• Title/Summary/Keyword: industrial by products

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Analysis of Reducing Characteristics of Direct Reduced Iron using Blast Furnace Dust

  • Yun, Young Min;Chu, Yong Sik;Seo, Sung Kwan;Jeong, Jae Hyun
    • Journal of the Korean Ceramic Society
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    • v.53 no.4
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    • pp.444-449
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    • 2016
  • Industrial by-products generated by integrated iron and steel manufacture cause environmental pollution. The by-products contain not only iron element but also harmful substances. Therefore, in view of to waste recycling and environmental preservation, production of sponge iron using the by-product is considered an effective recycling method. In this study, reduction efficiency of pellets from blast furnace dust was measured. Metallization was found to be increased, as $C/Fe_{total}$ ratio and reaction time were increased. The pellets were formed into a globular shape, and calcined for 60 minutes at $1100^{\circ}C$ in an electric furnace. Phase changes were analyzed using an X-ray diffractometer. Microstructures of the pellets were observed by a scanning electron microscope.

Modeling the Catalytic Activity and Kinetics of Lipase(Glycerol-Ester Hydrolase)

  • Demirer, Goksel N.;Duran, Metin;Tanner, Robert D.
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.1 no.1
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    • pp.46-50
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    • 1996
  • In order to design industrial scale reactors and proceises for multi-phase biocatalytic reactions, it is essential to understand the mechanisms by which such systems operate. To il-lustrate how such mechanisms can be modeled, the hydrolysis of the primary ester groups of triglycerides to produce fatty acids and monoglycerides by lipased (glycerol-ester hydrolase) catalysis has been selected as an example of multiphase biocatalysis. Lipase is specific in its behavior such that it can act only on the hydrolyzed (or emulsified) part of the substrate. This follows because the active center of the enzyme is catalytically active only when the substrate contacts it in its hydrolyzed form. In other words, lipase acts only when it can shuttleback and forth between the emulsion phase and the water phase, presumably within an interphase or boundary layer between these two phases. In industrial applications lipase is employed as a fat splitting enzyme to remove fat stains from fabrics, in making cheese, to flavor milk products, and to degrade fats in waste products. Effective use of lipase in these processes requires a fundamental understanding of its kinetic behavior and interactions with substrates under various environmental conditions. Therefore, this study focuses on modeling and simulating the enzymatic activity of the lipase as a step towards the basic understanding of multi-phase biocatalysis processes.

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Analysis of Lignans in Acanthopanax sessiliflorus Fruits and Their Fermented Wine by HPLC

  • Kim, Hye-Min;Kim, Ju-Sun;Cho, Seon-Haeng;Kang, Sam-Sik;Cheoi, Dae-Sung;Lee, Sang-Hyun
    • Korean Journal of Medicinal Crop Science
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    • v.14 no.5
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    • pp.289-292
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    • 2006
  • High performance liquid chromatography (HPLC) was used for the determination of lignans, eleutherosides B and E, in Acanthopanax sessiliflorus fruits and their fermented wine. The lignans were quantified by a reversed-phase system using a gradient of $H_2O$ and acetonitrile as a mobile phase within 20 min. The analysis was successfully carried out within 20 min. The contents of eleutherosides Band E as main active principles of Acanthopanax species were measured in A. sessiliflorus fruits (1.15 and $8.49\;{\mu}g/mg$, respectively), their fermented wine (0.45 and $1.33\;{\mu}g/mg$, respectively) and wine residues (no detection).

Analyzing the Evolutionary Stability for Behavior Strategies in Reverse Supply Chain

  • Tomita, Daijiro;Kusukawa, Etsuko
    • Industrial Engineering and Management Systems
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    • v.14 no.1
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    • pp.44-57
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    • 2015
  • In recent years, for the purpose of solving the problem regarding environment protection and resource saving, certain measures and policies have been promoted to establish a reverse supply chains (RSCs) with material flows from collection of used products to reuse the recycled parts in production of products. It is necessary to analyze behaviors of RSC members to determine the optimal operation. This paper discusses a RSC with a retailer and a manufacturer and verifies the behavior strategies of RSC members which may change over time in response to changes parameters related to the recycling promotion activity in RSC. A retailer takes two behaviors: cooperation/non-cooperation in recycling promotion activity. A manufacturer takes two behaviors: monitoring/non-monitoring of behaviors of the retailer. Evolutionary game theory combining the evolutionary theory of Darwin with game theory is adopted to clarify analytically evolutionary outcomes driven by a change in each behavior of RSC members over time. The evolutionary stable strategies (ESSs) for RSC members' behaviors are derived by using the replicator dynamics. The analysis numerically demonstrates how parameters of the recycling promotion activity: (i) sale promotion cost, (ii) monitoring cost, (iii) compensation and (iv) penalty cost affect the judgment of ESSs of behaviors of RSC members.

Effect of Trace Amount of Ca on Corrosion Resistance of Solutionized Mg-4%Zn Alloy (용체화처리된 Mg-4%Zn 합금의 부식 저항성에 미치는 미량 Ca 첨가의 영향)

  • Jun, Joong-Hwan;Hwang, In-Je
    • Journal of the Korean Society for Heat Treatment
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    • v.29 no.4
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    • pp.168-175
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    • 2016
  • Influence of trace amount of Ca addition on the corrosion resistance was comparatively investigated in solutionized Mg-4%Zn and Mg-4%Zn-0.1%Ca alloys. In as-cast state, the alloys were characterized by primary ${\alpha}-(Mg)$ dendrite with MgZn intermetallic compound particles. After solution-treatment, both alloys consisted of single ${\alpha}-(Mg)$ phase by dissolution of the compound particles into the matrix. It was found from the immersion and electrochemical corrosion tests that the Mg-4%Zn alloy had better corrosion resistance than the Mg-4%Zn-0.1%Ca alloy. Morphological and compositional analyses on the surface corrosion products indicate that the incorporation of Ca oxide with low PBR value into the surface corrosion products would be responsible for the decreased corrosion resistance of the Ca-containing alloy.

Pyrolysis of PE plastics in the batch type microreactor (회분식 미분반응기를 이용한 PE계 플라스틱의 열분해특성 연구)

  • Kim, Sang-Hoon;Jang, Hyun-Tae;Cha, Wang-Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.8 no.3
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    • pp.632-638
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    • 2007
  • Pyrolysis experiments of HDPE and LDPE were carried out in the stainless steel reactor of internal volume of 40 $cm^3$. Pyrolysis reactions were performed at temperature $410{\sim}460^{\circ}C$ and the pyrolysis products were collected separately as liquid and gas products. The molecular weight distributions(MWDs) and composition of each product were determined by HPLC-GPC and GC analysis. It was represented that the yield and the molecular weight of liquid product were decreased with the increase of reaction temperature and time. The chain-end scission rate parameters, respectively, were determined to be 63.0kcal/mole of HDPE, 45.7kcal/mole of LDPE by the Arrhenius plot.

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Synthesis and Surface Active Properties of Long Chain N-Acyl Collagen Derivatives (고급 지방산 N-아실 콜라겐 유도체의 합성 및 계면활성)

  • Kim, T.Y.;Nam, K.D.;Nam, S.I.;Ahn, J.H.;Lee, J.H.
    • Journal of the Korean Applied Science and Technology
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    • v.10 no.2
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    • pp.81-90
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    • 1993
  • The Surfactants composed of acylated aterocollagen which is produced by the acylation of the side chain amino radicals of aterocollagen with an aliphatic acid having 12 to 18 carbon atoms will be discussed in this study. This condensation is done at moderate reaction temperature (<$25^{\circ}C$) in aqueous alkaline solution. The products of this reaction were identified by UV/VIS spectroscopy and infrared spectroscopy. For these compounds, surface active properties and physical properties including isoelectric point, Krafft point, surface tension, critical micelle concentration(cmc), foaming power, viscosity behaviour, water holding capacity, skin irritation and emulsifying power were measured respectively. The experimental results received that the products have a good emulsifying power, excellent water holding capacity while having low skin irritation. Thus, these derivatives will be expected to be used as an emulsifying agent for O/W type cosmetic emulsion.

A Simultaneous Delivery and Pick-up Heterogeneous Vehicle Routing Problem with Separate Loading Area (다품종 독립 적재공간을 갖는 배달과 수거를 동시에 고려한 차량경로문제)

  • Kim, Gak-Gyu;Kim, Seong-Woo;Kim, Seong-Woo
    • Journal of Korean Institute of Industrial Engineers
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    • v.39 no.6
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    • pp.554-561
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    • 2013
  • As a special topic of the vehicle routing problems (VRP), VRPSDP extends the vehicle routing problem as considering simultaneous pickup and delivery for goods. The past studies have mainly dealt with a only weight constraint of a loading capacity for heterogeneous products. However. this study suggests VRPSDP considering separate loading area according to characteristics of loading species. The objective is to design a set of minimum distance routes for the vehicle routing assignment with independent capacity for heterogeneous species. And then we present a another HVRPSDP model which is easy to utilizes in a unique circumstance that is a guarantee of executing a task simultaneously from the various areas under restricted time and raising an application of vehicles that returns at the depot for the next mission like the military group. The optimal results of the suggested mathematical models are solved by the ILOG CPLEX software ver. 12.4 that is provided by IBM company.

Internal Defects Inspection of Die-cast Parts via the Comparison of X-ray CT Image and CAD Data (CAD 데이터 및 엑스레이 CT이미지 비교를 통한 다이캐스팅 부품의 내부 결함 검사방법)

  • Hong, Gyeong Taek;Shim, Jae Hong
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.1
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    • pp.27-34
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    • 2018
  • Industrially, die-casting products are formed through casting, and so the methods to inspect the defects inside them are very restrictive. External inspection methods including visual inspection, sampling judgment, etc. enables researchers to inspect possible external defects, but x-ray inspection equipment has been generally used to inspect internal ones. Recently, they have been also applying three-dimensional internal inspections using CT equipment. However, they have their own limitations in applying to the use of industrial inspection due to limited detection size and long calculation time. To overcome the above problems, this paper has suggested a method to inspect internal defects by comparing the CAD data of the product to be inspected with the 3D data of the CT image. In this paper, we proposed a method for fast and accurate inspection in three dimensions by applying x-ray inspection to find internal defects in industrial parts such as aluminum die casting products. To show the effectiveness of the proposed method, a series of experiments have been carried out.

On the Theoretical Solution and Application to Container Loading Problem using Normal Distribution Based Model (정규 분포 모델을 이용한 화물 적재 문제의 이론적 해법 도출 및 활용)

  • Seung Hwan Jung
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.45 no.4
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    • pp.240-246
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    • 2022
  • This paper introduces a container loading problem and proposes a theoretical approach that efficiently solves it. The problem is to determine a proper weight of products loaded on a container that is delivered by third party logistics (3PL) providers. When the company pre-loads products into a container, typically one or two days in advance of its delivery date, various truck weights of 3PL providers and unpredictability of the randomness make it difficult for the company to meet the total weight regulation. Such a randomness is mainly due to physical difference of trucks, fuel level, and personalized equipment/belongings, etc. This paper provides a theoretical methodology that uses historical shipping data to deal with the randomness. The problem is formulated as a stochastic optimization where the truck randomness is reflected by a theoretical distribution. The data analytics solution of the problem is derived, which can be easily applied in practice. Experiments using practical data reveal that the suggested approach results in a significant cost reduction, compared to a simple average heuristic method. This study provides new aspects of the container loading problem and the efficient solving approach, which can be widely applied in diverse industries using 3PL providers.