• Fire Science and Engineering
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• v.31 no.5
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• pp.1-6
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• 2017

The fire and explosion properties of combustible materials are necessary for the safe handling, storage, transportation and disposal. Typical combustion characteristics for process safety include auto ignition temperature(AIT). The AIT is an important index for the safe handling of combustible liquids. The AIT is the lowest temperature at which the material will spontaneously ignite. In this study, the AITs and ignition delay times of n-pentanol and p-xylene mixture were measured by using ASTM E659 apparatus. The AITs of n-pentanol and p-xylene which constituted binary system were $285^{\circ}C$ and $557^{\circ}C$, respectively. The experimental AITs and ignition delay times of n-pentanol and p-xylene mixture were a good agreement with the calculated AITs and ignition delay times by the proposed equations with a few A.A.D. (average absolute deviation). Therefore, it is possible to estimate the AITs and ignition delay times in other compositions of n-pentanol and p-xylene mixture by using the predictive equations which presented in this study.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2012.05a
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• pp.106-109
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• 2012

It was designed and tested ignition that an oxidizer rich preburner for a staged combustion cycle liquid rocket engine propelled by kerosene and LOx. Operation conditions of the preburner are about 60 of OF ratio and 20 MPa of combustion pressure. Ignition characteristics were compared by propellants flowrate. As the results, the higher propellants flowrate, the shorter the ignition delay time and the higher ignition stiffness. The ignition delay time was affected by incoming the oxidizer flowrate through the refrigerative cooling channels. The oxidizer flowrate from the cooling channels decreased by inflow of combustion gas during initial ignition. The oxidizer flowrate of the cooling channels increases, it is rapid recovery by cooling effect, eventually the ignition delay time decreases.

• Bulletin of the Korean Chemical Society
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• v.18 no.10
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• pp.1071-1075
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• 1997

Detonation characteristics of acetylene were studied behind reflected shock waves in the temperature range 800-1350 K by monitoring OH emission and pressure profiles. For a comprehensive measurement of ignition delay time, the mixture composition was varied in a wide range of Ar mole % was varied from 0.625 to 2.5 in stoichiometric ratio of C2H2-O2-Ar. A computer simulation study was also performed to elucidate the important elementary steps determining ignition behavior. The 33-reaction mechanism provides a good agreement in delay time between the observed and the calculated ones.

• Journal of ILASS-Korea
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• v.16 no.4
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• pp.167-175
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• 2011

The HCCI engines have been known with high efficiency and low pollution and can be actualized as the new internal combustion engines. However, As for(??) the ignition and combustion depend strongly on the oxidation reaction of the fuel, so it is difficult to control auto-ignition timing and combustion duration. Purpose of this paper is creating the database for development of multi-dimensional simulation and investigating the influence of different molecular structure. In this research, the effect of n-heptane mole ratio in fuel (XnH) on the ignition delay from homogeneous charge compression ignition(HCCI) has been investigated experimentally. By varying the XnH, it was possible to ascertain whether or not XnH is the main resource of ignition delay. Additionally, the information on equivalence ratio for varying XnH was obtained. The tests were performed on a RCM (Rapid Compression Machine) fueled with n-heptane and iso-octane. The results showed that decreasing XnH (100, 30, 20, 10,0), the ignition delays of low temperature reaction (tL) and high temperature reaction (tH) is longer. And the temperature of reaction increases by about 30K. n-heptane partial equivalence ratio (fnH) affect on tL.and TL. When ${\phi}$nH was increased as a certain value, tL was decreased and TL was increased.

• Journal of the Korean Institute of Gas
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• v.25 no.2
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• pp.1-12
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• 2021

MILD(Moderate or Intense Low-oxygen Dilution) combustion has attracted attention as the clean thermal energy technology due to the lower emissions of unburnt carbon and NO_x. MILD combustion aims to enlarge the combustion reaction zone using the spontaneous ignition phenomenon of the reactants. In this study, the ignition delay time of CH₄ according to the initial temperature of reactants and the addition of CO, H₂ was investigated using a numerical approach. Ignition delay time became shorter as the increases of initial temperature and H₂ addition. But, CO addition to the fuel increase the ignition delay time. In case of H₂ addition to the fuel, the ignition delay time decreased because the higher fraction of HO₂ promotes the decomposition of methyl radical(CH₃) and produce OH radical. However, in case of CO addition to the fuel, ignition delay time inceased because a high proportion of HCO consumes H radical. There was no significant effect of HCO on the reduction of ignition delay time. Also, the increase rates of NO emissions by the addition of CO and H₂ were approximately 7% and 1%, respectively. A high proportion of NCO affects the increase in NO production rate.

• 한국연소학회:학술대회논문집
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• 2013.06a
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• pp.25-28
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• 2013

This study presents both experimental and numerical investigation of ignition characteristics of n-heptane and n-butanol mixture. The $O_2$ concentration was fixed to 9-10% to make high exhaust gas recirculation(EGR) rate condition. Experiments were performed using a rapid compression machine. In addition, a numerical study of the ignition delay time was performed using CHEMKIN codes to validate experimental results and predict chemical species after combustion process. The results showed that the ignition delay time increased with increasing n-butanol ratio and the reactivity decreased by low $O_2$ concentration.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.03a
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• pp.301-306
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• 2008

A pyrogen igniter was designed to satisfy the required condition of kick motor system for the space launch vehicle. We analyzed the ignition characteristics and performed the combustion tests to verify the internal ballistic performance. In the design process, the arc-image test was carried out to find the sufficient heat flux as varying the initial pressure from 10 to 700kPa. The analysis indicated that the initial pressure condition would delay ignition time within a range from 100 to 500ms. The combustion test with an inert chamber was also performed to understand the ignition characteristics with the variation of the initial pressure of free chamber volume. Finally, we confirmed that the igniter could provide the acceptable energy to ignite the propellant of kick motor at the ground test. The result of the ground tests showed that the ignition delay time was within the design range at the atmospheric pressure condition.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.13-19
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• 2003

As the environmental pollution becomes serious global problem, the regulation of emission exhausted from automobiles is strengthen. Therefore, it is very important to know how to reduce the NOx and PM simultaneously in diesel engines, which has lot of merits such as high thermal efficiency, low fuel consumption and durability. By this reason, the new concept called as Homogeneous Charge Compression Ignition(HCCI) engines are spotlighted because this concept reduced NOx and P.M. simultaneously. However, it is well known that HCCI engines increased HC and CO. Thus, the investigation of combustion characteristics which consists cool and hot flames for HCCI engines were needed to obtain the optimal combustion condition. In this study, combustion characteristics for direct inject type HCCI engine such as quantity of cool flame and hot flame, ignition timing and ignition delay were investigated to clarify the effects of these parameters on performance. The results revealed that diesel combustion showed the two-stage ignition of cool flame and hot flame, the rate of cool flame increase and hot flame decrease with increasing intake air temperature. On the other hand, the gasoline combustion is the single-stage ignition and ignition timing is near the TDC. In addition mixed fuel combustion showed different phenomenon, which depends on the ratio of gasoline component. Ignition timing of mixed fuel is retarded near the TDC and the ignition delay is increased according to ratio of gasoline.

• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.6
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• pp.118-125
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• 2018

This study aimed to obtain data for a comparative analysis of the properties of bio aviation fuel to be developed in the future by measuring and comparing the ignition delay times of various presently used aviation fuels. In the case of petroleum-based aviation fuel, the ignition delay time of exo-THDCP was 4.92 ms, which was 3.42 times longer than 1.44 ms of Jet A-1 at $590^{\circ}C$ / 55 bar. In the case of foreign bio aviation fuel, the ignition delay time of 11POSF7629 was the longest (1.16 ms), while the ignition delay time of 10POSF6308 (1.06 ms), 12POSF7720 (1.07 ms), and 07POSF5172 (1.05 ms) were similar.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.50 no.11
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• pp.783-789
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• 2022

In a recent study, it was observed that the combustion gas entering the post chamber of a hybrid rocket contains vortices with very small size and high frequency characteristics. In addition, it was observed that small vortices collided with the nozzle wall to create a counter-flow, resulting in additional combustion with ignition delay. This study investigated the physical relationship between ignition delay induced by the counter-flow and the formation of beating pressure. To do this, a newly modified model was proposed by including ignition delay in the existing energy kicked oscillator model proposed by Culick. Numerical results show that the ignition delay is an important factor in determining the occurrence of the combustion pressure beats through the periodic formation of thermoacoustic coupling. In addition, when the ignition delay was reduced by increasing the post chamber length, the phase difference between the energy kick and the pressure generation was increased, the periodic pressure beats did not occur at all.