• Title/Summary/Keyword: initial surface absorption

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Pretreatment condition Optimization of Hydrolysis and Water Absorption Behavior of PET Fibrous Assembly (전처리 조건에 따른 PET 섬유 집합체의 가수분해 및 흡수성 거동 연구)

  • Lee, Jun-Hee;Lee, Kwang-Woo;Seo, Mal-Yong;Kang, Ji-Man;Kim, Book-Sung
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.88-88
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    • 2012
  • Applied decanol and nonanol provided more weight loss than applied heptanol and octanol. PET using decanol showed the highest weight loss than other alcohols applied. Sodium hydroxide caused weight loss in PET fabrics because terephthalic acid and ethylene glycol were separated by the hydrolysis of the ester group in the PET chains. The terephthalic acid was neutralized to disodium terephthalate and the reaction results in weight loss in the PET fabrics. The weight loss increased with increasing hydrolysis time because disodium terepthalate was water soluble and the reaction was not reached at equilibrium. Pretreatment alcohols increased water absorption, especially in case of PET applied decanol revealed the highest water absorption. PET applied decanol showed 400% of initial water absorption, and PET applied nonanol revealed 250% of initial water absorption. However, the pristine PET showed 90% initial water absorption, and it revealed 230% maximum water absorption as compared to other alcohols. Also, PET applied decanol, nonanol, octanol and heptanol showed 600%, 400%, 350% and 300% maximum water absorption, respectively. The result implied alcohol length affected on water absorption of PET fibrous assembly. This implies that the microvoid of the PET surface hold water molecules. Surface morphology of PET appears that the pretreatment reagent attacks almost entire surface of the fiber, causing surface etching. As the surface etching progresses, it propagates inside the fiber, resulting in the formation of elongated cavities on the surface.

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Rock wool wastes as a supplementary cementitious material replacement in cement-based composites

  • Lin, Wei-Ting;Cheng, An;Huang, Ran;Wu, Yuan-Chieh;Han, Ta-Yuan
    • Computers and Concrete
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    • v.11 no.2
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    • pp.93-104
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    • 2013
  • The use of rock wool waste, an industrial by-product, in cement-based composites has positive effects on the environment because it reduces the problems associated rock wool disposal. The experiments in this study tested cement-based composites using various rock wool waste contents (10, 20, 30 and 40% by weight of cement) as a partial replacement for Portland cement in mortars. The pozzolanic strength activity test, flow test, compressive strength test, dry shrinkage test, absorption test, initial surface absorption test and scanning electron microscope observations were conducted to evaluate the properties of cement-based composites. Test results demonstrate that the pozzolanic strength activity index for rock wool waste specimens is 103% after 91 days. The inclusion of rock wool waste in cement-based composites decreases its dry shrinkage and initial surface absorption, and increases its compressive strength. These improved properties are the result of the dense structure achieved by the filling effect and pozzolanic reactions of the rock wool waste. The addition of 30% and 10% rock wool wastes to cement is the optimal amount based on the results of compressive strength and initial surface absorption for a w/cm of 0.35 and 0.55, respectively. Therefore, it is feasible to utilize rock wool waste as a partial replacement of cement in cement-based composites.

End Use Tactile Property of the Split-type Nylon/PET Microfiber Fabrics (마찰과 세탁에 의한 극세섬유 직물의 표면과 촉감변화에 관한 연구)

  • 오경화;윤재희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.3_4
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    • pp.539-545
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    • 2004
  • In this study, the effect of washing, bleaching, and abrasion on tactile and the water absorption properties of the split-type Nylon/Polyester (N/P) microfiber pile-knit was investigated under various enduse conditions. We examined the water absorption and surface properties of PET microfiber which will be very useful in the future. We also studied the variations of their performance during usage caused by friction and repeated washing, regard to all kinds of physical, chemical changes which will appear while using those textiles. Progress in further splitting of PET microfiber fabric is observed with increases in the number of washing and bleaching cycles, and treatment temperature. Initial water absorption (%) was increased with progress in splitting, which provided efficient capillary channel. Surface properties were varied with additional splitting by washing and abrasion. Formation of pilling and splitting by abrasion increase surface roughness, diminishing tactile property, and reduced water absorption property. The current results from this study is expected to provide the appropriate washing management guide to consumers, and to inform end-use performance of product to a producer for improving product quality.

Numerical Analysis of Heat and Mass Transfet in the Absorbent By Surfactant Addition (계면활성제첨가에 의한 흡수용액내의 열 및 물질이동해석)

  • ;;Heo Boo, Back Mok
    • Journal of the Korean Society of Safety
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    • v.6 no.3
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    • pp.40-49
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    • 1991
  • To better understand the phenomena inside an absorber, where heat and mass transfer coexist, this study selected the most baslc absorption model from in whifh water vapor is absorbed on the surface of a stationary lithium bromide absurbent solution. The purpose of this study is to obtain basic knowledge of heat and mass transfer processes as affected by Marangoni convection induced by addition of surfactant. We apply a non-flowing bulk absorption model and assume that dropwise surfactant is fixed on the absorbent surface. Four governing equation-continuity, laminar monentum, energy and diffusion are solved numerically to obtain temperature and concentraion distributions during steam absorption with Marangonl convection.. In conclusion, Sh and Nu genrally increase at the initial absorption stage.

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Effect of Bead Shape in Aluminum Crash Box for Effective Impact Energy Absorption Under Low- Velocity Impact Condition (저속충돌조건에서 효과적인 충돌에너지흡수를 위한 알루미늄 크래쉬 박스의 비드형상 효과)

  • Lee, Chan-Joo;Lee, Seon-Bong;Ko, Dae-Cheol;Kim, Byung-Min
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.10
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    • pp.1155-1162
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    • 2012
  • The purpose of this study is to investigate the effects of the bead shape on the crash performance of an aluminum crash box under a low-velocity impact condition. The initial peak load and impact energy absorption of a crash box with three types of bead shapes-edge concave, surface convex, and surface concave type-were studied through an FE analysis and an experiment. In addition, the effects of the bead shapes on the crash performance of the crash box were verified through a low-velocity-impact test with a front side member assembled with an aluminum crash box. The initial peak load of the surface-concave-type crash box was reduced by the bead, and therefore, deformation of the front side member at initial contact could be prevented. Furthermore, there was no deformation of the front side member after the impact test because the crash box with a surface-concave-type bead absorbed all the impact energy.

EFFECTS OF VARIOUS SURFACE TREATMENTS FOR TITANIUM ON SURFACE MICRO ROUGHNESS, STATIC WETTABILITY, FIBRONECTIN ADSORPTION (표면 처리 방법에 따른 타이타늄의 미세 표면 거칠기, 표면 젖음성, fibronectin 흡착량에 미치는 영향)

  • Shin Hwa-Sub;Kim Young-Su;Shin Sang-Wan
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.4
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    • pp.443-454
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    • 2006
  • Purpose: This study aims to get the fundamental data which is necessary to the development direction of implant surface treatment hereafter, based on the understanding the surface structure and properties of titanium which is suitable for the absorption of initial tissue fluid by researching effects of additional surface treatments fir sandblasted with large git and acid-etched(SLA) titanium on surface micro-roughness, static wettability, fibronectin adsorption Materials and Method: In the Control groups, the commercial pure titanium disks which is 10mm in diameter and 2mm in thickness were treated with HCI after sandblasting with 50$\mu$m $Al_2O_3$. The experiment groups were made an experiment each by being treated with 1) 22.5% nitric acid according to SLA+ASTM F86 protocol, 2) SLA+30% peroxide, 3) SLA+NaOH, 4) SLA+ Oxalic acid, and 5) SLA+600$^{\circ}C$ heating. In each group, the value of Ra and RMS which are the gauges of surface roughness was measured, surface wettability was measured by analyzing with Sessile drop method, and fibronectin adsorption was measured with immunological assay. The significance of each group was verified by (SPSS, ver.10.0 SPSS Inc.) Kruskal-Wallis Test. (α=0.05) And the correlation significance between Surface micro-roughness and surface wettability. surface roughness and fibronectin adsorption, and surface wettability and fibronectin adsorption was tested by Spearman's correlation analysis. Result: All measure groups showed the significant differences in surface micro-roughness, surface wettability, and fibronectin adsorption. (p<0.05) There was no significance in correlation among the surface micro-roughness, surface wettability, and fibronectin adsorption. (p>0.05) Conclusion: Surface micro-roughness and surface wettability rarely affected the absorption of initial tissue fluid on the surface of titanium.

Durability assessment of self-compacting concrete with fly ash

  • Deilami, Sahar;Aslani, Farhad;Elchalakani, Mohamed
    • Computers and Concrete
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    • v.19 no.5
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    • pp.489-499
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    • 2017
  • Self-Compacting Concrete (SCC) is a new technology capable to flow without segregation or any addition of energy which leads to efficient construction and cost savings. In this study, the effect of replacing the Ordinary Portland Cement (OPC) with Fly Ash (FA) on the strength, durability of the concrete was investigated experimentally, and carbon footprint and cost were also assessed. Four different replacement FA ratios (0%, 20%, 40% and 60%) were used to create four SCC mixes. Standard test methods were used to determine the workability, strength, and durability of the SCC mixes including resist chloride ion penetration, water permeability, water absorption, and initial surface absorption. The axial cube compressive strength tests were performed on the SCC mixes at 1, 7, 14, 28 and 35 days. Replacing the OPC with FA had a significant positive impact on chloride iron penetration resistance and water absorption but had a considerable negative impact on the compressive strength. The SCC mix with 60% FA had 36.7% and 15.8% enhancement in the resistance to chloride ion penetration and water absorption, respectively. Evaluation of the carbon footprint and the cost of each SCC mixes showed the $CO_2$ emissions mixes 1, 2, 3 and 4 were significantly reduced by increasing the FA content from 0% to 60%. Compared with the control mix, the cost of all mixes increased when the FA content increased, but no significant differences were seen between the estimated costs of all four mixes.

Study on CR/SAP Water Swellable Composite for Application of Functional Additives to Improve Water Absorption Rate

  • Seo, Eunho;Lim, Sungwook;Kang, Seungwan;Han, Dongbin;Park, Eunyoung
    • Elastomers and Composites
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    • v.55 no.4
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    • pp.314-320
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    • 2020
  • This study focused on experiments with polyethylene glycol (PEG) and glycidyl methacrylate (GMA), which are functional additives for water-expandable rubber. Polychloroprene rubber (CR)/superabsorbent polymer (SAP) composites were prepared and their cure behaviors, mechanical properties, water absorption rates, and surface morphology were measured based on the functional additives applied. When PEG and GMA were applied to the composites, the water absorption rate increased-including the initial rate-compared to that measured when functional additives were not used. The results also show that PEG has a hydrophilic functional group, which allows it to absorb more water, and GMA acts as a coupling agent between CR and SAP. However, with the introduction of functional additives, the cure rate slowed down and the mechanical properties also decreased.

Experiments on a Regenerator with Thermosyphon for Absorption Heat Pumps (기포 펌프를 적용한 흡수식 열펌프용 고온 재생기의 작동 특성 실험)

  • Park, C.W.;Jurng, J.;Nam, P.W.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.4
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    • pp.463-472
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    • 1996
  • Experiments were carried out to study the operation characteristics of a regenerator with a thermo-syphon pump and a surface-flame burner for a lithium bromide (LiBr)-water absorption heat pump. A cylindrical-shape metal-fiber burner and commercial grade propane were used. The emission of carbon monoxide and nitric oxide was measured by a combustion gas analyzer. Ther regeneration rate of water vapor as a refrigerant was measured. It could be as a reference value showing the performance of the regenerator. The circulation rate of the LiBr-water solution was also measured from both the tanks for the weak-and the strong-solution. Using a refractometer, the LiBr concetration in the solution was calculated from the measured refractory index of the solution. Temperature of the solution and the condensed water was recorded at several points in the experimental apparatus with thermocouples, using a personal computer. This data collecting system for measuring temperature was calibrated with a set of standard thermometers. The generating rate of water vapor as refrigerant increased linearly with heat supplied. It was about 4.0g/s with the heat supplied at a rate of 16,500kcal/h. The circulation rate of LiBr solution also increases with the heat supplied. The difference in LiBr concentrations between the weak and the strong solution was in the range of 1 to 5% when the concentration of the strong solution was about 60%. It was dependent upon both the heat supplied and the circulation rate of the solution. The initial concentration and the level of the LiBr solution in the regenerator were measured and recorded before experiments. The effect of them on the generating rate of water vapor and the circulation rate of the solution was also studied. The generating rate of water vapor was not strongly dependent upon both the level of the LiBr solution and the initial LiBr concentration. However, the concentration difference of the solution increases with the initial level of the LiBr solution.

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Finite Element Inverse Analysis of an S-rail Forming Process with Direct Mesh Mapping Method and Crash Analysis considering Forming Effects (직접격자 사상법을 이용한 S-rail 성형공정의 유한요소 역해석 및 성형효과를 고려한 충돌해석)

  • Kim, Seung-Ho;Huh, Hoon
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2002.05a
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    • pp.125-128
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    • 2002
  • The automotive industry have made an effort to reduce the weight of vehicle structures with increased safety, while initial model of the final product does not contain any prehistoric effects in a design stave. It takes lots of time to calculate forming effects that have great influences on the energy absorption of structures. In this paper, finite element inverse analysis is adopted to calculate forming effects, such as thickness variation and effective plastic strain as well as an initial blank shape with small amount of computation time. Crash analysis can be directly performed after inverse analysis of the forming process without remeshing scheme. The direct mesh mapping method is used to calculate an initial guess from the sliding constraint surface that is extracted from the die and punch set. Analysis results show that energy absorption of structures is increased with consideration of forming effects and finite element inverse analysis is usefully applicable to calculate forming erects of vehicle structures for the crash analysis.

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