• Title/Summary/Keyword: hydrogen oxide

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Synthesis of Spinel Phase Manganese Oxide and Its Activation by Hydrogen Reduction (망간산화물의 합성과 수소환원에 의한 활성화)

  • Yang, Chun-Mo;Kim, Soon-Tae;Rim, Byung-O
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.1
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    • pp.49-53
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    • 2000
  • For decompose carbon dioxide, manganese oxide was synthesized with $0.25M-MnSO_{4}{\cdot}nH_{2}O$ and 0.5M-NaOH by coprecipitation. We made magnetite deoxidized manganese oxide by hydrogen reduction for 1hour at $330^{\circ}C$. We investigated characteristics of catalyst, hydrogen reduction degree and decomposition rate of carbon dioxide. The structure of the hausmannite certified spinel type. The specific surface area of synthesized hausmannite and deoxidized hausmannite were $22.36m^{2}/g$, $33.56m^{2}/g$ respectively. The decomposition rate of $CO_{2}$ of deoxidized hausmannite was 57%.

Effect of ARTEMISIAE ARGI FOLIUM Acupuncture Solution on Raw 264.7 Cells Treated by Toxicants (애엽(艾葉) 약침액(藥鍼液)이 에탄올 등에 의한 마우스 대식세포의 활성변화에 미치는 영향)

  • Park, Wan-Su
    • Korean Journal of Acupuncture
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    • v.25 no.3
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    • pp.137-146
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    • 2008
  • Objectives : The leaves of Artemisia argyi L. have been used for the treatment of bleeding-related diseases in traditional korean medicine. But the immunological activities with macrophage have not been sufficiently reported. This study is to investigate the immunological bioactivities of the herbal acupuncture solution obtained from leaves of Artemisia argyi L. (AAAS). Methods & Results : Against Nicotine and Acetaldehyde, AAAS increased significantly the production of hydrogen peroxide (H2O2) within mouse macrophage Raw 264.7 cells above the concentration of 10 ${\mu}g/m{\ell}$. AAAS increased significantly the production of nitric oxide (NO) in Raw 264. 7 cells above the concentration of 100 ${\mu}g/m{\ell}$ against EtOH. And AAAS increased significantly the production of nitric oxide (NO) in Raw 264. 7 cells above the concentration of 200 ${\mu}g/m{\ell}$ against Nicotine, Acetaminophen, and Acetaldehyde. Conclusions : These results suggest that AAAS could be thought to have the immunological activities related with the production of hydrogen peroxide and NO in macrophage.

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An Experimental Study on Underwater Wet Arc Welding and Weldability (TMCP강의 수중 ARC용접 실험과 용접성)

  • 오세규;김민남
    • Journal of Ocean Engineering and Technology
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    • v.1 no.2
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    • pp.67-73
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    • 1987
  • The feasibility for a practical use of underwater wet arc welding process is experimentally investigated by using low hydrogen and high oxide type electrodes and TMCP steel plates. Main results are summarized as follows: 1)The absorption speed of the coated low hydrogen and high titanium oxide type eletrodes becomes constant after about 30 minutes in water, and more steeping time in water does not influnce welding arc behavior. 2) By bead appearance and X-ray inspection, the high titanium oxide type electrode is better than the low hydrogen type in underwater arc welding process. 3) The mechanical properties of underwater wet arc welds depend upon welding conditions more than those of in-air welds, and the optimum welding condition can be obtained. 4) Because of quenching effect by rapid cooling rate in underwater wet welding, the maximum hardness of HAZ is increased relatively higher in underwater wet welding, process.

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Analysis of Oxide Film on X65-Line Pile Steel Formed in Hydrogen Induced Cracking Environment by Dynamic Nano-indentation Method (동적 나노압칩법을 이용한 수소유기균열분위기에서 생성된 X65-석유수소용 강관의 산화막 분석)

  • O, Se-Beom;Gang, Bo-Gyeong;Lee, Sang-Heon;Choe, Yong;Kim, Wan-Geun;Go, Seong-Ung;Jeong, Hwan-Gyo;Lee, Chang-Seon
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.155-155
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    • 2014
  • The oxide film was formed in hydrogen induced cracking (HIC) environment by potentio-dynamic method. Corrosion potentials and rates of the X-65 and X-80 line pipe steels were -0.3495 $V_{SHE}$, $2.833{\times}10^{-3}A/cm^2$ and 0.2716 $V_{SHE}$ and $2.533{\times}10^{-3}A/cm^2$, respectively. Surface composition analysis of the oxide film contained sulfur. Thermodynamic analysis of the HIC solution chemistry suggested that the oxide phase consisted of iron sulfate. Dynamic nano-indentation method applied to determine nano-hardnesses of the oxide film and base metal hardness.

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Surface Renewable Hydrogen Ion-Selective Polymeric Composite Electrode Containing Iridium Oxide

  • Quan, Hongmei;Kim, Won;Chung, Koo-Chun;Park, Jong-Man
    • Bulletin of the Korean Chemical Society
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    • v.26 no.10
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    • pp.1565-1568
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    • 2005
  • A surface renewable pH electrode was prepared by utilizing composite electrode technique. Iridium oxide micro-fine particles was prepared by hydrolysis of $(NH_4)_2IrCl_6$ at elevated temperature. The iridium oxide particles were mixed with well-dispersed carbon black and then filtered. The mixture was suspended in DMF containing PVC as a binder. The mixture was precipitated rapidly by adding large amount of water. The precipitate was ground and pressure-molded to iridium oxide composite electrode material. The electrode showed linear response between pH 1-13 with 50 to 60 mV/pH slope. The electrode maintained the pH response without appreciable slope drift for 170 days if stored in deionized water. The electrode surface can be renewed reproducibly by simple grinding process whenever contaminated or deactivated.

Trap Generation during SILC and Soft Breakdown Phenomena in n-MOSFET having Thin Gate Oxide Film (박막 게이트 산화막을 갖는 n-MOSFET에서 SILC 및 Soft Breakdown 열화동안 나타나는 결함 생성)

  • 이재성
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.41 no.8
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    • pp.1-8
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    • 2004
  • Experimental results are presented for gate oxide degradation, such as SILC and soft breakdown, and its effect on device parameters under negative and positive bias stress conditions using n-MOSFET's with 3 nm gate oxide. The degradation mechanisms are highly dependent on stress conditions. For negative gate voltage, both interface and oxide bulk traps are found to dominate the reliability of gate oxide. However, for positive gate voltage, the degradation becomes dominated mainly by interface trap. It was also found the trap generation in the gate oxide film is related to the breakage of Si-H bonds through the deuterium anneal and additional hydrogen anneal experiments. Statistical parameter variations as well as the “OFF” leakage current depend on both electron- and hole-trapping. Our results therefore show that Si or O bond breakage by tunneling electron and hole can be another origin of the investigated gate oxide degradation. This plausible physical explanation is based on both Anode-Hole Injection and Hydrogen-Released model.

Characteristics of Redox Agent with Additive in Steam-Iron Process for the High Purity Hydrogen Production (고순도 수소 생성을 위한 SIP법에서 첨가제에 따른 환원 특성)

  • Jeon, Bup-Ju;Kim, Sun-Myung;Park, Ji-Hun
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.3
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    • pp.340-348
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    • 2011
  • Effects of various inorganic-metal oxide (Zr, Zn, Si, Al and Ca as promoters and stabilizers) additive on the reduction rate of iron oxide and the composition of forming hydrogen using the steam-iron cycle operation was investigated. The reduction rate of redox agent with additive was determined from weight change by TGA. The changes of weight loss and reduction rate according to redox agent with various additive affected the hydrogen purity and cycle stability of the process. The cyclic micro reactor showed that hydrogen purity exceeding 95% could be obtained by the water splitting with Si/Fe, Zn/Fe, Zr/Fe redox agents. The redox agents with these elements had an affect on redox cycle stability as a good stabilizer for forming hydrogen by the steam-iron process.

Room Temperature Hydrogen Sensor

  • Cho, Hyoung Jin;Zhang, Peng;Seal, Sudipta
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.51.3-51.3
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    • 2010
  • Due to the recent public awareness of global warming and sustainable economic growth, there has been a growing interest in alternative clean energy sources. Hydrogen is considered as a clean fuel for the next generation. One of the technical challenges related to the use of hydrogen is safe monitoring of the hydrogen leak during separation, purification and transportation. For detecting various gases, chemiresistor-type gas sensors have been widely studied and used due to their well-established detection scheme and low cost. However, it is known that many of them have the limited sensitivity and slow response time, when used at low temperature conditions. In our work, a sensor based on Schottky barriers at the electrode/sensing material interface showed promising results that can be utilized for developing fast and highly sensitive gas sensors. Our hydrogen sensor was designed and fabricated based on indium oxide (In2O3)-doped tin oxide (SnO2) semiconductor nanoparticles with platinum (Pt) nanoclusters in combination with interdigitated electrodes. The sensor showed the sensitivity as high as $10^7%$ (Rair/Rgas) and the detection limit as low as 30 ppm. The sensor characteristics could be obtained via optimized materials synthesis route and sensor electrode design. Not only the contribution of electrical resistance from the film itself but also the interfacial effect was identified as an important factor that contribute significantly to the overall sensor characteristics. This promises the applicability of the developed sensor for monitoring hydrogen leak at room temperature.

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Hydrogen Trapping Using Yttrium to Manage Hydrogen in HSLA Steel Welds (고장력강의 용접부에서 Yttrium을 이용한 수소의 트랩에 관한 연구)

  • Park, Yeong-Do
    • Proceedings of the KWS Conference
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    • 2005.06a
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    • pp.141-143
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    • 2005
  • Yttrium has been investigated as hydrogen trapping site in pure iron and HSLA steel welds. Assessment of hydrogen trapping parameters for yttrium oxide has also shown the high potential of yttrium addition to improve hydrogen management in high strength steel welding. The purpose of this study was to reduce and control the diffusible hydrogen content in the weld deposit.

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Syngas Production Based on Co-electrolysis of CO2 and H2O in Solid Oxide Electrolysis Cell (고체 산화물 CO2-H2O 공전해 기반 합성가스 생산 기술 )

  • NAMGI JEON;SANGHYEOK LEE;SANGKUK KIM;CHIKYU AHN;JIN SOO AHN
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.2
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    • pp.140-145
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    • 2024
  • High temperature co-electrolysis of H2O-CO2 mixtures using solid oxide cells has attracted attention as promising CO2 utilization technology for production of syngas (H2/CO), feedstock for E-fuel synthesis. For direct supply to E-fuel production such as hydrocarbon and methanol, the outlet gas ratio (H2/CO/CO2) of co-electrolysis should be controlled. In this work, current voltage characteristic test and product gas analysis were carried out under various reaction conditions which could attain proper syngas ratio.