• Title/Summary/Keyword: impedance characteristics

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Variations in electrode characteristics through simplification of phosphorus-doped NiCo2O4 electrode manufacturing process (인이 도핑된 NiCo2O4 전극 제조 공정의 간소화를 통한 전극 특성의 변화)

  • Seokhee-Lee;Hyunjin Cha;Jeonghwan Park;Young Guk Son;Donghyun Hwang
    • Journal of Surface Science and Engineering
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    • v.56 no.5
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    • pp.299-308
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    • 2023
  • In this study, phosphorus (P)-doped nickel cobaltite (P-NiCo2O4) and nickel-cobalt layered double hydroxide (P-NiCo-LDH) were synthesized on nickel (Ni) foam as a conductive support using hydrothermal synthesis. The thermal properties, crystal structure, microscopic surface morphology, chemical distribution, electronic state of the constituent elements on the sample surface, and electrical properties of the synthesized P-NiCo2O4 and P-NiCo-LDH samples were analyzed using thermogravimetric analysis-differential scanning calorimetry (TGA-DSC), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). The P-NiCo2O4 electrode exhibited a specific capacitance of 1,129 Fg-1 at a current density of 1 Ag-1, while the P-NiCo-LDH electrode displayed a specific capacitance of 1,012 Fg-1 at a current density of 1 Ag-1. When assessing capacity changes for 3,000 cycles, the P-NiCo2O4 electrode exhibited a capacity retention rate of 54%, whereas the P-NiCo-LDH electrode showed a capacity retention rate of 57%.

Design of Vivaldi Antenna suitable for Impulse-like Waveform Radiation (임펄스 유사 신호 복사에 적합한 비발디 안테나 설계)

  • Doojin Lee;Bong Jin Ko
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.17 no.1
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    • pp.59-66
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    • 2024
  • In this paper, the method to design the antenna, which is suitable for an impulse-like waveform radiation, is presented. In general, the impulse-like waveform has its spectrum of around sub GHz bandwidth and the antenna should be properly designed for not only operating wide-bandwidth also reflecting the time domain characteristics for near-zone impulse radar applications. In this regard, Vivaldi antenna has been designed and characterized in terms of short-pulse radiating aspects in the time domain and verified by measured results. The designed antenna has shown to be operating within wide-bandwidth and to be stable for the input impedance from 1.8 to more than 10GHz. The far-zone radiating waveform has been investigated on each plane at the interval of 30degree and the designed antenna has shown to be a directive characteristic. It can be seen that those results proposed are widely applicable to the near area sensing applications such as ground-penetrating radar.

Novel Synthesis of MnO2-SiC Fiber-TiO2 Ternary Composite and Effective Photocatalytic Degradation with Standard Dyes

  • Latiful Kabir;Yeon Woo Choi;Yun Seo Shin;Yeon Ji Shin;Geun Chan Kim;Jun Hyeok Choi;Jo Eun Kim;Young Jun Joo;Kwang Youn Cho;Hyuk Kim;Je-Woo Cha;Won-Chun Oh
    • Korean Journal of Materials Research
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    • v.34 no.6
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    • pp.275-282
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    • 2024
  • In this work, we investigated the photo-degradation performance of MnO2-SiC fiber-TiO2 (MnO2-SiC-TiO2) ternary nanocomposite according to visible light excitation utilizing methylene blue (MB) and methyl orange (MO) as standard dyes. The photocatalytic physicochemical characteristics of this ternary nanocomposite were described by X-ray diffraction (XRD), scanning electron microscopy (SEM), tunneling electron microscopy (TEM), ultraviolet-visible (UV-vis), diffuse reflectance spectroscopy (DRS), electrochemical impedance spectroscopy (EIS), photocurrent and cyclic voltammogram (CV) test. Photolysis studies of the synthesized MnO2-SiC-TiO2 composite were conducted using standard dyes of MB and MO under UV light irradiation. The experiments revealed that the MnO2-SiC-TiO2 exhibits the greatest photocatalytic dye degradation performance of around 20 % with MB, and of around 10 % with MO, respectively, within 120 min. Furthermore, MnO2-SiC-TiO2 showed good stability against photocatalytic degradation. The photocatalytic efficiency of the nanocomposite was indicated by the adequate photocatalytic reaction process. These research results show the practical application potential of SiC fibers and the performance of a photocatalyst composite that combines these fibers with metal oxides.

Broadband 8 dBi Double Dipole Quasi-Yagi Antenna Using 4×2 Meanderline Array Structure (4×2 미앤더라인 배열 구조를 이용한 광대역 8 dBi 이중 다이폴 준-야기 안테나)

  • Junho Yeo;Jong-Ig Lee
    • Journal of Advanced Navigation Technology
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    • v.28 no.2
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    • pp.232-237
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    • 2024
  • In this paper, a broadband double dipole quasi-Yagi antenna using a 4×2 meander line array structure for maintaining 8 dBi gain was studied. The 4×2 meanderline array structure consists of a unit cell in the shape of a meanderline conductor, and it was placed above the second dipole antenna of the double dipole quasi-Yagi antenna. A double dipole quasi-Yagi antenna with generally used multiple strip directors was designed on an FR4 substrate with the same size, and the input reflection coefficient and gain characteristics were compared. Comparison results showed that the impedance frequency bandwidth increased by 6.3% compared to when using the multiple strip directors, the frequency bandwidth with a gain of 8 dBi or more increased by 10.1%, and average gain also slightly increased. The frequency band of the fabricated antenna for a voltage standing wave ratio less than 2 was 1.548-2.846 GHz(59.1%), and gain was measured to be more than 8 dBi in the 1.6-2.8 GHz band.

Design and Fabrication of Multi-Band Antenna for WLAN and Sub-6GHz Band (WLAN 및 Sub-6GHz 대역을 위한 다중대역 안테나 설계 및 제작)

  • Joong-Han Yoon
    • The Journal of the Korea institute of electronic communication sciences
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    • v.19 no.5
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    • pp.845-852
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    • 2024
  • In this paper, we propose mult-band antenna included Sub-6 GHz band for WLAN system. The proposed antenna has the fourth strip line and slot in the partial ground plane to obtain impedance matching. The total substrate size is 48.0 mm (W)×50.0 mm (L), thickness (h) 1.0 mm, and the dielectric constant is 4.4, which is made of 26.0 mm (W2)×42.0 mm (L1+L2+4.0(L1+L2+4.0 mm+L8+L9) antenna size on the FR-4 substrate. From the fabrication and measurement results, bandwidths of 115 MHz (0.825 to 0.940 GHz) for 900 MHz band, 210.0 MHz (2.29 to 2.50 GHz) for 2.4 GHz band, 270.0 MHz (3.45 to 3.72 GHz) for 3.5 GHz band, and 930.0 MHz (4.95 to 5.88 GHz) for 5.0 GHz band were obtained on the basis of -10 dB. Also, gain and radiation pattern characteristics are measured and shown in the frequency triple band as required.

Electrochemical Characteristics of Ultra Battery Anode Material using the Nano Pb/AC for ISG (나노 납/활성탄을 사용한 ISG용 울트라 전지 음극소재의 전기화학적 특성)

  • Hwang, Jin Ung;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.55 no.5
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    • pp.593-599
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    • 2017
  • In order to enhance ultra battery performances, the electrochemical characteristics of nano Pb/AC anode composite was investigated. Through nano Pb adsorption onto activated carbon, nano Pb/AC was synthesized and it was washed under vacuum process. The prepared anode materials was analysed by SEM, BET and EDS. The specific surface area and average pore size of nano Pb/AC composite were $1740m^2/g$ and 1.95 nm, respectively. The negative electrode of ultra battery was prepared by nano Pb/AC dip coating on lead plate. The electrochemical performances of ultra battery were studied using $PbO_2$ (the positive electrode) and prepared nano Pb/AC composite (the negative electrode) pair. Also the electrochemical behaviors of ultra battery were investigated by charge/discharge, cyclic voltammetry, impedance and rate capability tests in 5 M $H_2SO_4$ electrolyte. The initial capacity and cycling performance of the present nano Pb/AC ultra battery were improved with respect to the lead battery and the AC-coated lead battery. These experimental results indicate that the proper addition of nano Pb/AC into the negative electrode can improve the discharge capacity and the long term cycle stability and remarkably suppress the hydrogen evolution reaction on the negative electrode.

A Study on the Characteristics Analysis of Hybrid Choke Coil with Reduced Parasitic Capacitance suitable for LED-TV SMPS (LED-TV용(用) 전원장치에 적합한 기생 커패시턴스 저감형 Hybrid 초크 코일의 특성 해석에 관한 연구)

  • Lee, Jong-Hyeon;Kim, Gu-Yong;Kim, Jong-Hae
    • Journal of IKEEE
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    • v.22 no.1
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    • pp.185-188
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    • 2018
  • This paper describes the parasitic capacitance modeling according to the coil structure, section bobbin and winding method for hybrid choke coil with reduced parasitic capacitance capable of the EMI attenuation of broad bands from lower frequency to higher frequency applied in the EMI attenuation filter of LED-TV SMPS. Especially, the hybrid choke coil with reduced parasitic capacitance($C_p$) proposed in this paper can reduces the parasitic capacitance($C_p$) by adopting the winding methods of rectangular copper wire, compared to the conventional common mode choke coil with the winding method of automatic type. The first resonant frequency of the proposed hybrid choke coil has a tendency to increase as the parasitic capacitance is smaller and its impedance characteristics, especially in the high frequency bands, improves as the first resonant frequency increases. In the future, the proposed hybrid choke coil with reduced parasitic capacitance shows it can be actually utilized in not only LED-TV SMPS but also various applications such as LED Lighting, Note-PC Adapter, and so forth.

Effects of CaCO3 on the Defects and Grain Boundary Properties of ZnO-Co3O4-Cr2O3-La2O3 Ceramics (ZnO-Co3O4-Cr2O3-La2O3 세라믹스의 결함과 입계 특성에 미치는 CaCO3의 영향)

  • Hong, Youn-Woo;Ha, Man-Jin;Paik, Jong-Hoo;Cho, Jeong-Ho;Jeong, Young-Hun;Yun, Ji-Sun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.5
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    • pp.307-312
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    • 2018
  • Liquid phases in ZnO varistors cause more complex phase development and microstructure, which makes the control of electrical properties and reliability more difficult. Therefore, we have investigated 2 mol% $CaCO_3$ doped $ZnO-Co_3O_4-Cr_2O_3-La_2O_3$ (ZCCLCa) bulk ceramics as one of the compositions without liquid phase sintering additive. The results were as follows: when $CaCO_3$ is added to ZCCLCa ($644{\Omega}cm$) acting as a simple ohmic resistor, CaO does not form a secondary phase with ZnO but is mostly distributed in the grain boundary and has excellent varistor characteristics (high nonlinear coefficient ${\alpha}=78$, low leakage current of $0.06{\mu}A/cm^2$, and high insulation resistance of $1{\times}10^{11}{\Omega}cm$). The main defects $Zn_i^{{\cdot}{\cdot}}$ (AS: 0.16 eV, IS & MS: 0.20 eV) and $V_o^{\bullet}$ (AS: 0.29 eV, IS & MS: 0.37 eV) were found, and the grain boundaries had 1.1 eV with electrically single grain boundary. The resistance of each defect and grain boundary decreases exponentially with increasing the measurement temperature. However, the capacitance (0.2 nF) of the grain boundary was ~1/10 lower than that of the two defects (~3.8 nF, ~2.2 nF) and showed a tendency to decrease as the measurement temperature increased. Therefore, ZCCLCa varistors have high sintering temperature of $1,200^{\circ}C$ due to lack of liquid phase additives, but excellent varistor characteristics are exhibited, which means ZCCLCa is a good candidate for realizing chip type or disc type commercial varistor products with excellent performance.

Power Generating Characteristics of Anode-Supported SOFC fabricated by Uni-Axial Pressing and Screen Printing (일축가압/스크린인쇄 공정에 의해 제조된 음극지지형 SOFC의 출력특성)

  • 정화영;노태욱;김주선;이해원;고행진;이기춘;이종호
    • Journal of the Korean Ceramic Society
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    • v.41 no.6
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    • pp.456-463
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    • 2004
  • To enhance the performance of anode-supported SOFC, single cell fabrication procedure was changed for better and resulting power generating characteristics of single cell were investigated. Liquid condensation process was employed for the granulation of NiO/YSZ powder mixture and the produced powder granules were compacted into anode green substrate by uni-axial pressing. YSZ electrolyte was printed on green substrate via screen-printing method and co-fired at 1400$^{\circ}C$ for 3 h. LSM/YSZ composite cathode of which the composition and heat treatment condition was adjusted to minimize the polarization#resistance with AC-impedance spectroscopy, was screen printed. The final single cell size from this multi-step procedure was 5${\times}$5 $\textrm{cm}^2$ and 10${\times}$10 $\textrm{cm}^2$. The maximum power densities of 5${\times}$5 and 10${\times}$10 single cells were about 0.45 W/$\textrm{cm}^2$ and 0.22 W/$\textrm{cm}^2$ at 800$^{\circ}C$, which are two times superior than those from single cells fabricated by the conventional process in previous our work.

Design of a Planar LPDA Antenna with Light-Weight Supporting Structure for Installing on an Aircraft (항공기 탑재용 경량화 지지 구조를 갖는 평면 LPDA 안테나 설계)

  • Park, Young-Ju;Park, Dong-Chul
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.27 no.3
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    • pp.253-260
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    • 2016
  • This paper proposes a planar Log-Periodic Dipole Array(LPDA) antenna with light-weight supporting structure for installing on an aircraft. The proposed antenna is designed by applying a planar skeleton supporting structure that has light-weight for an aircraft and is capable of withstanding structural vibration. The material of the planar skeleton supporting structure is a Polyether ether ketone(Peek) which has excellent characteristics on strength and temperature. The proposed antenna is fabricated by attaching the radiating elements of the LPDA on both sides of the supporting structure. The changed input impedance due to the dielectric material of the supporting structure was compensated for by controlling the distance and length of several radiating elements. The 10-dB return loss bandwidths of the designed planar LPDA antenna with light-weight supporting structure are obtained as 0.4~3.1 GHz(7.3:1) in the simulation and 0.41~3.5 GHz(8.2:1) in the measurement. The average gains in 0.5~3 GHz band are 6.77 dBi in the simulation and 6.55 dBi in the measurement. Therefore, we confirm that the designed antenna is appropriate to be installed on an aircraft due to its light-weight structure and wideband directional radiation characteristics.