• 조명전기설비학회논문지
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• 제25권7호
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• pp.49-54
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• 2011

Now the world will regulate the CO2 emission due to environmental issues. For an alternative plan photovoltaic system is watched. So, photovoltaic system is trend of big city and it is mandatory for renovation of construction. Oil & gas filling station existed in city is suitable to found the photovoltaic system. But the general photovoltaic system in oil & gas filling station is difficult to found because it is classified into hazardous area. This paper evaluates intrinsic safety evaluation of solar cell for making basic data to found for the photovoltaic system on hazardous area. The intrinsic safety characteristic is evaluated by short-circuit ignition test using IEC type spark ignition test apparatus and temperature rising test. The result of short-circuit ignition test, propane-air mixture gas is exploded on condition that 4 solar cells(9[V], 90[mA]) are connected serially under insolation 800[W/$m^2$]. So, if a larger solar module will be used at oil & gas filling station than we were tested, it needs explosion proof. As the result of rising temperature test, the temperature rising due to short circuit is not so much, but when the temperature rises due to radiant heat, it demands careful consideration for environmental influence.

• 대한기계학회논문집B
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• 제22권12호
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• pp.1681-1690
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• 1998

The aim of this paper is to investigate combustion characteristics of lean premixed mixture stabilized by catalytic surface reaction. The catalytic combustor consisted of a catalyst bed and a thermal combustor. The catalyst bed was made of two stage, Pd catalyst in the first stage and Pt catalyst in the second stage. Auto ignition of lean mixture took place in the thermal combustor. Ignition temperature was about $810{\sim}820^{\circ}C$ at the fuel-air ratio of 1.5~3.0 % and the mixture velocity of 11~18m/sec. The position of flame front in the thermal combustor moved toward back as preheat temperature increased and fuel-air ratio decreased. The f1ame supported by surface reaction was stabilized without any flame stabilizers. NOx emissions from the catalytic combustor were below 2.0 ppm ($O_2$ 15 %) when gas temperature was limited below $1350^{\circ}C$. This result demonstrates that NOx emission from the catalytic combustor is much low comparing with conventional combustors.

• 대한화학회지
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• 제48권1호
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• pp.12-16
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• 2004

에탄올-산소-아르곤 혼합기체의 점화 과정을 반사 충격파를 이용 1281-1625 K의 온도 범위 및 0.69-1.06 bar 압력 범위에서 고찰하였다. 점화지연시간은 급격한 압력변화와 광 방출 스펙트럼으로부터 측정하였으며, 에탄올 및 산소 기체의 농도 그리고 반응온도에 따른 점화지연시간의 의존관계를 나타내는 실험식을 구할 수 있었다. 실험결과 에탄올 점화 과정에서 연료인 에탄올의 농도가 커지면 점화지연시간이 길어지는 경향을 보였으며, 이는 메탄올 점화 과정에서 메탄올의 농도가 증가하면 점화 과정이 짧아지는 것과는 다른 경향이었다. 그리고 에탄올 점화 과정에 관하여 보다 자세히 고찰하기 위해 다양한 에탄올 연소반응 메카니즘을 이용하여 모델 연구를 수행하였다.

• Korean Chemical Engineering Research
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• 제55권5호
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• pp.623-628
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• 2017

화력발전소의 연료로 사용되는 우드펠릿을 시료로 하여 시료 용기의 크기에 따른 최소자연발화온도를 구하였으며, 이 온도로부터 Frank-Kamenetskii의 열발화 이론을 이용하여 겉보기 활성화 에너지를 구함으로써 물질의 위험성을 예측하였다. 용기의 크기가 클수록 발화한계온도는 낮아졌으며, 겉보기 활성화 에너지는 37.83 kcal/mol을 구하였다. 또한 시료의 용기가 커질수록 발화유도시간 및 최고온도에 도달하는 시간이 길어졌다.

• 한국수소및신에너지학회논문집
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• 제23권6호
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• pp.628-633
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• 2012

It was found that the pure hydrogen-air pre-mixture was self-ignited at a high compression ratio without any assisting method in room temperature, thus refuting the preconception that compression ignition of hydrogen engine was impossible. Therefore, in order to analyze the correlation of compression ignition condition at cold start with hydrogen HCCI engine clearly, the possibility of compression igniting compression ratio is investigated with the change of equivalence ratio and engine speed, experimentally. As the results, it is confirmed that the possibility of compression-igniting compression ratio at cold start was decreased by increasing equivalence ratio due to decreasing auto-ignition temperature. In addition, it is grasped that the possibility of compression-igniting compression ratio at cold start is decreased around 14.9% by increasing engine speed at same supply energy.

• 한국안전학회지
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• 제19권2호
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• pp.54-60
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• 2004

Flammable substances are frequently used chemical industry processes. An accurate knowledge of the ALTs(Autoignition Temperatures) is important in developing appropriate prevention and control measures in industrial fire protection. The AITs describe the minimum temperature to which a substance must be heated, without the application of a flame or spark, which will cause that substance to ignite. The AITs are dependent upon many factors, namely initial temperature, pressure, volume, fuel/air stoichiometry, catalyst material, concentration of vapor, ignition delay. This study measured relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for methanol and ethanol. The A.A.P.E.(Average Absolute Percent Error) and the A.A.D.(Average Absolute Deviation) of the experimental and the calculated delay times by the AITs for methanol were 14.59 and 1.76 respectively. Also the A.A.P.E. and the A.A.D. of the experimental and the calculated delay times by the ATIs for ethanol were 8.33 and 0.88.

• 한국안전학회지
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• 제29권6호
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• pp.55-61
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• 2014

The autoignition temperature (AIT) of a material is the lowest temperature at which the substance will spontaneously ignite in the absence of an external ignition source such as a spark or flame. The AIT may be used as combustion property to specify operating, storage, and materials handling procedures for processs safety. This study measured the AITs of n-Propanol+n-Decane system from ignition delay time(time lag) by using ASTM E659 apparatus. The AITs of n-Propanol and n-Decane which constituted binary system were $435^{\circ}C$ and $212^{\circ}C$, respectively. The experimental AITs of n-Propanol+n-Decane system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D(average absolute deviation).

• 한국가스학회지
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• 제19권3호
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• pp.25-31
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• 2015

본 연구에서는 부유 Mg분진의 최소발화온도(MIT)에 있어서 입자 체류시간이 어떠한 영향을 주는지를 실험자료와 입자속도의 계산결과를 사용하여 조사하였다. 평균입경이 증가하면 Mg분진의 MIT는 증가하는 반면에 입자 체류시간(Residence time)은 지수함수적으로 감소하여 분진의 발화 가능성이 저하되는 요인이 될 수 있음을 계산을 통해 확인할 수 있었다. 또한 온도증가에 의한 입자속도에의 영향은 평균입경이 클수록 미세하지만 증가하는 결과가 얻어졌다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집B
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• pp.335-340
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• 2000

Most vehicle's exhaust emissions come from the cold transient period of the FTP-75 test. In this study, UEGI technology was developed to help close-coupled catalytic converter (CCC) reach light-off temperature within a few seconds after cold-start. In the UEGI system, unburned exhaust mixture is ignited by four glow plugs installed upstream of the catalyst. Experimental results showed that the temperature of CCC rises faster with the UEGI technology, and the CCC reaches light-off temperature earlier. Under the conditions tested, the light-off time of the baseline case was 62 seconds and that of the UEGI case was 33 seconds.

• 한국분무공학회지
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• 제22권4호
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• pp.190-196
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• 2017

The aim of this work is to investigate the combustion and exhaust emission characteristics of low-temperature combustion (LTC) at various EGR test conditions using a single cylinder common-rail diesel engine. In high EGR rate combustion mode with DME fuel, 30% (${\Phi}=0.61$) and 50% (${\Phi}=0.86$) of EGR were respectively examined, and then the combustion, exhaust emissions, nano-particle characteristics of each cases were measured. From these results, it revealed that The ignition delay and combustion duration are prolonged as the increase of EGR rate. In addition, at an advanced injection timing (BTDC $30^{\circ}$), ignition delays were fairly increased because the dilution effect of EGR and also low charge in-cylinder temperature created a lean mixture, thus decreased the peak release rate.