• Title/Summary/Keyword: hydroquinone

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Study on the Catalytic Properties of Copper Oxide Nanoparticles Synthesized by Levitational Gas Condensation (LGC) Method

  • Uhm, Y.R.;Lee, M.K.;Rhee, C.K.
    • Journal of the Korean Magnetics Society
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    • v.17 no.2
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    • pp.99-102
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    • 2007
  • The Cu oxide nano powders were synthesized by levitational gas condensation (LGC) method and their high heterogeneous catalytic effects of oxidation of 2,3,5-trimethyl-1,4-hydroquinone (TMHQ) and catalase activity were studied. The nano powders consist of mainly $Cu_2O$. The catalytic effect which was clarified by the oxidation of TMHQ and the activity of catalase, was found to depend on the amount of $Cu_2O$ phase and the particle size.

Ag Nanowires Prepared by a Modified Polyol Method with 1,4-Benzoquinone Additives

  • Kang, Miseon;Chung, Eunseon;Kim, Sang-Ho;Rhee, Seog Woo
    • Bulletin of the Korean Chemical Society
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    • v.35 no.11
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    • pp.3209-3212
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    • 2014
  • This paper describes a selective synthetic method of fabricating Ag nanowires by using a modified polyol process. To synthesize the Ag nanowire, an ethylene glycolic solution of silver nitrate and an ethylene glycolic solution of polyvinylpyrrolidone solution containing a small amount of organic oxidant, 1,4-benzoquinone, were slowly added to a hot ethylene glycol medium at $160^{\circ}C$ for 8 min using a syringe pump. The reaction mixtures were heated for an additional 45 min and cooled to room temperature. Finally, the silver nanomaterials were isolated from the mixture by centrifugation. The crystal structure of the nanomaterials was investigated by powder X-ray diffraction analyses, and their morphology was investigated by scanning electron microscopy. A small amount of organic oxidant, 1,4-benzoquinone, played a significant role in controlling the morphology during crystal growth. Consequently, Ag nanowires rather than Ag nanoparticles were selectively obtained.

Diffraction Efficiency Properties of Holographic Gratings by the Reversal Bleached on the Effect of Superadditivity (초부가성 효과에 의한 반전표백 홀로그래피 회절격자의 회절효율 특성)

  • Lim, Chun-Woo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.5
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    • pp.403-407
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    • 2010
  • This paper shows that the diffraction efficiency is influenced by superadditivity for the combination of the different developing agent and concentrations in the reversal bleach applied to the Slavich PFG-01 plate to be used for recording transmission holograms. The four developers based on ascorbic acid in combination with metol, phenidone, hydroquinone respectively, were studied. In diffraction efficiency aspect, the superadditivity effect of mixture of two developing agents is lower than one developing agent developer, AAC in the reversal bleach.

Supercapacitive Properties of Composite Electrode Consisting of Activated Carbon and Di(1-aminopyrene)quinone

  • Kim, Kwang Man;Lee, Young-Gi;Park, Jeong Ho;Ko, Jang Myoun
    • ETRI Journal
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    • v.38 no.2
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    • pp.252-259
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    • 2016
  • Di(1-aminopyrene)quinone (DAQ) as a quinone-containing conducting additive is synthesized from a solution reaction of 1-aminopyrene and hydroquinone. To utilize the conductive property of DAQ and its compatibility with activated carbon, a composite electrode for a supercapacitor is also prepared by blending activated carbon and DAQ (3:1 w/w), and its supercapacitive properties are characterized based on the cyclic voltammetry and galvanostatic charge/discharge. As a result, the composite electrode adopting DAQ exhibits superior electrochemical properties, such as a higher specific capacitance of up to $160F{\cdot}g^{-1}$ at $100mV{\cdot}s^{-1}$, an excellent high-rate capability of up to $1,000mV{\cdot}s^{-1}$, and a higher cycling stability with a capacitance retention ratio of 82% for the 1,000th cycle.

Potential Induction of Quinone Reductase Activity of Natural Products in Cultured Murine Hepa1c1c7 Cells

  • Heo, Yeon-Hoi;Lee, Sang-Kook
    • Natural Product Sciences
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    • v.7 no.2
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    • pp.38-44
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    • 2001
  • NAD(P)H:quinone reductase (QR), known as DT-diaphorase, is a kind of detoxifying phase II metabolic enzyme catalyzing hydroquinone formation by two electron reduction pathway from quinone type compounds, and thus facilitating excretion of quinoids from human body. With the usefulness of QR induction activity assay system for the modulation of toxicants, in the course of searching for cancer chemopreventive agents from natural products, the methanolic extracts of approximately two hundreds of oriental medicines were primarily evaluated using the induction potential of quinone reductase (QR) activity in cultured murine Hepa1c1c7 cells. As a result, several extracts including Hordeum vulgare, Momordica cochinchinensis, Strychnos ignatii, Houttuynia cordata, and Polygala japonica were found to significantly induce QR activity. In addition, the methylene chloride fraction of H. vulgare, one major dietary food source, showed potent induction of QR activity $(CD=6.4{\mu}g/ml)$. Further study for isolation of active principles from these lead extracts is warranted for the discovery of novel cancer chemopreventive agents.

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The Effects of Bamboo Extract on Human Melanocytes and B16 Melanoma Cells in vitro

  • Cho, Joon-Hwan;Lee, Ki-Moo;Kim, Nam-Soo;Kang, Won-Hyoung
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.25 no.4 s.34
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    • pp.133-143
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    • 1999
  • To identify inhibitory effect of Bamboo extract on melanogenesis, the effect was compared with arbutin, ascorbic acid, hydroquinone, and kojic acid on the melanin biosynthesis in B16 mouse melanoma cells and cultured human melanocytes. The cell viability of the agent was tested on cultured human melanocytes. We also examined its. free radical scavenging activity on 1,1-diphenyl-2-picrylhydrazyl(DPPH). Bamboo extract showed considerable effect against melanin production and did not reduce cell viability at the concentration tested. It also showed potent free radical scavenging activity.

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$^{13}C-Nuclear$ Magnetic Resonance of the Phenolic Compounds (I) -A Systematic Evaluation of the Chemical Shifts of the Phenolic Compounds- (Phenol성(性) 화합물(化合物)의 $^{13}C$-핵자기(核磁氣) 공명(共鳴)(I) -Phenol성(性) 화합물(化合物)의 Chemical Shift에 관(關)한 연구(硏究)-)

  • Ahn, Byung-Zun
    • Korean Journal of Pharmacognosy
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    • v.8 no.1
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    • pp.17-21
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    • 1977
  • $^{13}C-NMR$ behaviors of phenolic compounds such as phenol, catechol, pyrogallol, resorcine, phoroglucine and hydroquinone were studied. From the study on the effects of OH-substitution on benzene and its dervatives it was found that the additivity rule can be applied to the ortho-and para-effect but not to the meta-effect for the OH-function. The empirically calculated chemical shifts regarding the o-and p-effects coincide very well with the results of measurement. The chemical shifts of the phenolic compounds can be classified into three types. 1) Catechol-type C-1 and C-2 145 ppm C-3 and C-6 116-107 ppm 2) Pyrogallol-type C-1 132ppm C-2 and C-6 146ppm C-3 and C-5 106ppm 3) Resorcin-type C-1 and C-3 159ppm C-2 103-95ppm C-4 and C-6 107ppm

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Studies on the Antioxidant Action of Antioxidant of Oils and Fats (유지의 항산화제의 항산화능력에 대하여)

  • 강신주
    • Journal of the Korean Home Economics Association
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    • v.5 no.1
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    • pp.815-825
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    • 1966
  • Many synthetic antioxidants are now used to prevent the oxidation of oils and fats. Among the synthetic and tioxidants, it was known that those of HQ(Hydroquinone), BHA(Butyl hydroxyanisole), IG(isoamyl gallate), and NDGA(Nordihydro guaiaretic acid) are most efficient as the antioxidizing agent. In this work, Degree of antioxidation was investigated on the some such antioxidans BHA, CI(citric acid), AA(Ascoric acid) for several kinds of oils and fats which are most available in Korea by determining Acid value and Iodine Value. The results of experiments were as follows 1. The decreasing order of antioxidizing action by acid value is BHA, AA, CA. 2. The order of antioxidizing action by Iodine value is almost same as the case of Acid Value. 3. It is effective to add the antioxidants to kep oils and fat. 4. Oxidation is accelerated by standing oils and fats after boiling in the from fry pan. 5. Sesame oil is little oxidized without antioxidant.

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Antioxidative and Protective Activity of Polysaccharide Extract from Artemisia iwayomogi Kitamura Stems on UVB-Damaged Mouse Epidermis

  • Ahn, Byung-Yong;Jung, Mun-Yhung
    • Journal of Applied Biological Chemistry
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    • v.54 no.3
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    • pp.184-189
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    • 2011
  • Polysaccharide (PS) was fractionated from hot-water extract of Artemisia iwayomogi Kitamura stems. PS showed considerably higher hydroxyl radical scavenging activity than caffeic acid and glutathione. PS showed lower superoxide anion radical scavenging activity than hydroquinone and ascorbic acid. The scavenging activity of PS on the reactive oxygen species (ROS) induced by human neutrophils with zymosan was determined by the lucigenin-enhanced chemiluminescence assay. The scavenging effect of the PS on ROS as determined by the chemiluminescence assay was about 2-fold stronger than that of ascorbic acid at the same concentration. PS significantly decreased protein carbonyl and malonaldehyde contents in UVB irradiated skin homogenates, which was comparable to glutathione at the same concentration. This result suggested that PS derived from A. iwayomogi Kitamura stems may be a potent candidate as functional compound for the protection on UVB induced skin damage in cosmetics.

Studies on the Phenol Compounds in Smoke Total Particulate Matters of Flue-cured Tobacco Leaves (황색종 잎담배의 연기응축물중 페놀 화합물에 관한 연구)

  • 복진영;백순옥;김상범;안동명;조수헌
    • Journal of the Korean Society of Tobacco Science
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    • v.23 no.2
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    • pp.162-167
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    • 2001
  • This study was carried out to quantitatively determine phenol compounds in smoke total particulate matter(TPM) to evaluate the qualititive characteristics of flue-cured tobacco varieties(NC82, KFl14 and KFl18). After collecting The TPM by using smoking machine, the concentration of phenol compounds were analyzed by gas chromatography as their trimethylsilyl derivative on a fused capillary column bonded with a 5% PE ME siloxane stationary phase. In all the flue-cured tobacco varieties, the major phenol components were monohydroxy compounds. The order of the highest concentration of total phenol compounds in TPM was NC82, KF114 and KFl18 but the contents of dihydroxy compound in the KFl18 was higher than those of NC82 and KF114.

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