• 제목/요약/키워드: in-situ process

검색결과 853건 처리시간 0.029초

Reaction process in electrochromism of tungsten oxide thin films

  • An, Il-Sin;Lee, Chang-Hyo;Lim, Won-Taeg
    • Journal of Korean Vacuum Science & Technology
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    • 제2권2호
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    • pp.85-91
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    • 1998
  • The electrochromic behaviors of de-magnetron sputtered tungsten oxide thin films were investigated during coloration and bleach cycles using in situ real-time spectroscopic ellipsometry. Effective medium approximation and least-squares regression analyses were employed to investigate the electrochromic process. The optical properties of the tungsten oxide film were analyzed using the oscillator model and the evolution of the process using a reaction-limited model. In these analyses, we found that two different reaction rates were associated with the process. We ascribe this behavior to the microstructure of this films.

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In situ Transesterification/Reactive Extraction of Castor Bean Seeds Assisted by Flying Jet Plasma for Biodiesel Production

  • Elsheikh, Yasir A.;Abdul-Majeed, Wameath S.;Nasir, Qazi;Al-Rahbi, Balaqis;Al-Subhi, Noor;Mahmoud, Mohamed A.;AAl-Thani, Ghanim S.
    • 공업화학
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    • 제33권5호
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    • pp.538-544
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    • 2022
  • One of the most exciting areas for the development of alternative fuels is the production of biodiesel. To reduce the cost of biodiesel production, in situ trans-esterification has been introduced to simplify the production process by enabling extraction and trans-esterification to occur at a single stage in the presence of a catalyst. In this study, we investigated the feasibility of using non-corrosive and environmentally receptive flying jet plasma as an alternative catalytic route for in situ tran-sesterification of castor bean seeds (CBS). Upon optimizing the reaction conditions, it is elucidated that applying a low ratio of methanol to seeds (≤6:1) has resulted in hindering the in situ trans-esterification and leading to insignificant conversion. The yield of esters has increased from 80.5% to 91.7% as the molar ratio rose from 9:1 to 12:1. Excess alcohol beyond the ratio of 15:1 was shown to have a negative impact on the yield of the produced esters, attributed to an increase in the biodiesel portion prone to dissolving in the co-product (glycerol). An increase in the reaction bulk temperature from 40 to 55 ℃ led to a higher ester content by 50%. Further increases in the bulk temperature beyond 55 ℃ did not affect yields. Regarding the reaction period, the results have shown that 3 h of reaction is adequate for a higher biodiesel yield. The quality of the biodiesel obtained has demonstrated that all physicochemical properties meet the ASTM D6751 specifications.

in situ법(法)에 의한 Cu-Fe계(系) 다섬유상(多纖維狀) 복합재료제조(複合材料製造)에 관한 연구(硏究) (A Study on Cu-Fe Multifilamentary Composites Produced by in situ Process)

  • 서수정;박현순
    • 열처리공학회지
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    • 제4권2호
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    • pp.9-18
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    • 1991
  • Among the many maunfactured processes of producing multi filamentary composites, in situ process is widely used owing tv its simplicity and easyness of mass production. In this study, the mechanical and electromagnetic properties of Cu-Fe composite materials was investigated. The tensile strength of the Cu-Fe wires increased as the Fe content and reduction ratio were increased. The Cu-30 wt%Fe composites had the best properties in terms of figure merits compared to the other Cu-Fe composites made in this study or the commercially manufactured 6/1 ACSR cables of Cu cable. The coercivity was decreased by increasing Fe content, but the squareness was increased greatly. As increasing reduction ratio, the coercivity and squareness increased up to the maximum points, and then decreased. For example, the maximum values were obtained at $0.09mm{\phi}$ for Cu-30 wt%Fe composites and at $0.066mm{\phi}$ for Cu-45 wt%Fe composites. The magnetic property of Cu-Fe wires produced by precipitation treatment was higher than that of Cu-Fe wires produced by thermomechanical treatment. By annealing Cu-Fe wires after drawing process, the coercivity, remanence and squareness were improved.

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Biaxial integrated optical film for VA mode LCD's made from in-situ photopolymerised reactive mesogens.

  • Kim, Kyeong-Hyeon;Lyu, Jae-Jin;Chung, Dong-Hoon;Verrall, M.;Slaney, K.;Perrett, T.;Parri, O.;Lee, Seung-Eun;Lee, Hee-Kyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.773-775
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    • 2004
  • For high end, large area displays, all current LC modes require some degree of optical compensation to improve the front of screen viewing experience. Currently most optical films are laminated to the outside of the LCD cell, between the glass and polariser. In this paper we wish to show how it is possible to integrate the compensating optical film within a VA mode LCD cell. The paper will describe the process of making the biaxial film through the process of in-situ photopolymerisation of an aligned film of reactive mesogens in the cholesteric phase using polarised UV light. The film can be made on the colour filter array side of the LCD panel. In addition the process of fabricating a VA mode LCD containing this film will be described and the performance of this module will be presented

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Biaxial Integrated Optical Film for VA Mode LCD's Made from In-situ Photopolymerised Reactive Mesogens

  • Kim, Kyeong-Hyeon;Lyu, Jae-Jin;Chung, Dong-Hoon;Verrall, M;Slaney, K;Perrett, T;Parri, O;Lee, Seung-Eun;Lee, Hee-Kyu
    • Journal of Information Display
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    • 제5권2호
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    • pp.23-26
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    • 2004
  • For high end, large area displays, all current LC modes require some degree of optical compensation to improve the front of screen viewing experience. Currently most optical films are laminated to the outside of the LCD cell, between the glass and polariser. In this paper we wish to show how it is possible to integrate the compensating optical film within a VA mode LCD cell. The paper will describe the process of making the biaxial film through the process of in-situ photopolymerisation of an aligned film of reactive mesogens in the cholesteric phase using polarised UV light. The film can be made on the colour filter array side of the LCD panel. In addition the process of fabricating a VA mode LCD containing this film will be described and the performance of this module will be presented.

Rf co-sputtering으로 제작한 MgB$_2$ 박막의 in-situ 열처리 효과 (In-situ Annealing of $MgB_2$ Thin Films Prepared By rf Magnetron Co-Sputtering)

  • 김윤원;안종록;이순걸;이규원;김인선;박용기
    • Progress in Superconductivity
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    • 제5권2호
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    • pp.105-108
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    • 2004
  • We have studied effects of in-situ annealing on the fabrication of superconducting MgB$_2$ thin films prepared by rf magnetron co-sputtering. The Films were deposited on A1$_2$O$_3$ (1102) substrates at room temperature by using Mg and B targets. To trap remnant $O_2$ gas in the chamber, we used 20 mtorr Af sputter-gas balanced with 5 mol % of H$_2$ gas. To enhance adhesion to the substrate a thin layer of B was deposited prior to the codeposition of Mg and B. After completion of the film deposition, an additional Mg layer was deposited on top to compensate for Mg loss during the subsequent in-situ annealing. We have investigated the effects of two most important annealing parameters that are the Mg-to-B composition ratio and the annealing temperature. The range of the Mg-to-B composition ratio was from 0.42 to 0.85, and that of the annealing temperature was 500 $^{\circ}C$∼750 $^{\circ}C$. The Best result was obtained for the composition ratio of about 10% Mg excess from the stoichiometry and the annealing temperature of 700 $^{\circ}C$. Based on these results, we obtained films with T$_{c}$ : 36.5 K by further refining the fabrication process.s.

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In-Situ Heat Cooling using Thick Graphene and Temperature Monitoring with Single Mask Process

  • Kwack, Kyuhyun;Chun, Kukjin
    • 센서학회지
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    • 제24권3호
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    • pp.155-158
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    • 2015
  • In this paper, in-situ heat cooling with temperature monitoring is reported to solve thermal issues in electric vehicle (EV) batteries. The device consists of a thick graphene cooler on top of the substrate and a platinum-based resistive temperature sensor with an embedded heater above the graphene. The graphene layer is synthesized by using chemical vapor deposition directly on the Ni layer above the Si substrate. The proposed thick graphene heat cooler does not use transfer technology, which involves many process steps and does not provide a high yield. This method also reduces the mechanical damage of the graphene and uses only one photomask. Using this structure, temperature detection and cooling are conducted simultaneously using one device. The temperature coefficient of resistance (TCR) of a $1{\times}1mm^2$ temperature sensor on 1-$\grave{i}m$-thick graphene is $1.573{\times}10^3ppm/^{\circ}C$. The heat source cools down $7.3^{\circ}C$ from $54.4^{\circ}C$ to $47.1^{\circ}C$.

그라우팅을 병행한 강관추진공법의 현장 적용성 연구 (In-Situ Application of the Steel Pipe jacking with Grouting)

  • 정민형;임호정;신창섭;이송
    • 한국구조물진단유지관리공학회 논문집
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    • 제13권1호통권53호
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    • pp.152-160
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    • 2009
  • 강관추진공법은 비굴착공법으로써 중소규모 관로공사에 높은 시공성과 경제성을 가지고 있기 때문에 그 사용이 빈번해지고 있다. 그러나 강관추진공법의 추진과정은 원지반이 교란되고 느슨해지는 문제를 야기하고 있다. 이는 지표침하, 지반강도 저하 및 누수 등의 문제와 연결된다. 이에 본 연구는 강관추진과 동시에 그라우팅을 시행하는 그라우팅을 병행한 강관추진공법의 현장 적용성을 알아보고자 한다. 그 방법으로 그라우팅을 병행한 강관추진공법과 기존강관추진공법을 동일 지반에 시공하였다. 지표침하 계측, 현장밀도, GPR 물리탐사 그리고 대형전단실험의 결과는 그라우팅을 병행한 강관추진공법의 현장 적용성이 있음을 입증하였다.