• Title/Summary/Keyword: hydrogen generation

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Prediction of Life of Heat Pipes by Measuring Temperature Distribution (온도측정에 의한 히트파이프의 수명예측)

  • Shin, Hung Tae;Polasek, Frantisek;Lee, Yoon Pyo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.7
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    • pp.856-863
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    • 1999
  • The thermal performance degradation of heat pipes is caused by the non-condensable gas generation mainly due to the electrochemical corrosion which results from the reaction of working fluids with tube materials. In this study, a simplified method described below was proposed to estimate the life of heat pipes concerning the non-condensable gas generation. The temperature distributions at the outer surface of heat pipes was measured, and based on them the amount of non-condensable gas of hydrogen was estimated. Applying it to the Arrhenius model, the mass generation of hydrogen and the volume occupied by the gas In heat pipes could be estimated for an operating temperature and time. Moreover, this simplified method was applied to the accelerated life test of nine methanol-stainless steel heat pipe samples.

Development and Performance Test of SOFC Co-generation System for RPG (SOFC를 이용한 가정용 열병합 발전시스템 개발 및 성능시험)

  • Lee, Tae-hee;Choi, Jin-Hyeok;Park, Tae-Sung;Choi, Ho-Yun;Yoo, Young-Sung
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.361-364
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    • 2009
  • KEPRI has studied planar type SOFC stacks using anode-supported single cells and kW class co-generation systems for residential power generation. A 1kW class SOFC system consisted of a hot box part, a cold BOP part and a water reservoir. A hot box part contains a SOFC stack made up of 48 cells with $10{\times}10cm^2$ area and ferritic stainless steel interconnectors, a fuel reformer, a catalytic combustor and heat exchangers. Thermal management and insulation system were especially designed for self-sustainable operation. A cold BOP part was composed of blowers, pumps, a water trap and system control units. When a 1kW class SOFC system was operated at $750^{\circ}C$ with hydrogen, the stack power was 1.2kW at 30 A and 1.6kW at 50A. Turning off an electric furnace, the SOFC system was operated using hydrogen and city gas without any external heat source. Under self-sustainable operation conditions, the stack power was about 1.3kW with hydrogen and 1.2kW with city gas respectively. The system also recuperated heat of about 1.1kW by making hot water. Recently KEPRI developed stacks using $15{\times}15cm^2$ cells and tested them. KEPRI will develop a 5 kW class CHP system using $15{\times}15cm^2$ stacks by 2010.

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1D Kinetics Model of NH3-Fed Solid Oxide Fuel Cell (암모니아 공급 고체산화물 연료전지의 1D 반응 모델)

  • VAN-TIEN GIAP;THAI-QUYEN QUACH;KOOK YOUNG AHN;YONGGYUN BAE;SUNYOUP LEE;YOUNG SANG KIM
    • Journal of Hydrogen and New Energy
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    • v.33 no.6
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    • pp.723-732
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    • 2022
  • Cracking ammonia inside solid oxide fuel cell (SOFC) stack is a compact and simple way. To prevent sharp temperature fluctuation and increase cell efficiency, the decomposition reaction should be spread on whole cell area. This leading to a question that, how does anode thickness affect the conversion rate of ammonia and the cell voltage? Since the 0D model of SOFC is useful for system level simulation, how accurate is it to use equilibrium solver for internal ammonia cracking reaction? The 1D model of ammonia fed SOFC was used to simulate the diffusion and reaction of ammonia inside the anode electrode, then the partial pressure of hydrogen and steam at triple phase boundary was used for cell voltage calculation. The result shows that, the ammonia conversion rate increases and reaches saturated value as anode thickness increase, and the saturated thickness is bigger for lower operating temperature. The similar cell voltage between 1D and 0D models can be reached with NH3 conversion rate above 90%. The 0D model and 1D model of SOFC showed similar conversion rate at temperature over 750℃.

The policy study on the power grid operation strategy of new and renewable energy combined generation system (도서지역의 신재생에너지복합발전 전력계통 운영방안에 관한 정책연구)

  • Kim, Eui Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.109.1-109.1
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    • 2011
  • KEPCO was operating power plants with diesel generators in 49 islands including Baekryeong-Do, and the generation capacity was about 66 MW in 2008. The cost of fuel is increasing by the international oil price inflation and continuous rise of oil price is predicted. For the stabilizing of electric power supply to the separate islands, renewable energy and fuel cell systems were considered. Hydrogen is made using renewable energy such as wind power and solar energy, and then a fuel cell system generates electricity with the stored hydrogen. Though the system efficiency is low, it is treated as the only way to secure the stable electric supply using renewable energy at this present. The analytic hierarchy process was used to select suitable candidate island for the system installation and 5 islands including Ulleung-Do were selected. Economic evaluation for the system composed of a kerosene generator, a wind power, an electrolysis, and a fuel cell system was conducted with levelized generation cost based on present value methode. As the result, the necessity of renewable energy combined generation system and micro grid composition in the candidated islands was confirmed. Henceforth, the development of an integration technology which connects micro grid to the total power grid will be needed.

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Economic Evaluation on a private electric Generation Application in Unelectrified Remote Islands in Korea (미 전화 도서 자가 발전방식 도입에 따른 경제성 검토)

  • Ahn, Kyo-Sang;Lim, Hee-Chun;Eom, Young-Chang
    • Journal of Hydrogen and New Energy
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    • v.14 no.4
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    • pp.348-358
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    • 2003
  • According to Electricity Acceleration Law of Rural Area recently, the needs for replacement of a small scale diesel power generation facility which supplied electricity to 10-50 households Remote Islands has been revealed due to high operating and maintenance cost of Diesel Power Generation. Optimization of electric power system for Small Remote Islands must be made considering the economics, reliability and stability as power sources and estimation of total construction cost of those power stations. For its purpose, an assessment of power generation options such as Photovoltaic, Fuel cell, Wind-hybrid was implemented, economic evaluation of power supply shows the Photovoltaic, Fuel Cell for few household's islands and Diesel, Wind-hybrid for more inhabited islands. Power supplied by Diesel shows the best response to increasing electric demand and system reliability even with its lower economic value. Those who are in charge of power planning have to pay attention to system reliability, stability and operating characteristics of candidate's power supply besides its economics.

Performance Characteristics of a Combined Regenerative Ammonia-Water Based Power Generation Cycle Using LNG Cold Energy (LNG 냉열을 이용하는 암모니아-물 복합 재생 동력 사이클의 성능 특성)

  • Kim, Kyounghoon;Oh, Jaehyeong;Jeong, Youngguan
    • Journal of Hydrogen and New Energy
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    • v.24 no.6
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    • pp.510-517
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    • 2013
  • The ammonia-water based power generation cycle utilizing liquefied natural gas (LNG) as its heat sink has attracted much attention, since the ammonia-water cycle has many thermodynamic advantages in conversion of low-grade heat source in the form of sensible energy and LNG has a great cold energy. In this paper, we carry out thermodynamic performance analysis of a combined power generation cycle which is consisted of an ammonia-water regenerative Rankine cycle and LNG power generation cycle. LNG is able to condense the ammonia-water mixture at a very low condensing temperature in a heat exchanger, which leads to an increased power output. Based on the thermodynamic models, the effects of the key parameters such as source temperature, ammonia concentration and turbine inlet pressure on the characteristics of system are throughly investigated. The results show that the thermodynamic performance of the ammonia-water power generation cycle can be improved by the LNG cold energy and there exist an optimum ammonia concentration to reach the maximum system net work production.

Analysis of the Operating Point and Fault Current Contribution of a PEMFC as Distributed Generation (DG)

  • Moon, Dae-Seong;Kang, Gi-Hyeok;Chung, Il-Yop;Won, Dong-Jun
    • Journal of Electrical Engineering and Technology
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    • v.4 no.3
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    • pp.382-388
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    • 2009
  • Recently, hydrogen energy has been anticipated to change the paradigm of conventional power systems because it can expand sustainable energy utilization and conceptually provide remarkable flexibility to power system operation. Since hydrogen energy can be converted to electric energy through fuel cells, fuel cells are expected to play an important role in the future hydrogen economy. In this paper, a Proton Exchange Membrane Fuel Cell (PEMFC) is modeled as an equivalent circuit and its steady-state characteristics investigated using the model. PEMFCs can be connected to power systems through power conditioning systems, which consist of power electronic circuits, and which are operated as distributed generators. This paper analyzes the effects of the characteristics of the PEMFC internal voltages and investigated the dynamic responses of the PEMFC under fault conditions. The results show that the fault current contribution of the PEMFC is different from those of conventional generators and is closely related to its operating point.

Thermal Behavior of NiFe2O4 for Hydrogen Generation (NiFe2O4를 이용한 열화학 사이클 H2 제조)

  • Han, S.B.;Kang, T.B.;Joo, O.S.;Jung, K.D.
    • Journal of Hydrogen and New Energy
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    • v.14 no.4
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    • pp.298-304
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    • 2003
  • The thermal behavior of $NiFe_2O_4$ prepared by a solid-state reaction was investigated for $H_2$ generation by the thermochemical cycle. The reduction of $NiFe_2O_4$ started from $800^{\circ}C$, and the weight loss was 0.2-0.3 wt% up to $1000^{\circ}C$. In the $H_2O$ decomposition reaction, $H_2$ was generated by oxidation of reduced $NiFe_2O_4$. The crystal structure of $NiFe_2O_4$ maintained during the redox reaction of 5 cycles. From this observation, the lattice oxygen in $NiFe_2O_4$ is released without the structural change during the thermal reduction and oxygen deficient $NiFe_2O_4$ can be restored to the spinel structure of $NiFe_2O_4$.

Noise Generation by Water-Sodium Reaction and its Absorption on Hydrogen Bubbles for KALIMER Steam Generator (칼리머 증기발생기에서 물-소듐 반응에 의한 소음 발생과 수소 기포의 소음 흡수)

  • Kim, Tae-Joon;Yughay, Valeri S.;Hwang, Sung-Tai
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.06a
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    • pp.1829-1835
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    • 2000
  • The experimental results of sodium-water reaction noise measurement in frequency range $1{/sim}200kHz$ are presented. The experiments of noise generation under the condition of sodium test facility, water leak rate $0.01{\sim}1.2g/s$ and temperature of sodium $250{\sim}500^{\circ}C$, were carried out. From theoretical study it is noted that the noise resonant attenuation on hydrogen bubbles in liquid sodium plays the significant role for leak noise spectra formation. Interaction of leak noise and hydrogen bubbles in sodium being accompanied by thermal, emission and viscosity energy dissipation was studied. Acoustic noise spectra were investigated from point of view of water leak detection in sodium/water steam generator. The results of sodium-water reaction noise absorption on hydrogen bubbles in liquid sodium by temperature $250{\sim}500^{\circ}C$ are presented. The theoretical model of noise absorption using the coefficients of attenuation was developed. From calculation the coefficients of attenuation were estimated.

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Temperature Changes of Cryogenic Fluid Flow in Pipe Bends due to Viscous Heating Effect (점성가열 효과에 의한 곡관 내 극저온 유체의 온도 변화)

  • HYO LIM KANG;IN JAE KO;SEUNG HO HAN
    • Journal of Hydrogen and New Energy
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    • v.35 no.4
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    • pp.428-436
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    • 2024
  • Liquid hydrogen, which operates in cryogenic environments has a density 800 times greater than gaseous hydrogen, making it advantageous for large-scale storage and transportation. However, continuous evaporation due to external heat intrusion and internal heat generation poses challenges. To mitigate heat conduction, various insulation materials are used. In pipe systems, viscous heating effects from turbulence and viscosity, especially in bends, cause heat generation. This study employs computational fluid dynamics (CFD) to analyze the impact of fluid velocity, pressure drop, inner diameter, and curvature radius of pipe bends on viscous heating. Using liquid nitrogen at 77 K as a working fluid, the CFD results showed that increased velocity and pressure drop along with smaller inner diameter and curvature radius enhanced viscous heating, raising fluid temperature.