• Title/Summary/Keyword: hydrous basaltic materials

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Solid-Solution Mechanism of Aluminum and Hydrogen in Stishovite (스티쇼바이트에 고용하는 알루미늄과 수소와의 관계)

  • 정정인;김희수
    • Journal of the Mineralogical Society of Korea
    • /
    • v.16 no.3
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    • pp.245-254
    • /
    • 2003
  • Stishovite was synthesized from hydrous basaltic starting materials at 10∼15 ㎬ and $1000∼1400^{\circ}C$. Water content of synthetic stishovite has been determined, and solid solution mechanism of $H_2$ and Al in stishovite was investigated. The maximum water content obtained from stishovite single crystal was up to $844\pm$44 ppm $H_2$O. The concentration of hydrogen increased with increasing substitution of trivalent cation, mainly Al. The temperature effect on the hydrogen content in stishovite is more sensitive than that on any other impurities. Among the nominally anhydrous mantle-minerals, stishovite could be an important water-containing phase and contribute to the transportation of $H_2$O to lower mantle.