• Title/Summary/Keyword: ideal solution

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Effect of pH on the sorption and desorption of chlorinated phenols using HDTMA-montmorillonite (HDTMA-몬모릴로나이트를 이용한 염화페놀류 화합물의 흡착 및 탈착시 pH의 영향)

  • 김지훈;김영규;신원식;김영훈;최상준;전영웅;송동익
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.09a
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    • pp.19-22
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    • 2001
  • The effects of pH on the sequential sorption/desorption of chlorinated phenols (2-chlorophenol, 2.4-dichlorophenol and 2,4,5-trichlorophenol) in HDTMA-montmorillonite were investigated by maintaining pH 4.85 or 9.15 in the sequential batch sorption and desorption experiments. The chlorinated phenols are hydrophobic ionizable orginic compounds; they can exist as either neutral (pH << pKa) or anionic (pH >> pKa) forms. Among the tested chlorinated phenols, 2,4,5-trichlorophenol showed the highest sorption affinity at pH 4.85 as expected by the $K_{ow}$ . Neutral speciation at pH 4.85 exhibited higher sorption affinity than anionic speciation at pH 9.15. Our results indicates that desorption of chlorinated phenols is strongly dependent on pH of the aqueous phase. Freundlich model was used to analyze the single-solute sorption/desorption results. The ideal adsorbed solution theory(IAST) was employed to predict the hi-solute sorption/desorption equilibria.

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Morphology and Properties of Polyacrylonitrile/Single Wall Carbon Nanotube Composite Films

  • Kim, Seong Hoon;Min, Byung Ghyl;Lee, Sang Cheol;Park, Sung Bum;Lee, Tae Dong;Park, Min;Kumar, Satish
    • Fibers and Polymers
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    • v.5 no.3
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    • pp.198-203
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    • 2004
  • Composite films were prepared by casting the solution of polyacrylonitrile (PAN) and single wall nanotube (SWNT) in DMF subsequent to sonication. The SWNTs in the films are well dispersed as ropes with 20-30 nm thickness. Moreover, AFM surface image of the composite film displays an interwoven fibrous structure of nanotubes which may give rise to conductive passways and lead to high conductivity. The polarized Raman spectroscopy is an ideal characterization technique for identification and the orientation study of SWNT. The well-defined G-peak intensity at 1580 $cm^{-1}$shows a dependency on the draw ratio under cross-Nicol. The degree of nanotube orientation in the drawn film was measurable from the sine curve obtained by rotating the drawn film on the plane of cross-Nicol of polarized Raman microscope. The threshold loading of SWNT for electrical conductivity in PAN is found to be lower than 1 wt% in the composite film. The electrical conductivity of the SWNT/PAN composite film decreased with increasing of draw ratio due to the collapse of the interwoven fibrous network of the nanotubes with uniaxial orientation.

Evaluate of Electrochemical Characteristics in Electrolyzed Reduced Water

  • Park, Sung-Ho;Yun, Su-Jin;Kim, Jeong-Sik;Shin, Hyun-Su;Park, Soo-Gil
    • Journal of Electrochemical Science and Technology
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    • v.2 no.2
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    • pp.85-90
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    • 2011
  • Active oxygen species or free radicals are considered to cause extensive oxidative damage to biological macromolecules, which brings about a variety of diseases as well as aging. Electrolyzed reduced water(ERW) has been regarded as a ideal antioxidative agent in recent years. ERW is produced by passing a diluted salt solution through an electrolytic cell, within which the anode and cathode are separated by membrane. It can be produced reactive materials in ERW near the cathode during the electrolysis of water. ERW have the following advantages over other traditional cleaning agents: effective antioxidative agent, easy preparation, inexpensive, and environmentally friendly. The main advantage of ERW is its safety and antioxidative effect. ERW with strong reducing potential can be used to remove dirt and grease from items such as cutting boards and other kitchen utensils. The primary aim of this study is the activation mechanism of oxidation reduction potentials, ion conductivity, pH, and electrochemical properties with reactive materials in ERW.

Nucleation and Growth of Vacancy Agglomeration in CZ Silicon Crystals

  • Ogawa, Tomoya;Ma, Minya
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1999.06a
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    • pp.45-49
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    • 1999
  • When concentration of vacancies in a CZ silicon crystal is defined by molar fraction XB, the degree of super-saturation $\sigma$ is given by [XB-XBS]/XBS=XB/XBS-1=ln (XB/XBS) because XB/XBS is nearly equal to unity. Here, XBS is the saturated concentration of vacancies in a silicon crystal and XB is a little larger than XBS. According to Bragg-Williams approximation, the chemical potential of the vacancies in the crystal is given by ${\mu}$B=${\mu}$0+RT ln XB+RT ln ${\gamma}$, where R is the gas constant, T is temperature, ${\mu}$0 is an ideal chemical potential of the vacancies and ${\gamma}$ is an adjustable parameter similar to the activity of solute in a solution. Thus, $\sigma$(T) is equal to (${\mu}$B-${\mu}$BS)/RT. Driving force of nucleation of the vacancy agglomeration will be proportional to the chemical potential difference (${\mu}$B-${\mu}$BS) or $\sigma$(T), while growth of the vacancy agglomeration is proportional to diffusion of the vacancies and grad ${\mu}$B.

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Collision Response of Bow Structure and Its Affected Collision Bulkhead in Bow Collision (선수 충돌시 구조거동과 충돌격벽에 미치는 영향)

  • 신영식;박명규
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2000.04a
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    • pp.195-204
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    • 2000
  • In this paper a complicated structural behavior in collision and its effect of energy translation to the collision bulkhead was examined through a methodology of the numerical simulation to obtain a ideal bow construction and a location of collision bulkhead against head on collision. In the present the bow structure is normally designed in consideration of its specific structural arrangements and internal and external loads in these area such as hydrostatic and dynamic pressure, wave impact and bottom slamming in accordance with the Classification rules, and the specific location of collision bulkhead by SOLAS requirement. By these studies the behavior of the bow collapse due to collision was synthetically evaluated for the different size of tankers and its operational speed limits, and by the result of these simulation it provides the optimal design concept for the low construction to prevent the subsequent plastic deformation onto or near to the collision bulkhead boundary and to determine the rational location of collision bulkhead.

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Use of a gesture user interface as a touchless image navigation system in dental surgery: Case series report

  • Rosa, Guillermo M.;Elizondo, Maria L.
    • Imaging Science in Dentistry
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    • v.44 no.2
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    • pp.155-160
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    • 2014
  • Purpose: The purposes of this study were to develop a workstation computer that allowed intraoperative touchless control of diagnostic and surgical images by a surgeon, and to report the preliminary experience with the use of the system in a series of cases in which dental surgery was performed. Materials and Methods: A custom workstation with a new motion sensing input device (Leap Motion) was set up in order to use a natural user interface (NUI) to manipulate the imaging software by hand gestures. The system allowed intraoperative touchless control of the surgical images. Results: For the first time in the literature, an NUI system was used for a pilot study during 11 dental surgery procedures including tooth extractions, dental implant placements, and guided bone regeneration. No complications were reported. The system performed very well and was very useful. Conclusion: The proposed system fulfilled the objective of providing touchless access and control of the system of images and a three-dimensional surgical plan, thus allowing the maintenance of sterile conditions. The interaction between surgical staff, under sterile conditions, and computer equipment has been a key issue. The solution with an NUI with touchless control of the images seems to be closer to an ideal. The cost of the sensor system is quite low; this could facilitate its incorporation into the practice of routine dental surgery. This technology has enormous potential in dental surgery and other healthcare specialties.

Estimation Method of Local Elastic-Plastic Strain at Thinning Area of Straight Pipe Under Tension Loading (인장하중을 받는 직선 배관 감육부의 국부 탄소성 변형률 평가 방법)

  • An Joong-Hyok;Kim Yun-Jae;Yoon Kee-Bong;Ma Young-Wha
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.5 s.248
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    • pp.533-542
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    • 2006
  • In order to assess the integrity of pipes with local thinning area, the plastic strain as well as the elastic strain at the root of thinned region are required particularly when fluctuating load is applied to the pipe. For estimating elastic-plastic strain at local wall thinning area in a straight pipe under tensile load, an estimation model with idealized fully circumferential constant depth wall thinning area is proposed. Based on the compatibility and equilibrium equations a nonlinear estimation equation, from which local elastic-plastic strain can be determined as a function of pipe/defect geometry, material and the applied strain was derived. Estimation results are compared with those from detailed elastic-plastic finite element analysis, which shows good agreements. Noting that practical wall thinning in nuclear piping has not only a circular shape but also a finite circumferential length, the proposed solution for the ideal geometry is extended based on two-dimensional and three-dimensional numerical analysis of pipes with circular wall thinning.

A Decision Support System for the Selection of a Rapid Prototyping Process (쾌속조형공정 선정을 위한 지원 시스템)

  • 변홍석;이관행
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.5-8
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    • 2003
  • This paper presents a methodology to be able to select an appropriate RP system that suits the end use of a part. Evaluation factors used in process selection include major attributes such as accuracy, roughness, strength, elongation, part cost and build time that greatly affect the performance of RP systems. Crisp values such as accuracy and surface roughness are obtained with a new test part developed. The test part is designed with conjoint analysis to reflect users' preference. The part cost and build time that have approximate ranges due to cost and many variable parameters are presented by linguistic values that can be described with triangular fuzzy numbers. Based on the evaluation values obtained, an appropriate RP process for a specific part application is selected by using the modified TOPSIS(Technique of Order Preference by Similarity to Ideal Solution) method. It uses crisp data as well as linguistic variables, and each weight on the alternatives is assigned by using pair-wise comparison matrix. The ranking order helps the decision making of the selection of RP systems.

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Numerical analysis for the development of a Mixed-flow In-line duct fan with a high performance (고성능 사류식 In-line duct fan의 개발을 위한 전산해석)

  • Kim, Sung-Kon;Cho, Lee-Sang;Cho, Jin-Soo;Won, Eu-Pil
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.604-609
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    • 2001
  • This numerical analysis uses the lifting surface method and frequency-domain panel method based on the linear compressible aerodynamic theory. Increased knowledge of flow conditions within mixed-flow fan should indicates means of improving performance of these turbomachines. Thus, only an approximate solution is obtained whose prime intent is to recognize the most significant characteristics of the "ideal" geometry. For a given set of operating condition, the flow conditions within mixed-flow fan depend on the geometry of the machine (three-dimensional flow effects) and on the properties of the fluid. But most treatments of the problem have been concerned with the two-dimensional flow effects for incompressible, non-viscous fluids. Interest in the field of mixed-flow fan resulted in the undertaking of a program to develop reliable design procedures that would avoid the need for lengthy development work.

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The Simulation and Experimental Study on the Bridge Response of AGT Bridge - Vehicle interaction System (AGT 시스템 교량-차량 상호작용에 의한 교량응답 시뮬레이션 및 실험)

  • Na, Sang-Ju;Kim, Ki-Bong;Song, Jae-Pil;Kim, Hyun-Ho
    • Proceedings of the KSR Conference
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    • 2007.11a
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    • pp.395-400
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    • 2007
  • LRT(Light Railway Train), which is a intermediate system of train and bus, is arose for the solution of subway construction cost and the transportation capacity of bus. LRT was introduced in 1980's. About 30 local governments are plan to introduce LRT or constructing LRT, at present. AGT(Automated Guide-way Transit) system, which is a kind of LRT, is operated without driver. Rubber wheeled AGT system can reduce the noise and vibration compare to steel wheeled AGT, so it is estimated as ideal transportation system for urban area. And live loads at bridge are classified as the static load of vehicle and the dynamic wheel contact load which is occurred from the interaction of bridge and vehicle vibration, and the surface roughness. In the case of AGT system, the dynamic increment factor of bridge is greater than the normal train bridge and roadway bridge, because, the weight of AGT vehicle is more light that the train of truck. The exact method for dynamic increment factor is experiment. But this method is needed much money and time, moreover, this method cannot be adopted in design. Therefore, a simulation program for the interaction of AGT bridge, vehicle and surface roughness was developed, in this study. And the program was verified by experiment. As a result, the accuracy of the simulation program can be verified.

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