• Title/Summary/Keyword: ignition delay time(time lag)

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Prediction of Autoignition Temperature of n-Propanol and n-Octane Mixture (n-Propanol과 n-Octane 혼합물의 최소자연발화온도의 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.17 no.2
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    • pp.21-27
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    • 2013
  • The lowest values of the AITs(Autoignition temperatures) in the literature were normally used fire and explosion protection. In this study, the AITs of n-Propanol+n-Octane system were measured from ignition delay time(time lag) by using ASTM E659 apparatus. The AITs of n-Propanol and n-Octane which constituted binary systems were $435^{\circ}C$ and $218^{\circ}C$, respectively. The experimental ignition delay time of n-Propanol+n-Octane system were a good agreement with the calculated ignition delay time by the proposed equations with a few A.A.D.(average absolute deviation).

Measurement of Autoignition Temperature of Ethylbenzene+n-hexanol and Ethylbenzene+n-propionic Acid Systems (Ethylbenzene+n-hexanol 계와 ethylbenzene+n-propionic acid계의 최소자연발화온도의 측정)

  • Ha, Dong-Myeong;Lee, Sung-Jin
    • Fire Science and Engineering
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    • v.21 no.3
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    • pp.33-40
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    • 2007
  • The values of the AITs(Autoignition temperatures) for fire and explosion protection are normally the lowest reported. This study measured the AITs of ethylbenzene+n-hexanol and ethylbenzene+n-propionic acid Systems from ignition delay time(time lag) by using ASTM E659-78 apparatus. The AITs of ethylbenzene, n-hexanol and n-propionic acid which constituted binary systems were $475^{\circ}C,\;275^{\circ}C\;and\;511^{\circ}C$, respectively. The experimental ignition delay time of ethylbenzene+n-hexanol and ethylbenzene+n-propionic acid systems were a good agreement with the calculated ignition delay time by the proposed equations with a few A.A.D.(average absolute deviation).

Measurements of Autoigniton Temperature(AIT) and Time Lag of BTX(Benzene, Toluene, Xylenes) (BTX(Benzene, Toluene, Xylenes)의 자연발화온도와 발화지연시간의 측정)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.21 no.3 s.75
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    • pp.45-52
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    • 2006
  • The AITs(autoignition temperatures) describe the minimum temperature to which a substance must be heated, without the application of a flame or spark, which will cause that substance to ignite. The AITs are often used as a factor in determining the upper temperature limit for processing operations and conditions for handling, storage and transportation, and in determining potential fire hazard from accidental contact with hot surfaces. The measurement AITs are dependent upon many factors, namely initial temperature, pressure, volume, fuel/air stoichiometry, catalyst material, concentration of vapor, time lag. Therefore, the AITs reported by different ignition conditions are sometimes significantly different. This study measured the AITs of benzene, toluene and xylene isomers from time lag using AS1M E659-78 apparatus. The experimental ignition delay times were a good agreement with the calculated ignition delay times by the proposed equations wtih a few A.A.D.(average absolute deviation). Also The experimental AITs of benzene, toluene, o-xylene, m-xylene and p-xylene were $583^{\circ}C,\;547^{\circ}C,\;480^{\circ}C,\;587^{\circ}C,\;and\;557^{\circ}C$, respectively.

Measurement and Prediction of Autoignition Temperature of n-Propanol+n-Decane Mixture (노말프로판올과 노말데칸 혼합물의 최소자연발화온도 측정 및 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.29 no.6
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    • pp.55-61
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    • 2014
  • The autoignition temperature (AIT) of a material is the lowest temperature at which the substance will spontaneously ignite in the absence of an external ignition source such as a spark or flame. The AIT may be used as combustion property to specify operating, storage, and materials handling procedures for processs safety. This study measured the AITs of n-Propanol+n-Decane system from ignition delay time(time lag) by using ASTM E659 apparatus. The AITs of n-Propanol and n-Decane which constituted binary system were $435^{\circ}C$ and $212^{\circ}C$, respectively. The experimental AITs of n-Propanol+n-Decane system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D(average absolute deviation).

Measurement and Prediction of Autoignition Temperature of n-Butanol + n-Decane System (n-Butanol과 n-Decane계의 최소자연발화온도 측정 및 예측)

  • Ha, Dong-Myeong;Hong, Soo-Kang
    • Fire Science and Engineering
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    • v.25 no.6
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    • pp.184-189
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    • 2011
  • This study measured the AITs of n-butanol + n-decane system from ignition delay time (time lag) by using ASTM E659 apparatus. The AITs of n-butanol and n-decane which constituted binary system were $340^{\circ}C$ and $212^{\circ}C$, respectively. The experimental AITs of n-butanol + n-decane system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D. (average absolute deviation).

Measurement and Prediction of Autoignition Temperature(AIT) of n-Propanol and Acetic acid System (노말프로판올과 아세틱에씨드 계의 최소자연발화온도(AIT) 측정 및 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.32 no.2
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    • pp.66-71
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    • 2017
  • The autoignition temperature (AIT) is crucial combustible characteristics which need attention in chemical process that handle hazardous materials. The AIT, also to as minimum spontaneous ignition temperature(MSIT), is the lowest temperature of a hot surface at which the substance will spontaneously ignite without any obvious sources of ignition such as a spark or flame. The AIT may be used as combustion property to specify operating, storage, and materials handling procedures for process safety. This study measured the AITs of n-propanol+acetic acid system from ignition delay time(time lag) by using ASTM E659 apparatus. The AITs of n-propanol and acetic acid which constituted binary system were $435^{\circ}C$ and $212^{\circ}C$, respectively. The experimental AITs of n-propanol+acetic acid system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D.(average absolute deviation). In the case of n-propanol and acetic acid system, the minimum autoignition temperature behavior (MAITB), which is lower than the lower AIT, is shown among the two pure substances constituting the mixture.

The Minimum Autoignition Temperature Behavior(MAITB) of n-Decane and Acetic acid Mixture (n-Decane과 Acetic acid 혼합물의 최소자연발화온도 거동)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.28 no.2
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    • pp.49-54
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    • 2013
  • The autoignition temperature(AIT) is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs and ignition delay time for n-Decane and Acetic acid system by using ASTM E659 apparatus. The AITs of n-Decane and Acetic acid which constituted binary system were $212^{\circ}C$ and $512^{\circ}C$, respectively. The experimental AITs of n-Decane and Acetic acid system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D.(average absolute deviation). And n-Decane and Acetic acid system was shown the minimum autoignition temperature behavior(MAITB).

Measurement and Prediction of Autoignition Temperature of n-Butanol and sec-Butanol System (노말부탄올과 2차부탄올 계의 최소자연발화온도의 측정 및 예측)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.26 no.5
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    • pp.48-53
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    • 2012
  • The autoignition temperature (AIT) is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs and ignition delay time for n-Butanol+sec-Butanol system by using ASTM E659 apparatus. The AITs of n-Butanol and sec-Butanol which constituted binary system were $340^{\circ}C$ and $447^{\circ}C$, respectively. The experimental AITs of n-Butanol+sec-Butanol system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D. (average absolute deviation).

A Study of Minimum Autoignition Temperature Behavior (MAITB) of Benzene and n-Hexane Mixture (벤젠과 노말헥산 혼합물의 최소자연발화온도 거동에 관한 연구)

  • Ha, Dong-Myeong;Kim, Kyu-Hyun
    • Fire Science and Engineering
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    • v.27 no.1
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    • pp.8-13
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    • 2013
  • The autoignition temperature (AIT) is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs and ignition delay time for Benzene and n-Hexane system by using ASTM E659 apparatus. The AITs of Benzene and n-Hexane which constituted binary system were $583^{\circ}C$ and $240^{\circ}C$, respectively. The experimental AITs of Benzene and n-Hexane system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D. (average absolute deviation).

Measurement of Autoignition Temperature of n-Propanol and Formic acid System (n-Propanol과 Formic acid계의 최소자연발화온도의 측정)

  • Cho, Young-Se;Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.27 no.5
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    • pp.64-69
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    • 2013
  • The autoignition temperatures (AITs) of solvent mixture was important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs and ignition delay time for n-propanol and formic acid system by using ASTM E659 apparatus. The AITs of n-Propanol and Formic acid which constituted binary system were $435^{\circ}C$ and $498^{\circ}C$, respectively. The experimental AITs of n-propanol and formic acid system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D. (average absolute deviation). And n- Propanol and formic acid system was shown the minimum autoignition temperature behavior (MAITB).