Seong Hyuk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.126-132
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    • 2016
  • This study numerically investigates the characteristics of chemical reactions and thermal deformation in a steam reformer. These phenomena are significantly affected by the high-temperature burner gas and the process gas conditions. Because the high temperature of the burner gas ranges from 800 to 1000 K, the reformer tubes undergo substantial thermal deformation, eventually resulting in structural failure. Thus, it is necessary to understand the characteristics of the reaction and thermal deformation under the operating conditions to evaluate the reformer tubes for sustainable, stable operation. Extensive numerical simulations were carried out using commercial CFD code (ANSYS FLUENT/MECHANICA Ver. 13.0) while considering three-dimensional turbulent flows and combined heat transfer including conduction, convection, and radiation. Structural analysis considering conjugated heat transfer between solid tubes and fluid flows was conducted using the Fluid-Solid Interaction (FSI) method. The results show that when the injection temperature of the process gas and burner gas decreased, the hydrogen production rate decreased significantly, and thermal deformation decreased by at least 15 to 20%.

The Design and Fabrication of RESURF type SOI n-LDMOSFET (RESURF type의 SOI n-LDMOSFET 소자 설계 및 제작)

  • Kim, Jae-Seok;Kim, Beom-Ju;Koo, Jin-Gen;Koo, Yong-Seo;An, Chul
    • Proceedings of the IEEK Conference
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    • 2004.06b
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    • pp.355-358
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    • 2004
  • In this work, N-LDMOSFET(Lateral Double diffused MOSFET) was designed and fabricated on SOI(Silicon-On-Insulator) substrate, for such applications as motor controllers and high voltage switches, fuel injection controller systems in automobile and SSR(Solid State Rexay)etc. The LDMOSFET was designed to overcome the floating body effects that appear in the conventional thick SOI MOS structure by adding p+ region in source region. Also, RESURF(Reduced SURface Field) structure was proposed in this work in order to reduce a large on-resistance of LDMOSFET when operated keeping high break down voltage. Breakdown voltage was 268v in off-state ($V_{GS}$=OV) at room temperature in $22{\mu}m$ drift length LDMOSFET. When 5V of $V_{GS}$ and 30V of $V_{DS}$ applied, the on resistance(Ron), the transcon ductance($G_m$) and the threshold voltage($V_T$) was 1.76k$\Omega$, 79.7uA/V and 1.85V respectively.

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Development of an Ejector System for Operation of Chemical Lasers (II) - Optimal Design of the Second-Throat Type Annular Supersonic Ejector - (화학레이저 구동용 이젝터 시스템 개발 (II) - 이차목 형태의 환형 초음속 이젝터 최적 설계 -)

  • Kim Sehoon;Jin Jungkun;Kwon Sejin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.10
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    • pp.1231-1237
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    • 2004
  • Determination of geometric design parameters of a second-throat type annual supersonic ejector is described. Tested geometric parameters were primary nozzle area ratio, cross-sectional area of second-throat, L/D ratio of second-throat and primary flow injection angle. Varying these four geometric parameters, we build a test matrix made of 81 test conditions, and experimental apparatus was fabricated to accommodate them. For each test condition, the stagnation pressure of primary flow and the static pressure of the secondary flow were measured simultaneously along with their transition to steady operation and finally to unstarting condition. Comparing the performance curve of every case focused on starting pressure, the unstarting pressure and the minimum secondary pressure, we could derive correlations that the parameters have on the performance of the ejector and presented the optimal design method of the ejector. Additional experiments were carried out to find effects of temperature and mass flow rate of the secondary flow.

Morphological Aspects of Water Treeing in $Co^{60}$ $\gamma$-ray Irradiated Polyethylene ($Co^{60}$ $\gamma$-선으로 조사된 Polyethylene에서 수트리 현상의 구조적 측면에 관한 연구)

  • Lee, B.W.;Kim, J.T.;Koo, J.Y.;Ryu, B.H.
    • Proceedings of the KIEE Conference
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    • 1991.11a
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    • pp.435-438
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    • 1991
  • This work is aimed to clarify the effect of only crosslinking of polyethylene on the water tree propagation and thus the crosslinking of LDPE was made by use of $Co^{60}$ $\gamma$-ray irradiation at room temperature. For this purpose, before water tree testing under same test conditions, injection molded samples were made of LDPE using CNRS laboratory model and also some of them were irradiated under different dose rate for crosslinking. Afterwards, the aged specimens were put into microscopic investigation as a mean to compare their different morphological aspects by use of SEM for the fractured surface. The SEM observation points out that the untreed region in the irradiated PE shows the densed structure whereas that in the LDPE is not closely packed. Also in the water treed region of LDPE, the density and the dimension of voids are higher than those in irradiated PE. Based on our results, it seems that the difference in the PE structure could sufficiently contribute to cause the different water tree propagation of these materials.

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A Study on The Reduction of Fuel Oil Consumption for Fishing Boat Engine (어선기관의 연료유 절감에 관한 연구)

  • 이창호
    • Journal of Advanced Marine Engineering and Technology
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    • v.5 no.1
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    • pp.12-19
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    • 1981
  • As the fuel oil cost covers from 45% to 60% of the total expenditure for fishing boat operation, the energy saving is now an urgent problem to be taken a countermeasure for engineers, manufacturers or specialists engaging in this field. Undertaking a second-hand engine of the trainging ship, the author made several reconstructions to restore its performances. By inserting foot linears of connecting rods the compression ratio was increased and by adjusting both the fuel injection timing and the cooling water outlet temperature, its thermal efficiency was improved. The results of the experimental operation were summarized as follows. 1. By raising the piston top position 0.75mm more than the value of the operating manual, the compression pressure increased 1.3 kg/$cm^2$ and the maximum pressure did 3.4 kg/$cm^2$ at 75% load. 2. At 75% load, the difference of the maximum pressure between each cylinder was decreased from 2.4 kg/$cm^2$ to 1.8 kg/$cm^2$. 3. The fuel consumption was decreased about 8 g/ps.h at 75% load, and about 5.3 g/ps.h at 85% load. 4. The brake thermal efficiency was improved about 1.5% at 75% load and 0.9% at 85% load.

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A Study on Characteristic of NO Reduction by High Level O2Gas in Selective Non-Catalystic Reaction (High Level O2배가스중 NO 저감에 대한 선택적비촉매환원 반응특성에 관한 연구)

  • 이강우;정종현;오광중
    • Journal of Environmental Science International
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    • v.11 no.6
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    • pp.577-582
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    • 2002
  • Selective catalytic reduction and selective non-catalytic reduction processes are mainly used to treat nitrogen oxidants generated from fossil-fuel combustion. Especially, the selective non-catalytic reduction process can be operated more economical and designed more simply than the selective catalytic reduction. For this reason, many researchers carried out to increase the removal efficiency of nitrogen oxidants in the condition of low oxygen concentration by using the selective non-catalytic reduction process. However, this study was flue gas contained high oxygen concentration of 20(v/v%) with ammonia as a reducing agent. Moreover, it carried out experiment with many factors that are reaction temperature, retention time, initial NO concentration, NSR(normalized stoichiometric ratio). It was determined optimal operating conditions to improve NO removal efficiency with SNCR process. The De-NOx efficiency was increased with NSR, initial NO concentration and retention time increasement. This study has NO removal efficiency over 80% in the high oxygen concentration as well as low oxygen concentration. The injection of reducing agent may be considered for SNCR process and facility operation in 850$\^{C}$ of optimal condition.

Experimental Study on Heat Release in a Lean Premixed Dump Combustor using OH Chemiluminescence Images (희박 예혼합 덤프 연소기에서 OH 자발광을 이용한 열 방출에 관한 실험적 연구)

  • Moon, Gun-Feel;Lee, Jong-Ho;Jeon, Chung-Hwan;Chang, Young-June
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1146-1151
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    • 2004
  • Measurements of OH chemiluminescence in an atmospheric pressure, laboratory-scale dump combustor at equivalence ratios ranging from 0.63 to 0.89 were reported. The signal from the first electronically excited state of OH to ground state was detected through a band-pass filter with an ICCD. The objectives of this study are two: One is to see the effects of equivalence ratio on global heat release rate and local Rayleigh index distribution. To get the local Rayleigh index distribution, the line-of-sight images were inverted by tomographic method, such as Abel de-convolution. Another aim is to investigate the validity of using OH chemiluminescence acquired with an ICCD as a qualitative measure of local heat release. For constant inlet velocity and temperature, the overall intensities of OH emission acquired at different equivalence ratio showed periodic and higher value at high equivalence ratio. OH intensity averaged over one period of pressure increased exponentially with equivalence ratio. Local Rayleigh index distribution clearly showed the region of amplifying or damping the combustion instability as equivalence ratio increased. It could provide an information/insights on active control such as secondary fuel injection. Finally, local heat release rate derived from reconstructed OH images were presented for typical locations.

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