• Title/Summary/Keyword: hydrophobic silica

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PDMS (Polydimethylsilioxane)-Coated Silica Nanoparticles for Selective Removal of Oil and Organic Compound from Water

  • Cho, Youn Kyoung;Kim, Dae Han;Yoon, Hye Soo;Jeong, Bora;Kim, Young Dok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.257-257
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    • 2013
  • In order to selectively remove oil and organic compound from water, silica nanoparticles with hydrophobic coating was used. Since silica nanoparticles are generally hydrophilic, removal efficiency of oil and organic compound, such as toluene, in water can be decreased due to competitive adsorption with water. In order to increase the removal efficiency of oil and toluene, hydrophobic polydimethylsiloxane (PDMS) was coated on silica nanoparticles in the form of thin film. Hydrophobic property of the PDMS-coated silica nanoparticles and hydrophilic silica nanoparticles were easily confirmed by putting it in the water, hydrophilic particle sinks but hydrophobic particle floats. PDMS coated silica nanoparticles were dispersed on a slide glass with epoxy glue on and the water contact angle on the surface was determined to be over $150^{\circ}$, which is called superhydrophobic. FT-IR spectroscopy was used to check the functional group on silica nanoparticle surface before and after PDMS coating. Then, PDMS coated silica nanoparticles were used to selectively remove oil and toluene from water, respectively. It was demonstrated that PDMS coated nanoaprticles selectively aggregates with oil and toluene in the water and floats in the form of gel and this gel remained floating over 7 days. Furthermore, column filled with hydrophobic PDMS coated silica nanoparticles and hydrophilic porous silica was prepared and tested for simultaneous removal of water-soluble and organic pollutant from water. PDMS coated silica nanoparticles have strong resistibility for water and has affinity for oil and organic compound removal. Therefore PDMS-coated silica nanoparticles can be applied in separating oil or organic solvents from water.

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Preparing Hydrophobic Mesoporous Silica as an Effective Pre-concentration Agent Under Humid Condition

  • Park, Eun Ji;Cho, Youn Kyoung;Jeong, Myung-Geun;Kim, Dae Han;Jeong, Bora;Yoon, Hye Soo;Seo, Hyun Ook;Kim, Young Dok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.159.1-159.1
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    • 2014
  • We report a simple method for preparing hydrophobic mesoporous silica and its use as a pre-concentrating agent of gas analytes. Hydrophobic mesoporous silica was prepared by coating PDMS (polydimethylsiloxane) thin layer on commercial mesoporous silica with thermal deposition method in a sealed chamber. By using this method, we were able to coat PDMS layer on inner-walls of pores larger than 15 nm. Also, contact angle measured on a surface consisting of PDMS-coated mesoporous silica exceeded $150^{\circ}$, implying that the surface has high water repellency. Pre-concentration ability of PDMS-coated mesoporous silica and baremesoporous silica was tested under dry and humid conditions. Adsorption and molecular desorption of gas analytes was much enhanced by PDMS-coating on mesoporous silica under both dry and humid conditions. Therefore we suggest that PDMS-coated mesoporous silica can be an efficient pre-concentration agent in order to enhance sensitivity of various detectors.

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Enhancement in the Textural Properties and Hydrophobicity of Tetraethoxysilane-based Silica Aerogels by Phenyl Surface Modification

  • Dhavale, Rushikesh P.;Parale, Vinayak G.;Kim, Taehee;Choi, Haryeong;Kim, Younghun;Lee, Kyu-Yeon;Jung, Hae-Noo-Ree;Park, Hyung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.2
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    • pp.27-32
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    • 2020
  • Robust and hydrophobic tetraethoxysilane (TEOS) based silica aerogel was synthesized by supercritical alcohol drying with surface modification using the phenyl based silica co-precursor (PTMS). The aerogels were synthesized by hydrolysis and polycondensation reaction in which TEOS and PTMS in methanol were reacted together in presence of oxalic acid and ammonium hydroxide as the catalysts. Supercritical alcohol dried PTMS/TEOS composite silica aerogel were examined for the hydrophobicity, chemical interaction, surface morphology, and textural characteristics. The hydrophobic silica-based aerogels were characterized by Fourier transform infrared spectroscopy to investigate the presence of functional groups and chemical bonds. The prepared silica demonstrates hydrophobicity (76°-149°), a high specific surface area (398 ㎡/g to 739 ㎡/g). The present investigation provides a simple approach to synthesize hydrophobic and thermally stable silica aerogels.

Effect of Hydrophobic Coating on Silica for Adsorption and Desorption of Chemical Warfare Agent Simulants Under Humid Condition

  • Park, Eun Ji;Cho, Youn Kyoung;Kim, Dae Han;Jeong, Myung-Geun;Kim, Young Dok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.148.2-148.2
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    • 2013
  • We prepared hydrophobic PDMS-coated porous silica as pre-concentration adsorbent for chemical warfare agents (CWAs). Since CWAs can be harmful to human even with a small amount, detecting low-concentration CWAs has been attracting attention in defense development. Porous silica is one of the promising candidates for CWAs pre-concentration adsorbent since it is thermally stable and its surface area is sufficiently high. A drawback of silica is that adsorption of CWAs can be significantly reduced due to competitive adsorption with water molecule in air since silica is quite hydrophilic. In order to solve this problem, hydrophobic polydimethylsiloxane (PDMS) thin film was deposited on silica. Adsorption and desorption of chemical warfare agent (CWA) simulants (Dimethylmethylphosphonate, DMMP and Dipropylene Glycol Methyl Ether, DPGEM) on bare and PDMS-coated silica were studied using temperature programed desorption (TPD) with and without co-exposing of water vapor. Without exposure of water vapor, desorbed amount of DMMP from PDMS-coated silica was twice larger than that from bare silica. When the samples were exposed to DMMP and water vapor at the same time, no DMMP was desorbed from bare silica due to competitive adsorption with water. On the other hand, desorbed DMMP was detected from PDMS-coated silica with reduced amount compared to that from the sample without water vapor exposure. Adsorption and desorption of DPGME with and without water vapor exposing was also investigated. In case of bare silica, all the adsorbed DPGME was decomposed during the heating process whereas molecular DPGME was observed on PDMS-coated silica. In summary, we showed that hydrophobic PDMS-coating can enhance the adsorption selectivity toward DMMP under humid condition and PDMS-coating also can have positive effect on molecular desorption of DPGME. Therefore we propose PDMS-coated silica could be an adequate adsorbent for CWAs pre-concentration under practical condition.

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Influence of Hydrophobic Silica on Physical Properties of Epoxy Nanocomposites for Epoxy Molding Compounds (에폭시 몰딩 컴파운드를 위한 에폭시 나노복합재료의 소수성 실리카의 영향)

  • Kim, Ki-Seok;Oh, Sang-Yeob;Kim, Eun-Sung;Shin, Hun-Choong;Park, Soo-Jin
    • Elastomers and Composites
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    • v.45 no.1
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    • pp.12-16
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    • 2010
  • In this work, the effect of hydrophobic treated silica on the water absorption, thermal stabilities, and mechanical properties of the epoxy nanocomposites were investigated as a function of the silica content. As filler, fumed silica treated by dimethyldichlorosilane was used. It was found that the silica was well dispersed in the epoxy resins by the melt-mixing method with the addition of a silane coupling agent. The water absorption of the nanocomposites decreased with an increase of the silica content due to the effect of hydrophobic treated silica. The thermal properties, such as thermal degradation temperature, glass transition temperature ($T_g$), and coefficient of thermal expansion (CTE), of the nanocomposites were improved by the addition of silica. Furthermore, the mechanical properties of the nanocomposites, that is, the tensile strength and modulus, were enhanced with increasing silica content. This was attributed to the physically strong interaction between silica and epoxy resins.

Surface Modification of Silica Aerogels (실리카 에어로겔의 표면 개질)

  • 현상훈;이찬호;김동준
    • Journal of the Korean Ceramic Society
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    • v.33 no.12
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    • pp.1319-1324
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    • 1996
  • Silica aerogels were synthesis by the sol-gel-supercritical drying process using isopropanol as a solvent. Effets of the heat-treatment and the surface modification through propoxylation on the structural reinforcement as well as the surface hydrophobic/hydrophilic characteristics of aerogels were investigated. Silica aerogels synthesized by supercritical drying were hydrophobic but aerogels heat-treated above 20$0^{\circ}C$ were transformed to be hydrophilic. In particular it was found that the skeletal structure of aerogels heat-treated at 50$0^{\circ}C$ was strong enough not to crack after adsorbing a large amount of water vapor. Hydrophilic aerogels modified by propoxylation at 28$0^{\circ}C$ for 20 h were reversed to the hydrophobic form. Transition between hydrophobicity and hydrophilicity was reversible. The hydrophobicvity and the hydrophilicity of silica aerogels were attributed to the Si-Oh bond and the nonpolar C-H bond groups of orgainc species respectively.

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Analysis of PVDF Coating Properties with Addition of Hydrophobically Modified Fumed Silica

  • Lee, Nam Kyu;Kim, Young Hoon;Im, Tae Gyu;Lee, Dong Uk;Shon, MinYoung;Moon, Myung Jun
    • Corrosion Science and Technology
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    • v.18 no.6
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    • pp.232-242
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    • 2019
  • In this study, hydrophobically modified fumed silica was added to the PVDF coating to improve corrosion protection performance. Two types of silane modifiers, trimethylchlorosilane (TMCS) and hexamethyldisilazane (HMDZ), were used for hydrophobic modification of the fumed silica. The composition of modified fumed silica was analyzed by Fourier transform infrared, X-ray photoelectron spectroscopy, and elemental analysis. The dispersion of modified fumed silica in the PVDF coating was observed by the transmission electron microscopy, and the hydrophobicity of PVDF coating was analyzed by the water contact angle. Surface properties were examined by the field emission scanning electron microscopy and scanning probe microscopy. Potentiodynamic polarization was conducted to confirm corrosion protection performance of PVDF coating in terms of hydrophobically-modified fumed silica contents. As a result, the average surface roughness and the water contact angle of the PVDF coating increased with modifier contents. The results of the potentiodynamic polarization test showed an increase of the Ecorr values with increase of the hydrophobicity of PVDF coating. Thus, it clearly indicates that the corrosion protection performance of PVDF coating improved with the addition of the hydrophobic-modified fumed silica that prevents the penetration of moisture into the PVDF coating.

Silica/polymer Nanocomposite Containing High Silica Nanoparticle Content : Change in Proton Conduction and Water Swelling with Surface Property of Silica Nanoparticles (고농도의 Silica Nanoparticle을 함유한 Silica/polymer 나노복합체 : 실리카 표면 특성에 따른 수소이온 전도성 및 수팽윤도 변화)

  • Kim, Ju-Young;Kim, Seung-Jin;Na, Jae-Sik
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.514-521
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    • 2010
  • A new one-shot process was employed to fabricate proton exchange membranes (PEMs) over conventional solvent-casting process. Here, PEMs containing nano-dispersed silica nanoparticles were fabricated using one-shot process similar to the bulk-molding compounds (BMC). Different components such as reactive dispersant, urethane acrylate nonionmer (UAN), styrene, styrene sulfuric acid and silica nano particles were dissolved in a single solvent dimethyl sulfoxide (DMSO) followed by copolymerization within a mold in the presence of radical initiator. We have successfully studied the water-swelling and proton conductivity of obtained nanocomposite membranes which are strongly depended on the surface property of dispersed silica nano particles. In case of dispersion of hydrophilic silica nanoparticles, the nanocomposite membranes exhibited an increase in water-swelling and a decrease in methanol permeability with almost unchanged proton conductivity compared to neat polymeric membrane. The reverse observations were achieved for hydrophobic silica nanoparticles. Hence, hydrophilic and hydrophobic silica nanoparticles were effectively dispersed in hydrophilic and hydrophobic medium respectively. Hydrophobic silica nanoparticles dispersed in hydrophobic domains of PEMs largely suppressed swelling of hydrophilic domains by absorbing water without interrupting proton conduction occurred in hydrophilic membrane. Consequently, proton conductivity and water-swelling could be freely controlled by simply dispersing silica nanopartilces within the membrane.

Adsorption and Desorption of Chemical Warfare Agent Simulants on Silica Surfaces with Hydrophobic Coating

  • Park, Eun Ji;Kim, Young Dok
    • Bulletin of the Korean Chemical Society
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    • v.34 no.7
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    • pp.1967-1971
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    • 2013
  • Aim of our study is finding adsorbents suitable for pre-concentration of chemical warfare agents (CWAs). We considered Tenax, bare silica and polydimethylsiloxane (PDMS)-coated silica as adsorbents for dimethyl methylphosphonate (DMMP) and dipropylene glycol methyl ether (DPGME). Tenax showed lower thermal stability, and therefore, desorption of CWA simulants and decomposition of Tenax took place simultaneously. Silica-based adsorbents showed higher thermal stabilities than Tenax. A drawback of silica was that adsorption of CWA simulant (DMMP) was significantly reduced by pre-treatment of the adsorbents with humid air. In the case of PDMS-coated silica, influence of humidity for CWA simulant adsorption was less pronounced due to the hydrophobic nature of PDMS-coating. We propose that PDMS-coated silica can be of potential importance as adsorbent of CWAs for their pre-concentration, which can facilitate detection of these CWAs.

Effect of Hydrophobic Surface Coating on Flowability of Ceramic Tile Granule Powders (표면 소수화 처리를 통한 도자타일 과립 분말의 유동 특성)

  • Kim, Jin-Ho;Kim, Ung-Soo;Han, Kyu-Sung;Hwang, Kwang-Take
    • Korean Journal of Materials Research
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    • v.29 no.7
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    • pp.425-431
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    • 2019
  • Generally, ceramic tiles for building construction are manufactured by dry forming process using granular powders prepared by spray drying process after mixing and grinding of mineral raw materials. In recent years, as the demand for large ceramic tiles with natural texture has increased, the development of granule powders with high packing ratio and excellent flowability has become more important. In this study, ceramic tile granule powders are coated with hydrophobically treated silica nanoparticles. The effects of hydrophobic silica coating on the flowability of granule powders and the strength of the green body are investigated in detail. Silica nanoparticles are hydrophobically treated with GPTMS(3-glycidoxypropyl trimethoxy silane), which is an epoxy-based silane coupling agent. As the coating concentration increases, the angle of repose and the compressibility decrease. The tap density and flowability index increase after silica coating treatment. These results indicate that hydrophobic treatment can improve the flowability of the granular powder, and prevent cracking of green body at high pressure molding.