• Transactions of the Korean hydrogen and new energy society
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• v.23 no.3
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• pp.256-263
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• 2012

We studied the degradation phenomenon of Pt catalyst in PEMFC. We used the electron microscope analysis technique including the ultra-microtome pretreatment method, FEG-SEM and TEM analysis methods for analysis of Pt nanoparticles. The Pt catalyst degradation is observed not only in electrode site but also in membrane site. We investigated these various degradation phenomena. The cathode electrode layer thickness is reduced. The size of the catalyst is increased much larger than initial size in membrane site. The catalyst moved from electrode layer to the electrolyte membrane. The rounded shape of catalyst was changed to the polygon. As a result, we found that the catalyst degradation processes of migration and coarsening occurred by the followings mechanisms; (1) dissolution of Pt ; (2) diffusion of Pt ion ; (3) Pt ion chemical reduction in membrane; (4) Coarsening of Pt particles (Ostwald ripening) ; (5) polygon shape change of Pt by {111} plane growth.

• Environmental Engineering Research
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• v.23 no.1
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• pp.1-9
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• 2018

The degradation of methylene blue (MB) in an aqueous solution by nano-metallic particles (NMPs) was studied to evaluate the possibility of applying NMPs to remove MB from the wastewater. Scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS) were used to characterize the synthesized NMPs before and after the reaction. The effects of the NMP dosage, the initial pH, the initial concentration of MB and the amount of $H_2O_2$ on the MB degradation outcomes were studied. The highest removal rate of MB was achieved to be 100% with an initial MB concentration of 5 mg/L, followed by 99.6% with an initial concentration of 10 mg/L under the following treatment conditions: dose of NMP of 0.15 g/L, concentration of $H_2O_2-100mM$ and a temperature of $25^{\circ}C$. The SEM analysis revealed that the nano particles were not spherical in shape. FTIR spectra shows occurrence of metal oxides on the surfaces of the NMPs. The XPS analyses results represent that Fe, Zn, N, Ca, C and O were occurred on the surfaces of the NMPs. The degradation of MB was suitable for the pseudo-first-order kinetics.

• Ocean Systems Engineering
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• v.8 no.3
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• pp.247-279
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• 2018

This study aims to investigate the behavioral characteristics of the LWSCR (lazy-wave steel catenary riser) for a turret-moored FPSO (Floating Production Storage Offloading) by using fully-coupled hull-mooring-riser dynamic simulation program in time domain. In particular, the effects of initial geometric profile on the global performance and structural behavior are investigated in depth to have an insight for optimal design. In this regard, a systematic parametric study with varying the initial curvature of sag and arch bend and initial position of touch down point (TDP) is conducted for 100-yr wind-wave-current (WWC) hurricane condition. The FPSO motions, riser dynamics, constituent structural stress results, accumulated fatigue damage of the LWSCR are presented and analyzed to draw a general trend of the relationship between the LWSCR geometric parameters and the resulting dynamic/structural performance. According to this study, the initial curvature of the sag and arch bend plays an important role in absorbing transferred platform motions, while the position of TDP mainly affects the change of static-stress level.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.19 no.2
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• pp.97-102
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• 2020

To prevent vibration of a vehicle's interior parts due to external impacts, the vehicle should be designed to reduce vibration and increase rigidity. In this paper, we conducted a vehicle test in which the vibration characteristics of a seatbelt resulting from the impact of a person closing a car door were measured and analyzed. A correlation analysis was performed using the finite analysis method. Based on this, a sensitivity analysis was performed, and an improved model was designed. We compared the natural frequencies and mode shapes of the improved and the initial models, which confirmed that the natural frequency of the improved model was more than 10 Hz higher than that of the initial model. Moreover, the response frequency of the improved model was three times higher than the input frequency applied in the vehicle test.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.65 no.11
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• pp.1806-1812
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• 2016

We propose an interior permanent magnet syhchronous motor (IPMSM) with arc-shape ferrite permanent magnets (PMs) as a substitute for the rare-earth permanent magnet, and determine its optimal design through parametric study. First, we use 2D finite element analysis to analyze 4-poles and 6-slots initial model according to performance requirements and design parameters. The current angle of the maximum average torque considered in the analysis is different compared with the current angle of the minimum torque ripple. Thus, the parametric study for optimal rotor design is performed by varying the thickness and the offset radius of the PMs according to current angle. In particular, a narrow bridge is required in conventional IPMSM for reducing flux leakage; however, the increase in cogging torque in the analysis model saturates the narrow bridge (large offset radius). Therefore, we suggest an appropriate shape considering limiting conditions such as DC link voltage, average torque, torque ripple, and cogging torque taking into account performance requirements.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.21 no.2
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• pp.317-326
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• 1997

An investigation was performed to study the matrix cracking and delamination in laminated composite plates due to transverse impact. A model was developed for predicting the initiation of the matrix cracking and the shape and size of impact-induced delamination in laminated composite plates resulting from the ballistic impact. The model consists of a stress analysis and a failure analysis. A transient finite element analysis which was based on the higher-order shear deformation theory was adopted for calculating the stresses inside the laminated composite plates during impact. A failure analysis was used to predict the initial intraply matrix cracking and the shape and size of the interface delamination in the laminates. As a results, a shear matrix cracking which was governed by the transverse interlaminar shear stress occured at the middle layer near the midplane of laminates and a bending matrix cracking which was governed by the transverse inplane stress occured at the bottom layer near the surface of laminates. In a thick laminates, a shear matrix cracking generated first at the middle layer of laminates, but in a thin laminates, a bending matrix cracking generated first at the bottom layer of laminates.

• Journal of the Korean Society of Safety
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• v.27 no.3
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• pp.28-35
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• 2012

We investigated the breakdown patterns of silica glass under the various impacts by forensic scientific analysis. The impacts were chosen by thermal and projectiles impact stress. Thermal impacts under the fire were constructed by changing the position of the flame with gas torches. Physical impacts were constructed with the projectiles of slingshots and rifles by changing the size of the projectiles at the surfaces and the initial distance. Also we identified incident angles of the projectiles by analysis of the punching portion at the glass surface. Under the thermal impacts, the breakdown patterns were various by changing the position of the flame. Especially, the configuration of breakdown patterns had radial shape with the position of the flame at the center of the glass sheet. Under the physical impacts by the projectiles, the breakdown patterns had always radial shape.

• Earthquakes and Structures
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• v.22 no.3
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• pp.231-243
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• 2022

Beam-column joints (BCJs) are recognized among the most crucial zones in reinforced concrete structures, as they are the critical elements subjected to a complex state of forces during a severe earthquake. Under such conditions, BCJs exhibit behaviors with impacts that extend to the whole structure and significantly influence its ductility and capability of dissipating energy. The focus of this paper is to investigate the effect of undamaged transverse beam (secondary beams) on the ductility of concrete BCJs reinforced with conventional steel and shape memory alloys bars using pushover analysis at tip of beam under different axial load levels at the column using a nonlinear finite element model in ABAQUS environment. A numerical model of a BCJ was constructed and the analysis outcomes were verified by comparing them to those obtained from previous experiments found in the literature. The comparison evidenced the capability of the calibrated model to predict the load capacity response of the joint. Results proved the ability of undamaged secondary beams to provide a noticeable improvement to the ductility of reinforced concrete joints, with a very negligible loss in load capacity. However, the effect of secondary beams can become less significant if the beams are damaged due to seismic effects. In addition, the axial load was found to significantly enhance the performance of BCJs, where the increase in axial load magnified the capacity of the joint. However, higher values of axial load resulted in greater initial stiffness of the BCJ.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2003.05a
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• pp.221-224
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• 2003

In the open die forging process, it is difficult to optimize process parameters such as die shape, initial ingot size, feeding pitch, rotation angle and other process parameters in the operational environments. Therefore in this study, 3D finite element analysis has been performed to obtain optimal process condition for open die forging process. FEM analyses at various feeding pitches and rotation angles provide process conditions to make round bar having precise dimensional accuracy.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10a
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• pp.733-738
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• 2000

It is difficult to obtain accurate fracture toughness values by RILEM committees proposed three point bend test(TPB) because the shape of load-deflection curve is irregular and final crack propagation occurs after some slow stable cracking. However, for disk test, fracture toughness is easily obtained from crack initial load. We examined the cracked high strength concrete disk and the experimental results were compared with the results by finite element analysis(FEA). Also we compared experimental fracture locus with theoretical fracture locus.