• Title/Summary/Keyword: iTECH 합성보

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Experimental Study on the Fire Resistance of the iTECH Composite Beam (iTECH 합성보의 내화성능에 대한 실험연구)

  • Lee, Sueng Jae;Kang, Seong Deok;Choi, Seng Kwan;Kim, Myeong-Han;Kim, Sang Dae
    • Journal of Korean Society of Steel Construction
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    • v.18 no.5
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    • pp.643-654
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    • 2006
  • Thispaper presents the results of an experimental investigation into the fire performances ofsimply supported iTECH composite beams using an ISO834 standard fire. There are very few independent studies on the fire resistance of composite steel and concrete structures of various designs. The iTECH composite beam system has been used in construction, but nothing is known about its influence in a fire. To evaluate the fire resistance performanceof the iTECH beam, a test was conducted for 4.7m-span-length iTECH beams under given conditions in a laboratory. The fire resistance performance of unprotected coatings of the iTECH beam has been examined, and a longer period of fire resistance was achieved by increasing the beam coating's section size and decreasing its load ratio. Coatings for the fire protection of iTECH beams reduce the rate of temperature rise of the beam in case of fire, and the required thickness of spray-on fire protection coatings can be determined by means of tests.

Analytical Study on the Fire Resistance of iTECH Composite Beam (iTECH 합성보의 내화성능에 대한 해석연구)

  • Lim, Yoon Hee;Kang, Seong Deok;Oh, Myoung Ho;Kim, Myeong Han;Kim, Sang Dae
    • Journal of Korean Society of Steel Construction
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    • v.18 no.5
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    • pp.655-664
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    • 2006
  • The purpose of thisanalytical study of an iTECH composite beam subjected to fire conditions is to determine the beam's fire resistance performance using its load ratio and fire protection as parameters. A composite structural system is expected to have a safer and more economical fire safety design than a mere collection of isolated members.heat transfer analysis was performed on the basis of the finite element program ANSYS 10.0 using an ISO834 standard fire, following the main guidelines proposed by EC1 Part 2.2 and EC4 Part 1.2. To validate the analytical simulation of the iTECH composite beam, comparison of the experimental tests was proposed.

Studies on the ${\beta}-Tyrosinase$ -Part 2. On the Synthesis of Halo-tyrosine by ${\beta}-Tyrosinase$- (${\beta}-Tyrosinase$에 관한 연구 -제2보 ${\beta}-Tyrosinase$에 의한 Halogen화(化) Tyrosine의 합성(合成)-)

  • Kim, Chan-Jo;Nagasawa, Toru;Tani, Yoshiki;Yamada, Hideaki
    • Applied Biological Chemistry
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    • v.22 no.4
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    • pp.198-209
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    • 1979
  • L-Tyrosine, 2-chloro-L-tyrosine, 2-bromo-L-tyrosine, and 2-iodo-L-tyrosine were synthesized by ${\beta}-tyrosinase$ obtained from cells of Escherichia intermedia A-21, through the reversal of the ${\alpha},{\beta}-elimination$ reaction, and their molecular structures were analyzed by element analysis, NMR spectroscopy, mass spectrometry and IR spectroscopy. Rates of synthesis and hydrolysis of halogenated tyrosines by ${\beta}-tyrosinase$, inhibition of the enzyme activity by halogenated phenols, and effects of addition of m-bromophenol on the synthesis of 2-bromotyrosine were determined. The results obtained were as follows: 1) In the synthesis of halogenated tyrosines, the yield of 2-chlorotyrosine from m-chlorophenol were approximately 15 per cent, that of 2-bromotyrosine from m-bromophenol 13.8 per cent, and that of 2-iodotyrosine from m-iodophenol 9.8 per cent. 2) Rate of synthesis of halogenated tyrosines by ${\beta}-tyrosinase$ was slower than that of tyrosine and the rates were decreased in the order of chlorine, bromine and iodine, that is, by increasing the atomic radius. Relative rate of 2-chlorotyrosine synthesis was determined to be 28.2, that of 2-bromotyrosine to be 8.13, and that of 2-iodotyrosine to be 0.98, respectively, against 100 of tyrosine. However 3-iodotyrosine was not synthesized by the enzyme. 3) The relative rate of 2-chlorotyrosine hydrolysis by ${\beta}-tyrosinase$ was 70.7, that of 2-bromotyrosine was 39.0, and that of 2-iodotyrosine was 12.6 against 100 of tyrosine, respectively. The rate of hydrolysis appeared to be decreased in the order of chlorine, bromine and iodine, that is, by increasing the atomic radius or by decreasing the electronegativity. But 3-iodotyrosine was not hydrolyzed by the enzyme. 4) The activity of ${\beta}-tyrosinase$ was inhibited by phenol markedly. Of the halogenated phenols, o-, or m-chlorophenol and o-bromophenol gave marked inhibition on the enzyme action, however inhibition by iodophenol was not strong. Plotting by Lineweaver-Burk method, a mixed-type inhibition by m-chlorophenol was observed and its Ki value was found to be $5.46{\times}10^{-4}M$. 5) During the synthesizing reaction of 2-bromotyrosine by the enzyme, sequential addition of substrate which was m-bromophenol with time intervals and in a small amount resulted in better yield of the product. 6) The halogenated tyrosines which were produced by ${\beta}-tyrosinase$ from pyruvate, ammonia and m-halogenated phenols were analysed to determine their molecular structures by element analysis, NMR spectroscopy, mass spectrometry, and IR spectroscopy. The result indicated that they were 2-chloro-L-tyrosine, 2-bromo-L-tyrosine, and 2-iodo-L-tyrosine, respectively.

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Different Photosynthetic Responses of Black Cherry (Prunus serotina) with Different Sensitivities to Ambient Ozone Concentrations under Natural Conditions (자연상태에서 대기 중 오존 농도에 상이한 민감성을 가진 Black Cherry(Prunus serotina)의 상이한 광합성 반응)

  • Yun, Myoung-Hui;Chevone, Boris I.
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.10 no.4
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    • pp.132-140
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    • 2008
  • Two different sensitivity classes of black cherry (Prunus serotina) under the natural growing environmental conditions were assessed adjacent to Air Monitoring Station located at Horton research center in Giles County, Virginia, USA. Ambient ozone concentrations, leaf gas exchange, and visible foliar injury were measured on-site during the growing seasons of 2000, 2001, and 2002. Ambient ozone exposures were sufficient to induce typical foliar visible injury corresponding with the reduction in photosynthetic activities only in sensitive black cherry. There were positive correlations between increasing cumulative ozone concentration and percent reduction in maximum net photosynthetic rates ($Pn_{MAX}$) under saturating light conditions and in quantum yield for carbon reduction (${\Phi}CO_2$) of sensitive black cherry compared to tolerant black cherry. There was a negative correlation between chlorophyll content and percent leaf injury in sensitive black cherry. Furthermore, $Pn_{MAX}$ was inversely related to percent leaf injury.

Antimicrobial Activity Screening of Sixty-four Evergreen Woody Species According to Extraction Conditions against Trichophyton mentagrophytes (상록성 목본 64종의 추출조건에 따른 무좀원인균의 항균활성 스크리닝)

  • Jang, Bo Kook;Chi, Lai Won;Cho, Ju Sung;Lee, Cheol Hee
    • Korean Journal of Plant Resources
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    • v.31 no.4
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    • pp.330-341
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    • 2018
  • This study was performed to investigate and measure the antimicrobial activity of evergreen woody species extracts on Trichophyton mentagrophytes. To do this, leaves and stems were collected from Wando and Jeju islands, and were used for the extraction with different solvents (i.e., distilled water, 80% ethanol, and 100% methanol), and at different ultrasonic extracting times (i.e., 15, 30, and 45 minutes). The experiment was conducted by using the agar diffusion method. The clear zone was measured after incubating the paper disc containing the plant extract in a bacterial culture medium. The controls were synthetic antimicrobials, methylparaben and phenoxyethanol, at concentrations of 0.4, 1, 2, and 4 mg/disc. Altogether, extracts of 56 out of 64 species used in this study had inhibitory activity, which confirmed their antimicrobial activity against Athlete's foot. Among them, the crude ethanolic extract of Elaeocarpus sylvestris in 45 min showed a zone of inhibition < 20.2 mm, while the clear zone of Actinodaphne lancifolia ethanolic extraction for 30 min was 23.5 mm. Also, Quercus acuta, Dendropanax morbiferus and Daphne odora showed clear zones of 28.0 mm (45 minutes ethanolic extraction), 20.5 mm (45 minutes crude methanolic extraction) and 19.7 mm (45 minutes methanolic extraction), respectively. Thus, these results confirm that the extracts of evergreen woody species have therapeutic potential against Athlete's foot, and suggest that in order to extract adequate amounts of antimicrobial substance from the plant sources, ideal extraction condition has to be considered.