• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.3371-3376
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• 2007

The design of a ground-source heat pump system includes specifications for a ground loop heat exchanger where the heat transfer rate depends on the thermal conductivity of the ground. To evaluate this heat transfer property, in-situ thermal response tests on four vertical test boreholes with different grouting materials were conducted by adding a monitored amount of heat to water over various test lengths. By measuring the water temperatures entering and exiting the loop, water flow rate, and heat load, effective thermal conductivity values of the ground were determined. The effect of increasing thermal conductivity of grouting materials from 0.82 to 1.05 W/m$^{\circ}C$ resulted in overall increases in effective ground thermal conductivity by 25.8% to 69.5%.

• 공업화학
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• 제10권1호
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• pp.148-153
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• 1999

2-bromoterephthaloyl chloride와 1,4-bis(p-hydroxybenzoyloxy)butane을 PMMA 용액내에서 중축합시켜 in situ 복합재료를 제조하였다. 이들의 합성확인 및 열적, 기계적 성질은 FT-IR, FT-NMR, DSC와 DMTA에 의해서, 몰폴로지는 광학현미경과 SEM을 사용하여 조사하였다. 합성된 TLCP는 네마틱상을 보였고, 복합재료내 PMMA의 유리전이온도와 기계적 성질은 TLCP의 농도증가와 함께 증가하였다. TLCP domain은 PMMA 매트릭스내에서 미세 분산되었음을 확인하였고 in situ 중합에 의해 제조된 20 wt % TLCP/PMMA 복합재료는 같은 조성의 용액 블렌딩에 의해서 제조된 재료보다 더 높은 기계적 강도와 미세 분산도를 보였다.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2008년도 하계학술발표대회 논문집
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• pp.769-775
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• 2008

The objective of this report is to determine the difference of thermal response that grouted two different materials, and compare the simulation result of the length of total ground heat exchanger length that using the ground thermal conductivity. And also to know heat exchange variation of ground heat exchanger temperature that measured with various test depth. The result shows that the test hole grouted with water permeable material got better thermal response than grouted with water impermeable material. However, with consideration of ingnore for the initial 12 hour data, the test hole grouted with impermeable material has larger thermal conductivity than the other. By former thermal conductivity, simulated data by engineering program shows only 3.4% difference or less. This result shows that ground thermal conductivity is not the main variables for the design program of ground heat exchanger. At the cooling or heating mode, base on the depth of -150m, the ground heat exchanger has best temperature at $-90{\sim}-60m$ and than getting worse because of entering water heat exchanged with leaving water in the same hole.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 추계학술대회
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• pp.421-424
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• 2006

Nafion/Pt/Polypyrrole composite membranes were fabricated by chemical in-situ polymerization of pyrrole monomers with Pt precursors in Nafion matrix for DMFC. We demonstrated that positively charged pyrrolinum groups of polypyrrole particles were co-interacted with sulfonic groups of Nafion as verified by FT-IR results. Mutual interaction between $Nafion-SO_3^-$ (or negatively charged Pt precursors) and Polypyrrole$-NH_2^+$ influenced the physical properties of pristine Nafion. Thermal property proton conductivity, methanol permeability, and cell performance of pristine and modified Nafion were analyzed for an application of DMFC membrane. Thermal stabilities of sulfonic groups and side chains in Nafion/Pt/polypyrrole composite membranes were higher than those of Nafion due to mutual interaction between sulfonic groups of Nafion and pyrrolinum groups of polypyrrole. Methanol permeabilities of Nafion/Pt/Polypyrrole composite were reduced more proton conductivities with the increase in the content of Pt particles. As a result of that, the enhancement of cell performance by Nafion/Pt/Polypyrole O2 relative to Nafion was more pronounced under the specific experimental condition such as high temperature and more concentrated methanol solution.

• 토지주택연구
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• 제3권1호
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• pp.83-88
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• 2012

In this study, physical characteristics of cement and/or concrete materials that are typically used for energy-foundation (EF) structures have been studied. The thermal conductivity and structural integrity of the cement-based materials were examined, which are commonly encountered in backfilling a vertical ground heat exchangers, cast-in-place concrete piles and concrete lining in tunnel. For this purpose the thermal conductivity and unconfined compression strength of cement-based materials with various curing conditions were experimentally estimated and compared. Hydration heat generated from massive concrete in the cast-in-place concrete energy pile was observed for 4 weeks to estimate its dissipation time in the underground. The hydration heat may mask the in-situ thermal response test (TRT) result performed in the cast-in-place concrete energy pile. It is concluded that at least two weeks are needed to dissipate the hydration heat in this case. In addition, a series of numerical analysis was performed to compare the effect of thermal property of the concrete material on the cast-in-place pile.

• 터널과지하공간
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• 제9권1호
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• pp.27-35
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• 1999

아치형 공동의 열원 경계에 대한 열전도 특성은 반무한평면이나 원형공동에 대한 열전도 특성과는 다른 양상을 나타낸다. 본 연구에서는 지하 냉동저장 pilot plant 의 운영을 통하여 계측된 저장공동 주위안반내 온도분포패턴의 분석을 통하여 아치형 공동의 열원 경계를 갖는 새로운 열전도식을 유도하였다. 계측된 암반온도 분포패턴은 선형적 변화와 로그함수적 변화의 중간적인 양상을 보였다. 열전파에 미치는 열물성 변수들의 영향도 분석 및 도출된 열전도식과 현장계측에 의한 암반온도 분포양상의 비교를 통하여 암반의 열물성을 추정하였다. 추정된 암반의 열전도도와 비열은 실내시험에 의한 무결 암석의 열물성과 비교해 20~25%의 차이를 보였다. 이는 암반내의 절리와 지하수의 영향에 기인한 것으로 판단되는데, 앞으로 현지암반에 대한 이들 영향요소의 조사와 열물성의 측정 및 비교분석을 통하여 정량적인 상관관계의 규명이 이루어져야 할 것이다.

• 한국세라믹학회지
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• 제37권6호
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• pp.552-558
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• 2000

LiMn2O4 thin fiolm cathodes for Li-ion secondary battery were fabricated by r.f. magnetron sputtering technique. As-deposited films were amorphous. A spinel structure could not be obtained LiMn2O4 films by in-situ thermal annealing. After post thermal annealing over $700^{\circ}C$ in oxygen atmosphere, LiMn2O4 films prepared above 100 W r.f. power could be crystallized into a spinel structure. The electrochemical property of the LiMn2O4 film cathodes was tested in a Li/1 M LiClO4 in PC/LiMn2O4 cell. From cyclic voltammetry at scan rate of 2mV/sec of 2.5~4.5V, LiMn2O4 electrode prepared by post annealing at 75$0^{\circ}C$ showed good initial capacity. LiMn2O4 electrode prepared by post annealing at 80$0^{\circ}C$ showed the best crycling performance.

• 한국결정성장학회지
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• 제12권4호
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• pp.184-189
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• 2002

초음파 분무 MOCVD법에 의한 $(Pb_{0.91}La_{0.09})(Zr_{0.65}Ti_{0.35})O_3$(PLZT) 박막의 제조와 광학적, 전기적 특성을 조사하였다. Pb의 휘발성을 고려하여 0.2M의 precursor에 Pb를 5 wt%, 10 wt%과잉 첨가하였다. ITO-coated glass 기판 위에 산소분위기에서 30분 동안 증착한 후 in-situ 상태의 RTA (rapid thermal annealing) 방식으로 열처리를 하였다. 단일 perovskite상의 결정화 온도는 $600^{\circ}C$였다. Pb를 10 wt% 과잉 첨가한 박막의 최대 광투과율은 520nm에서 약 84%로 광학적 특성이 우수하였으며, 유전상수는 약 308의 값을 가졌고, 누설전류는 Pb를 0, 5 wt% 과잉 첨가한 PLZT 박막보다 낮은 값을 가졌다.

• 설비공학논문집
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• 제20권11호
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• pp.739-745
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• 2008

This paper presents the measurement of ground thermal conductivity and the characteristics of ground thermal diffusion by a ground heat exchanger(GHE). A borehole is installed to a depth of 175 m with a diameter of 150 mm. To analyze the thermal diffusion property of the GHE, thermocouples are installed under the ground near the GHE. The outdoor temperature, the ground temperature, and the water temperature of the GHE are monitored for evaluating the characteristics of ground thermal diffusion. The ground thermal conductivity is evaluated by the in-situ thermal response tester and the line source model. It is found to be 3.08 W/$m^{\circ}C$ in this study. The ground temperature is greatly dependent on the outdoor temperature from the ground surface to 2.5 m in depth and is stable below 10 m in depth. The surface temperature of the GHE varies as a function of the temperature of circulating water. But the ground temperature at 1.5 m far from the GHE is not changed in accordance with the temperature of circulating water.

• 대한기계학회논문집A
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• 제38권6호
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• pp.629-636
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• 2014

비정질합금이 가지고 있는 우수한 기계적 성질과 화학적 특성을 부품소재에 표면개질을 목적으로 고속화염 용사법으로 대면적 코팅층을 형성하였고 내열성이 높은 자융성합금과 초경합금 성분들을 적절히 혼합하여 비정질기지 복합재료를 제조하여 코팅들의 미세조직 관찰과 나노인덴테이션을 이용한 미세표면의 기계적 거동을 분석하였다. 각 코팅층의 미세조직을 관찰한 결과, 단일상 비정질 코팅에는 미용융 입자와 lamellae 영역이 존재하고 자융성합금이 고용된 복합재에는 in-situ $Cr_2Ni_3$ 석출물, 자융성합금과 초경합금성분이 함께 혼합된 코팅층은 석출물과 ex-situ WC 강화입자가 공존하였다. 이들 미세표면의 기계적 거동은 제 2 상이 고용된 비정질 기지 복합재의 코팅층의 기계적 특성이 전체적으로 향상되었다.