• Title/Summary/Keyword: industrial wastes

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A Study on Acid Recovering Process by Neutralization and Water-Splitting Electrodialysis (WSED) (중화법과 전기투석에 의한 산회수 공정연구)

  • Lee, Hong Joo;Moon, Seung-Hyeon;Park, Sung-Kook;Chun, Hee-Dong
    • Clean Technology
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    • v.3 no.2
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    • pp.74-86
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    • 1997
  • Recently the treatment of industrial wastes by membrane processes has drawn much attention due to increasing demands for clean technology. In the process investigated in this study, metal species in the acidic wastes are precipitated as metal hydroxide forms in a neutralization tank, and acid and base solutions are regenerated by water-splitting electrodialysis(WSED) to be reused in the process. Material balances of the processes for treating pickle liquor and mixed wastewater were calculated to explain conceptual design of the process. Experiments for neutralization precipitation with KOH and NaOH for mixed wastewater were carried out to precipitate metal hydroxide and to recover salt solution as supernatant. Also WSED of the salt solutions producing acid and base was tested in 2 or 3 compartment stacks using KCl and NaCl to investigate the effects of stack configurations on the WSED performance.

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Characterizations of High Early-Strength Type Shrinkage Reducing Cement and Calcium Sulfo-aluminate by Using Industrial Wastes

  • Lee, Keon-Ho;Nam, Seong-Young;Min, Seung-Eui;Lee, Hyoung-Woo;Han, Choon;Ahn, Ji-Whan
    • Journal of the Korean Ceramic Society
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    • v.53 no.2
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    • pp.215-221
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    • 2016
  • In this study, the utilization of the by-products of various industries was examined using raw materials of CSA high-functional cement such as coal bottom ash, red mud, phosphate gypsum, etc. Technology to improve energy efficiency and reduce $CO_2$ was developed as part of the manufacturing process; this technology included lower temperature sintering ($150{\sim}200^{\circ}C$) than is used in the OPC cement manufacturing process, replacement of CSA cement with the main raw material bauxite, and a determination of the optimum mix condition. In order to develop CSA cement, a manufacturing system was established in the Danyang plant of the HANIL Cement Co. Ltd., in Korea. About 4,200 tons of low purity expansion agent CSA cement (about 16%) and about 850 tons of the lime-based expansion agent dead burned lime (about 8%) were produced at a rate of 60 tons per hour at the HANIL Cement rotary kiln. To improve the OPC cement properties, samples of 10%, 13%, and 16% of CSA cement were mixed with the OPC cement and the compressive strength and length variation rate of the green cement were examined. When green cement was mixed with each ratio of CSA cement and OPC cement, the compressive strength was improved by about 30% and the expansibility of the green cement was also improved. When green cement was mixed with 16% of CSA cement, the compressive strength was excellent compared with that of OPC cement. Therefore, this study indicates the possibility of a practical use of low-cost CSA cement employing industrial wastes only.

Gravity, Magnetic and VLF explorations in the ubong industrial waste landfill, Pohang (포항 유봉산업 폐기물 매립지에서의 중력, 자력, VLF 탐사)

  • 권병두
    • Economic and Environmental Geology
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    • v.32 no.2
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    • pp.177-187
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    • 1999
  • Gravity, magnetic and VLF surveys were conducted to investigat the structural stability and hazards associated with the Ubong landfill in Pohang City, which has been built to dump industrial wastes. In 1994, the collapse of a bank happened in the 6th landfill site due to sudden heavy rain, and a large quantity of waste materials flowed out to the nearby landfill sites, factories and roads. We used $10{\times}10m$ resolution DEM data for gravity reductions. The maximum variation of the terrain effect in the survey area is about 0.5 mgal and the terrain effect is large in the vicinity of bank boundary. The Bouguer gravity anomaly map shows the effect due to the variatino of thickness and type of waste materials. The small negative gravity anomaly increases from the 9th site to the 6th site. The small negative gravity anomaly of the 9th site reflects the relatively shallow dumping depth of average 14.5 m in this site and increased density of waste materials by the repeated stabilization process of soil overlaying. The 6th site is located at the center of the former valley and rainfall and groundwater are expected to flow from south-east to north-west. Therefore, considering the previous accident of mixing waste and bank materials at the north-west boundary of the landfill, there may be some environmental problems of leakage of contaminated water and bank stability. The complex inversion technique using Simulated annealing and Marquardt-Levenberg methods was applied to calculate three-dimensional density distribution from gravity data. In the case of 6th site, it is apparent that the landfill had been dumped in four sectors. However, most part of the 9th site and showed that high magnetic industrial wastes were concentrated in the 6th site. The result of magnetic survey showing low magnetic anomalies along the boundaries of two sites is similar to that of gravity data. The VLF data also reveals four divided sectors in the 6th site, and overall anomaly trend indicates the directio of former valley.

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A Study on the Status of Air and Water Pollutants Emission from Industries in Korea (전국(全國) 산업장(産業場)에서 배출(排出)되는 오염물질량(汚染物質量)에 관(關)한 연구(硏究))

  • Cha, Chul-Hwan;Jang, Chang-Supp;Kim, Hyung-Won;Sung, Young-Ja
    • Journal of Preventive Medicine and Public Health
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    • v.6 no.1
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    • pp.27-41
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    • 1973
  • In order to provide some basic data for the control of air and water pollution in Korea, the authors have estimated the amount of air and water pollutants emitted from industries which are employed over 20 employees. This study have done from July 1, 1972 to the end of March 1973. The results are as followings; 1. Total number of establishments with over 20 employees is 5,197 in Korea and the largest group establishments was the manufacturing of textiles with 1,363 establishments (26.2%). 2. By order of number of employees it was observed that there 2,800 industries with 20-59(53.9%) employees, 1,101 with 50-99 (21.2%), 571 with 100-199 (11.0%), 501 with 200-499 (9.6%) and 225 with over 500 (4.3%) respectively. 3. By order of regional distribution, it was observed that there were 2,257 industries in Seoul (43.2%) and 736 industries in Pusan(14.2%). 4. Industrial coal consumption was 596,154 M/T in 1972, but it' 11 be 315,000 M/T in 1980. Fuel consumption was 4,972,000 K1 in 1972, and estimated volume will be 19,370,000 K1 in 1980. 5. Total amounts of air polutants entitled from industries by fuel combustion were sulfur oxides 79,459 tons, carbon monoxide 33,908 tons, particulate 31,304 tons and hydrocarbon 30,280 tons in 1972 but in 1990 there will be sulfur oxides 1,010,474 tons, nitrogen oxides 204,575 tons, carbon monoxide 68,014 tons, particulate 64,820 tons and hydrocarbon 67,622 tons, respectively. 6. Annual emitted air pollutants through the working processes were sulfur oxides 91,250 tons and nitrogen oxides 32,485 tons in 1972, but sulfur oxides 118,625 tons and nitrogen oxides 42,555 tons will be present in 1980, respectively. 7. Annual emitted air pollutants by national unit area amounted to $0.77ton/km^2/year$ in 1965 and $14.7ton/km^2/year$ in 1980. 8. Total industrial wastes from all industries in Korea were estimated at 810,360 tons/day in 1972; manufacturing of chemicals and plastic products showed the highest amount of wastes at 470,000 tons/day. 9. The amounts of water pollutants due to industrial wastes were the B.O.D., 471.5 tons/day, suspended solid 331.5 tons/day, CN, 2.3 tons/day, and Cr. 3.4 tons/day in 1972, but it might be evident of a B.O.D. of 3,388 tons/day, suspended solid 2,544 tons/day, CN 20.1 tons/day, and 26.5 tone/day in 1990. 10. Total population equivalent of B.O.D. was 943,000 in 1972, and the estimated value in 1950 will be 6,780,000.

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Preparation and Mechanical Properties of Bulk Molding Compound Composite Prepared using Recycled FRP Waste Powder (폐FRP 미분말을 재활용한 BMC 복합재료의 제조 및 기계적 물성)

  • Hwang, Eui-Hwan;Jeon, Jong-Ki
    • Applied Chemistry for Engineering
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    • v.21 no.2
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    • pp.217-223
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    • 2010
  • In general, fiber-reinforced plastics (FRP) wastes are simply buried or burned. Landfill brings about a permanent contamination of soil due to the inability of FRP to decompose and incineration causes an issue of generating toxic gases and dusts. There have been several ways to treat the FRP wastes such as landfill, incineration, chemical recycling, material recycling and the utilization of energy from combustion. Most methods excluding material recycling are known to have critical limitations in economic, technical and environmental manners. However it is known that material recycling is most desirable among the methods handling FRP wastes. In this study, to investigate the purpose of feasibility of material recycling, various bulk molding compound (BMC) specimens were prepared with the various contents of unsaturated polyester resin binder (25, 30, 35 wt%) and the various replacement ratios of FRP wastes powder (0, 25, 50, 75, 100 wt%) substituted for filler. To evaluate the physical properties BMC specimens, various tests such as tensile strength, flexural strength, impact strength, hot water resistance and SEM imaging were conducted. As a results, mechanical strengths decreased with an increase of replacement ratio of FRP waste powder and physical properties of BMC specimens were deteriorated in the hot water resistance. The fluidity of BMC with more than 50 wt% of the replacement ratio of FRP wastes powder decreased remarkably, causing a problem in the BMC composite.

Development of a Torrefaction Unit for Food and Agricultural Wastes (음식물·농업폐기물 열분해장치 개발)

  • Song, Dae-Bin;Lim, Ki-Hyeon;Jung, Dae-Hong
    • Journal of agriculture & life science
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    • v.52 no.6
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    • pp.73-79
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    • 2018
  • In this study, a torrefaction unit with a capacity of 50 kg/hr was developed and experimented to produce of solid fuel by reuse of the food and agricultural wastes. Dried food wastes and agricultural wastes were used for the experiments and the heated-air torrefaction characteristics were investigated by the raw materials, torrefaction air temperature, and torrefaction time. For the dried agricultural wastes, measured torrefaction capacity and lower heating values were 55.35 kg/hr and 3,333 kcal/kg, respectively. As the lower heating values of the treated samples were greater, by around 7.8%, than those of the non-treated samples, torrefaction process was a very effective method to increase the heating value of the agricultural waste. In case of the dried food waste, torrefaction capacity and lower heating value was measured 88.27 kg/hr and 4,016 kcal/kg, respectively. As the lower heating value of treated ones showed around 9.0% higher than that of non treated ones, torrefaction process is very effective method to increase the heating value of the agricultural waste also. It will be assumed that the heating value shows more higher as increase the air temperature and decrease the moisture content of torrified matter.

Study of Dynamic Polling in the IEEE 802.11 PCF

  • Kim, Che-Soong;Lyakhov, Andrey
    • Journal of Korean Institute of Industrial Engineers
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    • v.34 no.2
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    • pp.140-150
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    • 2008
  • Point Coordination Function (PCF) of the IEEE 802.11 protocol providing a centrally-controlled polling-based multiple access to a wireless channel is very efficient in high load conditions. However, its performance degrades with increasing the number of terminals and decreasing the load, because of wastes related to unsuccessful polling attempts. To solve the problem, we propose and study analytically the generic dynamic polling policy using backoff concept. For this aim, we develop Markov models describing the network queues changes, what allows us to estimate such performance measures as the average MAC service time and the average MAC sojourn time, to show the dynamic polling efficiency and to tune optimally the backoff rule.

Chemical resistance of Non-Sintered Cement Mortar using Inorganic Industrial Wastes as activator (무기계 산업폐기물을 자극제로 이용한 비소성 시멘트 모르타르의 내화학성)

  • Mun Kyoung Ju;Lee Chol Woong;Park Won Chun;Soh Yang Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.607-610
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    • 2005
  • If cement can be manufactured with industrial byproducts such as granulated blast furnace slag(GBFS), phosphogypsum(PG), and waste lime(WL) instead of clinker as its counterproposal, there would be many advantages, including maximum use of these industrial byproducts for high value-added resources, conservation of natural resources and energy by omitting the use of clinker, minimized environmental pollution problems caused by $CO_2$ discharge, and reduction of the production cost. This research investigates the chemical resistance of NSC mortar added PG and WL to GBFS as sulfate and alkali activators. The result of experiment of chemical resistance, showed that NSC is very excellent in acid resistance and seawater resistanc. Such a reasons are that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.

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Chloride ion Permeability of Non-Sintered Cement Concrete using Inorganic Industrial Wastes as activator (무기계 산업폐기물을 자극제로 이용한 비소성 시멘트 콘크리트의 염소이온 침투 저항성)

  • Mun, Kyoung-Ju;Lee, Chol-Woong;Park, Won-Chun;So, Seung-Young;Soh, Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.453-456
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    • 2006
  • If cement can be manufactured with industrial byproducts such as granulated blast furnace slag(GBFS), phosphogypsum(PG), and waste lime(WL) instead of clinker as its counterproposal, there would be many advantages, including maximum use of these industrial byproducts for high value-added resources, conservation of natural resources and energy by omitting the use of clinker, minimized environmental pollution problems caused by CO2 discharge, and reduction of the production cost. This research investigates the chloride ion permeability of NSC concrete added PG and WL to GBFS as sulfate and alkali activators. The result of experiment of chloride ion permeability, showed that NSC is very excellent in seawater resistance. Such a reasons are that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.

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Korea Recycling Policy for Inorganic Mineral Waste

  • Kim, Mi-Sung;Oh, Jae-Hyun;Ahn, Ji-Whan;Kim, Hwan
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.685-690
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    • 2001
  • Along with the expansion of industrial activities, the quantity of industrial waste sludge is increasing, and the treatment/disposal of wastes is a social problem regarding the preservation of the environment. In particular, recycling the sludge as a raw material is actively required considering the situation of Korea, which is poor in natural resources and energy. Lime is a necessity for treatment of waste sludge, which often can be made recyclable by lime treatment. In this thesis, a brief description has been given of my views on the ordinary treatment of waste sludge and the effective use of inorganic industrial waste sludge focusing on lime.

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