• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2004.10a
• /
• pp.1194-1197
• /
• 2004

High temporal-resolution and accurate measurement of skin impedance locus provides useful data for the identification of the physiological/psychological changes and also the identification of acupuncture point. An impedance spectroscopy method using digitally constructed current waveform consisting of many frequency components (multiples of 1Hz) was reported3. The time resolution of the method depends on the lowest frequency used in the waveform construction, and therefore, the measurement would be faster if the lowest frequency is the higher. However, it was not clear that how many and how low frequencies must be used for the estimation of the skin impedance parameters from which the impedance locus can be drawn. This study shows the relationship between the estimation error of the impedance parameters and the frequency coverage of the spectroscopy. The results of this study are expected to serve as the reference of the frequency selection in the impedance spectroscopy.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.08a
• /
• pp.153-153
• /
• 2012

Endpoint detection with plasma impedance monitoring and self-plasma optical emission spectroscopy is demonstrated for dielectric layers etching processes. For in-situ detecting endpoint, optical-emission spectroscopy (OES) is used for in-situ endpoint detection for plasma etching. However, the sensitivity of OES is decreased if polymer is deposited on viewport or the proportion of exposed area on the wafer is too small. To overcome these problems, the endpoint was determined by impedance signal variation from I-V monitoring (VI probe) and self-plasma optical emission spectroscopy. In addition, modified principal component analysis was applied to enhance sensitivity for small area etching. As a result, the sensitivity of this method is increased about twice better than that of OES. From plasma impedance monitoring and self-plasma optical emission spectroscopy, properties of plasma and chamber are analyzed, and real-time endpoint detection is achieved.

• Proceedings of the KIPE Conference
• /
• 2014.11a
• /
• pp.68-69
• /
• 2014

In the battery based applications such as electric vehicle and energy storage system, the performance of the system highly depends on the reliability of the battery. However, it is difficult to obtain the accurate information about the state-of-health (SOH) of battery during its operation. In this paper a 3kw battery charger with battery diagnosis function which can estimate the SOH of the battery by using online impedance spectroscopy technique is introduced. For the charger phase shift full bridge converter with synchronous rectification has been adopted to implement the charge and diagnosis functions. The impedance spectroscopy is performed after the charge to obtain the information about the internal impedance of the battery module, hence the SOH can be estimated online by observing the impedance variation of the battery over time. All the design procedure of the proposed charger is detailed and the feasibility of the system is verified by the experimental results.

• Journal of the Korean Electrochemical Society
• /
• v.17 no.2
• /
• pp.119-123
• /
• 2014

Here I report on how Fourier Transform Electrochemical Impedance Spectroscopy (FTEIS) overcomes the potential-current linearity problem encountered in the impedance calculation process. FTEIS was first invented to solve the time-related drawback of the conventional impedance technique. The dramatic time reduction of FTEIS enabled the real-time impedance measurement but brought about the linearity problem at the same time. While the conventional method circumvents the problem using the steady-state made by a sufficiently long measurement time, FTEIS cannot because of its real-time function. However, according to the mathematical development reported in this article, the potential step used in FTEIS is proved to avoid the linearity problem. During the step period, the potential and the current are linearized by the electrochemical impedance. Also, Fourier transform of the differentiated potential and current is proved to give the same result of the original ones.

• Journal of the Korean Ceramic Society
• /
• v.43 no.3 s.286
• /
• pp.156-161
• /
• 2006

Impedance spectroscopy was applied to the initial hydration of calcium phosphate bone cements in order to investigate the electrical/dielectric properties. Hydration or equivalently setting was monitored as a function of the amount of water and initial powder characteristics. Higher amounts of water produced more open microstructures, leading to higher conductivity and enhanced dielectric constant. The effects of the initial characteristics in the powder were investigated using bone cement powder prepared with and without granulation. Granulated powder exhibited a significant change in resistance and produced a higher dielectric constant than those of conventional powder. Through a simplified modeling, the effects of thickness in reaction products and pore sizes were estimated by the frequency-dependent impedance measurements. Furthermore, impedance spectroscopy was proven to be a highly reliable tool for evaluating the continuous change in pore structure occurring in calcium phosphate bone cements.

• International Journal of Concrete Structures and Materials
• /
• v.2 no.2
• /
• pp.99-105
• /
• 2008

Southern exposure test specimens were used to evaluate corrosion performance of epoxy-coated reinforcing bars in chloride contaminated concrete by electrochemical impedance spectroscopy method. The test specimens with conventional bars, epoxy-coated bars and corrosion inhibitors were subjected 48 weekly cycles of ponding with sodium chloride solution and drying. The polarization resistance obtained from the Nyquist plot was the key parameter to characterize the degree of reinforcement corrosion. The impedance spectra of specimens with epoxy-coated bars are mainly governed by the arc of the interfacial film and the resistance against the charge transfer through the coating is an order of magnitude higher than that of the reference steel bars. Test results show good performance of epoxy-coated bars, although the coatings had holes simulating partial damage, and the effectiveness of corrosion-inhibiting additives. The corrosion rate obtained from the impedance spectroscopy method is equivalent to those determined by the linear polarization method for estimating the rate of corrosion of reinforcing steel in concrete structures.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.5 no.4
• /
• pp.474-480
• /
• 2017

In this study, the evolution of electrical impedance of electric nodes was investigated to determine the setting time of cement paste using the electrical impedance spectroscopy method. The electric nodes were embedded in fresh cement paste and the electrical impedance signatures were continuously monitored. Vicat needle test and semi-adiabatic calorimetry test were also conducted to validate the electrical impedance spectroscopy method. During hydration period of cement paste, the magnitude of conductance gradually increased, and then started to decrease rapidly at a first certain time. After that, the magnitude of conductance gradually decreased at a second certain time. The times of turning point in the curves of magnitude of conductance seem to be related with the setting time by Vicat needle test. Also, the setting times by the electrical impedance spectroscopy method are well posed within the setting period estimated by the semi-adiabatic calorimetry test. Based on the results, it can be concluded that the setting time of cement paste can be effectively monitored through the electrical impedance spectroscopy method.

• Journal of Biosystems Engineering
• /
• v.33 no.4
• /
• pp.269-275
• /
• 2008

This study was conducted to design an impedance sensor that can measure soil water content of soils. Partial least square regression (PLSR) was applied to soil impedance data preprocessed with a smoothing method. An optimal sub-spectrum size and wavelength range were determined by comparing the coefficient of determination ($R^2$) and root mean square error (RMSE) of the PLSR models obtained using soil impedance data. various PLS analysis. Based on the PLSR analysis, it would be concluded that the optimal spectrum measurement range was $32.0{\sim}50.0\;MHz$ with the optimal sub-spectrum size of about 18.5 MHz.

• Journal of the Korean Ceramic Society
• /
• v.49 no.3
• /
• pp.260-265
• /
• 2012

Impedance spectroscopy was used to monitor the hydration in the electrical/dielectric behaviors of chemical mechanical planarization (CMP)-blended cement mixtures. The electrical responses were analyzed using their equivalent circuit models, leading to the separation of the bulk and electrode based responses. The role of the CMP slurry was monitored as a function of the relative compositions of the CMP-blended cements, i.e. water, CMP slurry, and ordinary Portland cement. The presence of $Al_2O_3$ nanocrystals in the CMP slurries appeared to accelerate the hydration process, along with a more tortuous microstructure in the hydration, with enhanced hydration products. The frequency-dependent impedance spectroscopy was proven to be a highly efficient approach for evaluating the electrical/dielectric monitoring of the change in the pore structure evolution that occurs in CMP-blended cements.

• Journal of the Korean Ceramic Society
• /
• v.50 no.2
• /
• pp.163-167
• /
• 2013

A modified two-point impedance spectroscopy technique exploits the geometric constriction between an electrolyte and a cathode with an emphasis on semispherical-shaped electrolytes. The spatial limitation in the electrolyte/electrode interface leads to local amplification of the electrochemical reaction occurring in the corresponding electrolyte/electrode region. The modified impedance spectroscopy was applied to electrical monitoring of a YSZ ($Y_2O_3$-stabilized $ZrO_2$)/SSC ($Sm_{0.5}Sr_{0.5}CoO_3$) system. The resolved bulk and interfacial component was numerically analyzed in combination with an equivalent circuit model. The effectiveness of the "spreading resistance" concept is validated by analysis of the electrode polarization in the cathode materials of solid oxide fuel cells.