• Title/Summary/Keyword: initial curing temperature

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Adhesion Properties of Urea-Melamine-Formaldehyde (UMF) Resin with Different Molar Ratios in Bonding High and Low Moisture Content Veneers

  • Xu, Guang-Zhu;Eom, Young-Geun;Lim, Dong-Hyuk;Lee, Byoung-Ho;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.2
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    • pp.117-123
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    • 2010
  • The objective of this research was executed to investigate the effect of molar ratio of formaldehyde to urea and melamine (F/(U+M)) of urea-melamine-formaldehyde (UMF) resin on bonding high and low moisture content veneers. For that purpose, UMF resin types with 5 different F/(U+M) molar ratios (1.45, 1.65, 1.85, 2.05, and 2.25) synthesized were used in present study. First, their curing behavior was evaluated by differential scanning calorimetry. Second, their adhesion performance in bonding high and low moisture content veneers was evaluated by probe tack and dry and wet shear strength tests. Curing temperature and reaction enthalpy decreased with the increase of F/(U+M) molar ratio. And the dry and wet shear strengthsof plywood manufactured from low moisture content veneers were higher than thoseof plywood manufactured from high moisture content veneers. Also, the maximum initial tack force on the low moisture content veneer was higher than that on the high moisture content veneer.

Anisotropic Conductive Film (ACF) Prepared from Epoxy/Rubber Resins and Its Fabrication and Reliability for LCD

  • Kim, Jin-Yeol;Kim, Eung-Ryul;Ihm, Dae-Woo
    • Journal of Information Display
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    • v.4 no.1
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    • pp.17-23
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    • 2003
  • A thermoset type anisotropic conductive adhesive film (ACAF) comprising epoxy resin and natural butyl rubber (NBR) as the binder, micro-encapsulated imidazole as the curing agent, and Ni/Au coated polymer bead as a conductive particle has been studied. These films have been prepared to respond to requirements such as improved contact resistance, current status less of than 60 ${\mu}m$ and reliability. These films can also be used for connection between the ITO glass for LCD panel and the flexible circuit board. The curing conditions for the connection were 40, 20 and 15 seconds at 150, 170 and 190 $^{\circ}C$, respectively. The initial contact resistance and adhesion strength were 0.5 ${\Omega}/square$ and 0.4 kg/cm under the condition of 30 kgf/$^{cm}^2}$, respectively. After completing one thousand thermal shock cycling tests between -15 $^{\circ}C$ and 100 $^{\circ}C$, the contact resistance was maintained below 0.7 ${\Omega}/square$. Durability against high temperature (80$^{\circ}C$) and high humidity (85 % RH) was also tested to confirm long-term stability (1000 hrs) of the conduction.

Fundamental Properties of Low-Heat Concrete According to the Mixing Rate of Super Retarding Agent (초지연제 혼입률에 따른 저발열 콘크리트의 양생온도별 기초물성평가)

  • Park, Byoung-Joo;Choi, Yoon-Ho;Hyun, seung-Yong;Kim, Jong;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.06a
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    • pp.90-91
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    • 2020
  • As the construction site has become narrower recently, the importance of mass concrete is naturally being highlighted as skyscrapers become popular. However, it is not possible to install the entire volume per day if the mass concrete is installed due to the Remicon 8⦁5 system and the 52-hour workweek system. When the mass concrete base is divided into several days, cold joints occur because the consolidation of joints is not integrated due to different degree of hardening in the case of the previous layer and the next day. As a result, existing research has shown that if super retarding agent are mixed into Ready Mixed Concrete (hereinafter referred to as Remicon) using sugar as a raw material to delay the curing time of concrete, cold joints are inhibited and cracks are inhibited by reducing the initial hydration heat.

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Effects of Hardeners and Catalysts on the Reliability of Copper to Copper Adhesive Joint (Cu-Cu 접착부의 고온고습 내구성에 미치는 경화제 및 촉매제의 영향)

  • Min, Kyung-Eun;Kim, Hae-Yeon;Bang, Jung-Hwan;Kim, Jong-Hoon;Kim, Jun-Ki
    • Korean Journal of Materials Research
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    • v.21 no.5
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    • pp.283-287
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    • 2011
  • As the performance of microelectronic devices is improved, the use of copper as a heat dissipation member is increasing due to its good thermal conductivity. The high thermal conductivity of copper, however, leads to difficulties in the joining process. Satisfactory bonding with copper is known to be difficult, especially if high shear and peel strengths are desired. The primary reason is that a copper oxide layer develops rapidly and is weakly attached to the base metal under typical conditions. Thus, when a clean copper substrate is bonded, the initial strength of the joint is high, but upon environmental exposure, an oxide layer may develop, which will reduce the durability of the joint. In this study, an epoxy adhesive formulation was investigated to improve the strength and reliability of a copper to copper joint. Epoxy hardeners such as anhydride, dihydrazide, and dicyandiamide and catalysts such as triphenylphosphine and imidazole were added to an epoxy resin mixture of DGEBA and DGEBF. Differential scanning calorimetry (DSC) analyses revealed that the curing temperatures were dependent on the type of hardener rather than on the catalyst, and higher heat of curing resulted in a higher Tg. The reliability of the copper joint against a high temperature and high humidity environment was found to be the lowest in the case of dihydrazide addition. This is attributed to its high water permeability, which led to the formation of a weak boundary layer of copper oxide. It was also found that dicyandiamide provided the highest initial joint strength and reliability while anhydride yielded intermediate performance between dicyandiamide and dihydrazide.

Studies on the changes of main components during the fermentation of Anchvy sauce (멸치젓 발효숙성중 주요성분의 변화)

  • 조영도
    • Journal of the Korean Professional Engineers Association
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    • v.29 no.2
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    • pp.80-90
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    • 1996
  • This research aimed at investigating the changes of volatile basic nitrogen, amino nitrogen and lipids during the fermentation of 6 month Anchovy cured under room temperature with various treatments(20, 30 and 40% salted) and examing the optimum condition of Anchovy sauce. The results are summerized as the V.B.N which increased with the curing period of anchovy from 14 mg% to 90~107mg% in 180 days curing at 20% salt level. Amino nitrogen in minced anchovy was higher than in whole anchovy during fermentation and the content of Extractive Nitrogen in the curing anchovy containing 20% of salt, kept the highest amount in 60 curing days. As a rule, minced anchovy showed more rapidly increased than whole anchovy. The lipid in curing anchovy containing 20% and 30% of salt has already been oxidized in 30 days while the lipid of anchovy cured with 40% salt prolonged the initial stage to 45 days. During fermentation, peroxide value and acid value showed constant increasing, while thiobarbituric acid began to decrease after 120 days curing. Among the non-polar lipids, linolenic acid, linoleic acid and erucic acid was decomposed by 24.5%, 22.2%, and 20.0%, respectively. It was noticed that the decomposition of polar lipid was retarded by higher salt content.

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Fundamental Characteristics of Carbon-Capturing and Sequestering Activated Blast-Furnace Slag Mortar (탄소포집 활성 고로슬래그 모르타르의 기초특성에 관한 연구)

  • Jang, Bong Jin;Kim, Seung Won;Song, Ji Hyeon;Park, Hee Mun;Ju, Min Kwan;Park, Cheolwoo
    • International Journal of Highway Engineering
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    • v.15 no.2
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    • pp.95-103
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    • 2013
  • PURPOSES : To investigate the fundamental characteristics of blast-furnace slag mortar that was hardened with activating chemicals to capture and sequester carbon dioxide. METHODS : Various mix proportions were considered to find an appropriate stregnth development in regards with various dosages of activating chemicals, calcium hydroxides and sodium silicates, and curing conditions, air-dried, wet and underwater conditions. Flow characteristics was investigated and setting time of the mortar was measured. At different ages of 3, 7 and 28days, strength development was investigated for all the mix variables. At each age, samples were analyzed with XRD. RESULTS : The measured flow values showed the mortar lost its flowability as the activating chemicals amount increased in the scale of mole concentration. The setting time of the mortar was relatively shorter than OPC mortar but the initial curing condition was important, such as temperature. The amount of activating chemicals was found not to be critical in the sense of setting time. The strength increased with the increased amount of chemicals. The XRD analysis results showed that portlandite peaks reduced and clacite increased as the age increased. This may mean the $Ca(OH)_2$ keeps absorbing $CO_2$ in the air during curing period. CONCLUSIONS : The carbon capturing and sequestering activated blast-furnace slag mortar showed successful strength gain to be used for road system materials and its carbon absorbing property was verified though XRD analysis.

Application Properties of Slag Concrete in Winter Season (슬래그 활용 콘크리트의 동절기 적용 성능 평가)

  • Yoo, Jo-Hyeong;Kim, Woo-Jae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.52-58
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    • 2017
  • Concrete made with ground granulated blast-furnace slag(GGBS) has many advantage, including improved durability, workability and economic benefits. GGBS concrete is that its strength development is considerably slower under standard $20^{\circ}C$ curing conditions than that of portland cement concrete, although the ultimate strength is higher for same water-binder ratio. GGBS is not therefore used in application where high early age strength is required. In this study, to overcome the limitation of the initial strength decrease due to the use of slag, the slag substitution rate was changed to 30% under the low temperature curing temperature condition and the slag used concrete composition with the same or higher strength performance as OPC(Ordinary Portland Cement).

Effects of Dielectric Curing Temperature and T/H Treatment on the Interfacial Adhesion Energies of Ti/PBO for Cu RDL Applications of FOWLP (FOWLP Cu 재배선 적용을 위한 절연층 경화 온도 및 고온/고습 처리가 Ti/PBO 계면접착에너지에 미치는 영향)

  • Kirak Son;Gahui Kim;Young-Bae Park
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.2
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    • pp.52-59
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    • 2023
  • The effects of dielectric curing temperature and temperature/humidity treatment conditions on the interfacial adhesion energies between Ti diffusion barrier/polybenzoxazole (PBO) dielectric layers were systematically investigated for Cu redistribution layer applications of fan-out wafer level package. The initial interfacial adhesion energies were 16.63, 25.95, 16.58 J/m2 for PBO curing temperatures at 175, 200, and 225 ℃, respectively. X-ray photoelectron spectroscopy analysis showed that there exists a good correlation between the interfacial adhesion energy and the C-O peak area fractions at PBO delaminated surfaces. And the interfacial adhesion energies of samples cured at 200 ℃ decreased to 3.99 J/m2 after 500 h at 85 ℃/85 % relative humidity, possibly due to the weak boundary layer formation inside PBO near Ti/PBO interface.

Setting Time Prediction of Super Retarding Concrete Using Improved Durometer (개량형 듀로미터를 이용한 초지연 콘크리트의 응결시간 분석)

  • Han, Soo-Hwan;Choi, Yoon-Ho;Yeun, Kyu-Won;Kim, Jong;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.06a
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    • pp.73-74
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    • 2020
  • In this study, the feasibility of the durometer into super retarding concrete was studied by comparing the penetration resistance with the hardness of each durometer using the penetration resistance and the improved Durometer and Durometer A-Type according to the ultra-delay mixture rate. The test results showed that initial setting time by improved Durometer and Durometer A-Type were fixed at 25, 50 HD, respectively, and the 35, 80 HD showed at final setting time. It was also found that the use of the durometer can be available to measure the setting time of the concrete.

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Prediction of concrete mixing proportions using deep learning (딥러닝을 통한 콘크리트 강도에 대한 배합 방법 예측에 관한 연구)

  • Choi, Ju-hee;Yang, Hyun-min;Lee, Han-seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.30-31
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    • 2021
  • This study aims to build a deep learning model that can predict the value of concrete mixing properties according to a given concrete strength value. A model was created for a total of 1,291 concrete data, including 8 characteristics related to concrete mixing elements and environment, and the compressive strength of concrete. As the deep learning model, DNN-3L-256N, which showed the best performance on the prior study, was used. The average value for each characteristic of the data set was used as the initial input value. In results, in the case of 'curing temperature', which had a narrow range of values in the existing data set, showed the lowest error rate with less than 1% error based on MAE. The highest error rate with an error of 12 to 14% for fly and bfs.

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