• 제목/요약/키워드: initial surface absorption

검색결과 80건 처리시간 0.028초

방식도막에 있어서 물의 흡수에 관한 연구 (A study on the water absorption in protective coatings)

  • 박진환
    • 전기화학회지
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    • 제1권1호
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    • pp.55-59
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    • 1998
  • 방식도막의 수명에 가장 큰 영향을 미치는 물의 흡수과정을 quartz crystal microbalance법 및 임피던스 원리를 이용하여 연구하였다. 도막에 있어서 물의 흡수량과 전해질 농도 변화에 따른 도막의 capacitance를 조사하였다 방식도막에 대한 물의 흡수는 삼투압 작용에 의해서 이루어지고, 흡수 초기단계에서는 도막두께가 얇을수록 흡수량이 많은 것을 알 수 있었다 그리고 도막을 구성하고 있는 수지의 종류 및 결합 가교밀도에 따라서 흡수성이 큰 영향을 받는다는 것을 알 수 있었다. 또한 방식도막에 있어서는 접촉하는 전해질 용액의 농도 변화에 따라 흡$\cdot$탈수 현상이 발생하였으며, 같은 종류의 도막이라도 도막두께가 얇을수록 탈수현상에 따른 capacitance의 증가폭이 큰 것으로 나타났다

지방산 Langmuir-Bledgett막의 광이성화에 관한 연구 (A Study on the Photoisomerization of Langmuir-Bledgett Films of Fatty Acid)

  • 박근호
    • 한국응용과학기술학회지
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    • 제16권3호
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    • pp.193-198
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    • 1999
  • Maxwell displacement current(MDC) measuring technique has been applied on the study of monolayers of fatty acid. The displacement current was generated from monolayers on the water surface by monolayer compression and expansion. Displacement current was generated when the area per molecule was about $130{\AA}^2$. MDCs were investigated in connection with monolayer compression cycles. It was found that the current pulses were generated over the entire range of molecular area, and the maximum of MDC appeared at the molecular area just before the initial rise of surface pressure in compression cycles. We investigated the change in absorption spectra of the fatty acid(8A5H) monolayer LB film due to cis-trans photoisomerization. It was found that the absorption spectrum of the 8A5H LB film was induce to photoisomerization by alternate irradiation with UV and visible light irradiation.

표면 성상에 따른 수용성 발수제 혼입 시멘트 모르타르의 발수특성 (Water Repellent Characteristics According to the Surface Properties of Cement Mortar Mixed with Water-soluble Water Wepellent)

  • 강석표;강혜주;홍성욱;양승현
    • 한국구조물진단유지관리공학회 논문집
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    • 제24권6호
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    • pp.42-49
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    • 2020
  • 본 논문은 시멘트계 재료의 표면 및 구체에 소수성을 부여하여 내구성을 향상시키기 위한 기초연구이다. 실란/실록산계 혼합형 발수제를 첨가한 시멘트 모르타르를 제조하고 초기 수화성능 및 유동성능, 재령별 압축강도를 측정하였다. 또한 표면연마 전후의 물접촉각 및 흡수율을 측정하였다. 실란/실록산계 혼합형 발수제를 첨가한 시멘트 모르타르의 플로우는 발수제 첨가량 1.5%까지는 감소하는 것으로 나타났으며 첨가량 3.0%에서는 증가하였다. 실란/실록산계 혼합형 발수제를 첨가할 경우 시멘트 페이스트의 응결시간은 초결 및 종결 모두 지연되는 것으로 나타났다. 압축강도는 발수제의 최대 첨가량 3.0%에서 최대 30%까지 감소하는 것으로 나타났다. 실란/실록산계 발수제를 시멘트 모르타르에 첨가할 경우 접촉각은 커지는 것으로 나타났으며, 표면연마 후 접촉각은 표면연마 전보다 커지는 것으로 나타났다. 실란/실록산계 혼합형 발수제의 첨가는 표면뿐만 아니라 연마로 인하여 손상된 표면과 단면에서도 소수성을 나타내었다. 실란/실록산계 혼합형 발수제를 시멘트 모르타르에 첨가할 경우 흡수율은 낮아지는 것으로 나타났으며, 표면연마 후 흡수율은 표면연마 전보다 커지는 것으로 나타났다.

Performance improvement of countercurrent-flow membrane gas absorption in a hollow fiber gas-liquid membrane contactor

  • Ho, Chii-Dong;Sung, Yun-Jen;Chen, Wei-Ting;Tsai, Feng-Chi
    • Membrane and Water Treatment
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    • 제8권1호
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    • pp.35-50
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    • 2017
  • The theoretical membrane gas absorption module treatments in a hollow fiber gas-liquid membrane contactor using Happel's free surface model were obtained under countercurrent-flow operations. The analytical solutions were obtained using the separated variable method with an orthogonal expansion technique extended in power series. The $CO_2$ concentration in the liquid absorbent, total absorption rate and absorption efficiency were calculated theoretically and experimentally with the liquid absorbent flow rate, gas feed flow rate and initial $CO_2$ concentration in the gas feed as parameters. The improvements in device performance under countercurrent-flow operations to increase the absorption efficiency in a carbon dioxide and nitrogen gas feed mixture using a pure water liquid absorbent were achieved and compared with those in the concurrent-flow operation. Both good qualitative and quantitative agreements were achieved between the experimental results and theoretical predictions for countercurrent flow in a hollow fiber gas-liquid membrane contactor with accuracy of $6.62{\times}10^{-2}{\leq}E{\leq}8.98{\times}10^{-2}$.

배합률의 변화에 의한 MORTAR의 초음파 흡수현상 (A Study on the Absorption Phenomena of Ultrasonic Exergy in the Mortar with different Mixing Ratio of Sand to Cement)

  • 전춘생;홍봉식
    • 전기의세계
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    • 제25권6호
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    • pp.74-80
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    • 1976
  • The temperature rise of the mortars while are being irradiated by ultrasonic waves and immersed in a liquid medium, are measured. The mixing ratios of sand to cement are varied for the different mortars. The results of the experiment are as follows, 1. The temperature rise of the mortar is decreased as themixing ration (S/C) is increased. 2. Thd temperature rise of the specimen is increased as its length is increased. 3. The surface conditions, either smooth or rough, may not have much influence on the temperature rise of the mortar. 4. The initial slope of temperature rise may not have much effect of the viscosity of liquid. The results, describes above, appear well coincide with the theory that the temperature rise is attributed mainly to the absorption heating. Since the absorption heating of the mortars varies with the mixing ratios of sand to cement, the strength of them would be estimated by means of irradiation of ultrasonic waves on the specimen.

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금속수소화물 수소저장 용기 내부의 열 및 물질전달 현상에 대한 수치적 연구(I) - $LaNi_5$ 베드를 이용한 수소 흡장반응 해석 모델 개발 (Numerical analysis of the coupled heat and mass transfer phenomena in a metal hydride hydrogen storage reactor(I) - Model development of analyzation for hydrogen absorption reaction using the $LaNi_5$ bed)

  • 남진무;주현철
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.225.1-225.1
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    • 2010
  • Within recent years attention has been focused on the method of hydrogen storage using metal hydride reactor due to its high energy density, durability, safety and low operating pressure. In this paper, a numerical study is carried out to investigate the coupled heat and mass transfer process for absorption in a cylindrical metal hydride hydrogen storage reactor using a newly developed model. The simulation results demonstrate the evolution of temperature, equilibrium pressure, H/M atomic ratio and velocity distribution as time goes by. Initially, hydrogen is absorbed earlier from near the wall which sets the cooling boundary condition owing to that absorption process is exothermic reaction. Temperature increases rapidly in entire region at the beginning stage due to the initial low temperature and enough metal surface for hydrogen absorption. As time goes by, temperature decreases slowly from the wall region due to the better heat removal. Equilibrium pressure distribution appears similarly with temperature distribution for reasons of the function of temperature. This work provides a detailed insight into the mechanism and corresponding physicochemical phenomena in the reactor during the hydrogen absorption process.

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Monitoring of III-V semiconductor surface by In-situ Surface PhotoAbsorption

  • Kim, T. J.;Kim, Y. D.;H. Hwang;E. Yoon
    • 한국진공학회지
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    • 제12권S1호
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    • pp.79-82
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    • 2003
  • We present the investigation on P- and As-desorption process from the (001) InP surface in metal organic chemical vapor deposition using surface photoabsorption (SPA). The monochromatic SPA signal showed rapid initial increase to reach In-stabilized surface value after $PH_3$ was turned off, but in case of As-desorption, the signal showed clear existence of a metastable state after the $AsH_3$ was turned off. The SPA spectra at each stable surfaces were taken to confirm the interpretation. This result indicates that the As-desorption process should be understood as a two-step process, in contrast to P-desorption of one-step process.

흡착보양재 적용에 따른 실내 오염물질 초기제어 성능에 관한 연구 (A Study on Initial Control Performance of the Adsorption Protector for Construction Surface about Contaminant)

  • 허정용;최창호;이윤규
    • 설비공학논문집
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    • 제21권4호
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    • pp.229-235
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    • 2009
  • In a domestic construction field, floor surface must be covered not to be scratched and polluted by protector until resident comes in. However this protector restricts the contaminant to leave from floor surface. So when the protector is removed, much contaminant is emitted from the floor surface to inside and makes a bad influence on the indoor air quality, In this research, it will be tested the reduction performance of contaminant between a normal protector and a contaminant absorption protector using charcoal powder.

나노초 가시광 레이저 펄스를 이용한 사파이어 미세천공 공정의 해석 (Analysis of Sapphire Microdrilling by a Nano Second Visible Laser Pulse)

  • 오부국;정영대;김남성;김동식
    • 한국레이저가공학회지
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    • 제12권1호
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    • pp.7-13
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    • 2009
  • Engineering ceramics as sapphire are widely used in industry owing to their superior mechanical and corrosion properties. However, micromachining of sapphire is a considerable challenge due to its transparency. Recently, direct ablation of sapphire has been demonstrated with a visible laser pulse at sufficiently high laser intensity. In this work, the theoretical model for pulsed laser ablation of sapphire is suggested and numerical analysis is carried out using the model. Sapphire ablation begins with plasma generation by the laser interaction with surface defects, impurities and contaminations in the initial stage of machining. Subsequent absorption of the visible laser beam can be explained by three mechanisms: metalization of sapphire surface due to the EUV radiation from the hot plasma, increments of surface roughness and temperature-dependent absorption coefficient. Comparison of the computation results with experimental observation indicates that the proposed model of sapphire is reasonable.

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계면활성제가 포함된 삼성분계 해석을 통한 마란고니 대류 발생 연구 (Onset of Marangoni Convection in a Ternary Mixture with Surfactant)

  • 김제익;강용태;최창균
    • 설비공학논문집
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    • 제15권11호
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    • pp.964-969
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    • 2003
  • The objective of this study is to investigate the effect of surfactant on the onset of Marangoni convection adapting a non-linear surface equation of state. The surface tension gradient with respect to the absorbate concentration, ${\gamma}$, is linearly related to the surface concentration of a surfactant with a coeffcient $x_{A}$. The numerical results show that the role of the initial surfactant concentration to Marangoni instability changes from the stabilizer to the destabilizer depending on the change of the sign of $x_{A}$ from negative to positive. It is concluded that for $x_{A}$>0 there is a critical modified Marangoni number of surfactant $M_{Ac}$ $^{*}$ above which liquid layer is always unstable against long wave disturbances.rbances.