• 제목/요약/키워드: hydrophilic properties

검색결과 506건 처리시간 0.032초

Effect of Coloration on the Hydrophilicity and Swelling Properties of Poly-HEMA Hydrogels

  • Jang, Jin-Ho;Park, Hwa-Sung;Jeong, Yong-Kyun
    • 한국염색가공학회지
    • /
    • 제19권2호
    • /
    • pp.7-13
    • /
    • 2007
  • Photopolymerization of 2-hydroxyethyl methacrylate(HEMA), in the presence of ethyleneglycol dimethacrylate(EGDMA) and 1-Hydroxycyclohexyl phenyl ketone as crosslinker and photoinitiator, respectively, produced crosslinked poly-HEMA hydrogels. The hydrogels were colored by the exhaustion of vinylsul-phone-type reactive dyes. Good colorfastness to laundering was achieved when colored with C.I. Reactive Black 5. We investigated that the effect of coloration on the hydrophilicity and swelling properties of the films. More hydrophilic gel-surfaces were generated with in increase in coloration and crosslinking. Higher surface energy was observed with higher crosslinking level. The more rapid and higher water swellability of poly-HEMA gels after coloration may be resulted from a more opened gel structure by the easier hydration of the hydrophilic sulphonic acid groups of the reacted dyes in water.

Synthesis and Microphase Separation of Biodegradable Poly($\varepsilon$-caprolactone)-Poly(ethylene glycol)-Poly($\varepsilon$-caprolactone) Multiblock Copolymer Films

  • You, Jae-Ho;Choi, Sung-Wook;Kim, Jung-Hyun;Kwak, Young-Tae
    • Macromolecular Research
    • /
    • 제16권7호
    • /
    • pp.609-613
    • /
    • 2008
  • Poly($\varepsilon$-caprolactone)-poly(ethylene glycol)-poly($\varepsilon$-caprolactone) (PCL-PEG-PCL) multiblock copolymers at various hydrophobic-hydrophilic ratios were successfully synthesized by the chain extension of triblock copolymers through isocyanate (hexamethylene diisocyanate). Biodegradable films were prepared from the resulting multiblock copolymers using the casting method. The mechanical properties of the films were improved by chain extension of the triblock copolymers, whereas the films prepared by the triblock copolymers were weak and brittle. Atomic force microscopy (AFM) of the multiblock copolymer film showed that the hydrophilic PEG had segregated on the film surface. This is consistent with the observed contact angle of the films.

Photocatalytic and Hydrophilic Properties or $TiO_2$/$Fe_2O_3$ Composite Films

  • Liu, Q.J.;L, Q.;Wu, X.H.;Zhang, G.Q.;Gao, Z.Q.;Chen, G.X.
    • Journal of Korean Vacuum Science & Technology
    • /
    • 제6권1호
    • /
    • pp.40-42
    • /
    • 2002
  • TiO$_2$/Fe$_2$O$_3$composite thin films were prepared on common glass substrates by sol-gel processing and dip-drawing method. The effect of Fe$_2$O$_3$content on the photocatalytic and hydrophilic properties of composite films was studied. The results indicate that the photocatalytic activities of composite TiO$_2$films are superior to that of pure TiO$_2$film, and the film containing 0.5% Fe$_2$O$_3$has the best photocatalytic activity. The hydrophilicity is difference with variant Fe$_2$O$_3$content, the films containing 0.05% ~0.1% Fe$_2$O$_3$have the best hydrophilicity and their contact angles are 0。.

  • PDF

UV조사를 통한 PET의 표면개질 (제1보) -화학구조 변화 및 표면특성 변화- (Surface Modification of PET Irradiated by Ultra-Violet (Part I) -Transformation of Chemical Structure and Surface Properties-)

  • 최혜영;이정순
    • 한국의류학회지
    • /
    • 제29권3_4호
    • /
    • pp.561-568
    • /
    • 2005
  • The irradiation of Ultra-Violet (UV) is an efficient treatment for polymer to improve hydrophilic properties. 4-Channel PET knit fabrics were treated with UVA and UVC to develop functional and environment-friendly fabric. The fabric was treated with various treatment times and distances from UV lamps having different wavelength. FT-IR and XPS investigated the chemical changes. To confirm the change of surface properties, contact angle, surface energy and SEM were examined. The study of UV as a treatment for PET knit fabric shows significant changes in chemical and surface properties, which is proved by analyses. FT-IR and XPS analyses prove the augmentation of carboxylic, Hydrophilic groups on the surfaces treated by UV. The increase of water contact angle and surface energy means more water wettable and surface energy of PET film was substantially increased by UV irradiation time. The ageing after surface treatment had little influence on the surface energy of the irradiated PET film. SEM proves the surface modification of PET such as etching, bubble and crack. The negative effects are increased in accordance with increasing treatment time.

A Study of Optical Properties of Intraocular Lenses and of Measurement of the Index of Reflection for an Unknown Liquid

  • Joo, Won Don;Jung, Mee Suk
    • Journal of the Optical Society of Korea
    • /
    • 제16권3호
    • /
    • pp.236-242
    • /
    • 2012
  • In general, such methods as interferometers or wavefront sensors are commonly used for testing of an optical system and optical components. In these cases, the surrounding environments are unlikely to affect the measurements. On the other hand, intraocular lenses of hydrophilic materials with special properties experience a certain difficulty in testing the optical properties. An intraocular lens is dried in the air, which causes deformation and changes the optical characteristics such as index of refraction and thickness. Thus, it is hard to measure the optical characteristics of an intraocular lens by using common methods. In this study, a special structure is used for measuring of the transmission wavefront aberration and effective focal length of an intraocular lens of hydrophilic materials by using a Shark-Hartmann sensor among the various measuring methods. As an application of this measuring method, this study shows a simple method to measure the index of refraction of unknown liquids with a plano-convex lens with a well known index of refraction. Also, this method is used to measure the optical properties of a plano-convex such as index of refraction and curvature by using a liquid with a well known index of refraction.

Surface Treatment of Air Gap Membrane Distillation (AGMD) Condensation Plates: Techniques and Influences on Module Performance

  • Harianto, Rachel Ananda;Aryapratama, Rio;Lee, Seockheon;Jo, Wonjin;Lee, Heon Ju
    • Applied Science and Convergence Technology
    • /
    • 제23권5호
    • /
    • pp.248-253
    • /
    • 2014
  • Air Gap Membrane Distillation (AGMD) is one of several technologies that can be used to solve problems fresh water availability. AGMD exhibits several advantages, including low conductive heat loss and higher thermal efficiency, due to the presence of an air gap between the membrane and condensation wall. A previous study by Bhardwaj found that the condensation surface properties (materials and contact angle) affected the total collected fresh water in the solar distillation process. However, the process condition differences between solar distillation and AGMD might result in different condensation phenomena. In contrast, N. Miljkovic showed that a hydrophobic surface has higher condensation heat transfer. Moreover, to the best of our knowledge, there is no study that investigates the effect of condensation surface properties in AGMD to overall process performance (i.e. flux and thermal efficiency). Thus, in this study, we treated the AGMD condensation surface to make it hydrophobic or hydrophilic. The condensation surface could be made hydrophilic by immersing and boiling plate in deionized (DI) water, which caused the formation of hydrophilic aluminum hydroxide (AlOOH) nanostructures. Afterwards, the treated plate was coated using hexamethyldisiloxane (HMDSO) through plasma-enhanced chemical vapor deposition (PECVD). The result indicated that condensation surface properties do not affect the permeate flux or thermal efficiency significantly. In general, the permeate flux and thermal efficiency for the treated plates were lower than those of the non-treated plate (pristine). However, at a 1 mm and 3 mm air gap, the treated plate outperformed the non-treated plate (pristine) in terms of permeate flux. Therefore, although surface wettability effect was not significant, it still provided a little influence.

환경 및 섬유 특성이 멀티레이어 직물시스템의 투습성에 미치는 영향 (Effects of Relative Humidity and Fiber Properties on the Moisture Permeability of Multilayer Fabric Systems)

  • 이수현;박소현
    • 한국의류산업학회지
    • /
    • 제25권1호
    • /
    • pp.119-126
    • /
    • 2023
  • This study aimed to determine the effects of relative humidity and fiber properties on the moisture permeability of multilayer systems by measuring water vapor transmission in the overlapping condition of various fabrics. The results confirmed that the property of the fabric in contact with the humid environment affects the moisture permeability. If the layer facing the humid environment is hydrophobic and the layer facing the dry environment is superhydrophobic, water vapor transmission increases by up to 17.8% compared to the opposite conditions. Comparing the correction values of the water vapor transmission reflecting the thickness of the specimen under the multilayer condition showed that permeability was higher when the hydrophilic or hydrophobic layer was facing the humid environment. The opposite was true from the "push-pull" effect of absorption mechanism. In the case of moisture permeability, the more hydrophilic the surface facing the humid environment, the more permeable that water vapor diffuses and passes through. It was concluded that the "pull-push" effect, in which water vapor diffuses widely through the hydrophilic facing a humid environment and then passes through the hydrophobic layer, contributes to the improvement of permeability. Permeability differed according to the multilayer overlapping condition. When the relative humidity was high, the "pull-push" effect was insignificant. This is caused by water droplets absorption after the partial migration of water due to condensation. These results suggest that the overlapping conditions and properties of fabrics should vary depending on heavy sweating or not.

플라즈마 에칭공정에 따른 산화물 박막의 광촉매 표면 특성 (Photocatalyst Surface Properties of the Oxide Thin Films According to the Plasma Etching Process)

  • 이창현;서성보;오지용;진익현;손선영;김화민
    • 한국전기전자재료학회논문지
    • /
    • 제28권5호
    • /
    • pp.300-305
    • /
    • 2015
  • $WO_3$, $SiO_2$, and $TiO_2$ films with hydrophilic property are deposited by rf-magnetron sputtering. Their wettability is strongly depends on the presence or absence of the oxygen plasma etching on the glass substrates. The $TiO_2$ film of 50 nm-thick on the plasma etched glass shows a water contact angle (WCA) below $5^{\circ}$ which means a super-hydrophilic surface. However, WCA values are gradually degraded when the films are exposed under atmosphere, especially $WO_3$. In order to improve hydrophilic property, the degraded films can be again recovered by UV illumination for 10 sec using UV-light and the $TiO_2$ film shows a super-hydrophilic surface about $3^{\circ}$.