• 한국수소및신에너지학회논문집
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• 제34권6호
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• pp.594-600
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• 2023

In this study, a process model and optimization design direction for a hydrogen production plant through ammonia decomposition are presented. If the reactor decomposition rate is designed to approach 100%, the amount of catalyst increases and the devices that make up the entire system also have a large design capacity. However, if the characteristics of the hydrogen regeneration process are reflected in the design of the reactor, it becomes possible to satisfy the total flow rate of fuel gas with the discharged tail gas flow rate. Analyzing the plant process simulation results, it was confirmed that when an appropriate decomposition rate is maintained in the reactor, the phenomenon of excess or shortage of fuel gas disappears. In addition, it became possible to reduce the amount of catalyst required and design the optimized capacity of the relevant processes.

• 한국수소및신에너지학회논문집
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• 제9권3호
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• pp.93-100
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• 1998

The ortho-para $H_2$ catalytic conversion equipment has been developed to reduce the evaporation loss from stored liquid hydrogen. The ortho-para $H_2$ conversion heat is evaluated at liquid nitrogen temperature. This problem is of particular interest in the design of the ortho-para $H_2$ converter in a hydrogen liquefaction system. The ortho-para $H_2$ conversion equipment consists of a catalytic converter, a precooler, and a liquid nitrogen bath. 30-90 cc of $Fe(OH)_3$ are employed as a catalyst in the present converter. The conversion heat and conversion effectiveness are evaluated when mass flow rate of hydrogen is in the range of 0.05-l.6 g/min. It is found that the ortho-para conversion heat is increased while conversion effectiveness is decreased as the mass flow rate of hydrogen is increased. Both the ortho-para conversion heat and conversion effectiveness are increased with an increase in the amount of the catalyst.

• 한국수소및신에너지학회논문집
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• 제26권4호
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• pp.301-307
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• 2015

We present a study of hydrogen liquefaction using the CFD (Computational Fluid Dynamics) program. Liquid hydrogen has been evaluated as the best storage method because of high energy per unit mass than gas hydrogen, but efficient hydrogen liquefaction and storage are needed in order to apply actual industrial. In this study, we use the CFD program that apply navier-stokes equation. A hydrogen is cooled by heat transfer with the while passing gas hydrogen through Cu tube. We change diameter and flow rate and observe a change of the temperature and flow rate of gas hydrogen passing through Cu tube. As a result of, less flow rate and larger diameter are confirmed that liquefaction is more well. Ultimately, When we simulate the hydrogen liquefaction by using CFD program, and find optimum results, it is expected to contribute to the more effective and economical aspects such as time and cost.

• 한국수소및신에너지학회논문집
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• 제34권5호
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• pp.439-446
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• 2023

In this study, the computational fluid dynamics (CFD) simulations were conducted to verify the cooling capacity of the cryocooler used for pre-cooling of hydrogen gas. Based on the experimental results, the effect of the flow rate on a copper pipe attached to the bottom of the cryocooler was investigated. In this study, the temperature data was calculated through the change of boundary condition for heat flux in the copper pipe. In addition, the cooling capacity of the cryocooler for pre-cooling hydrogen gas was considered by calculating the cooling temperature according to the flow rate in the certified operating range. Consequently the pre-cooing system for hydrogen gas was validated with a reasonable accuracy through CFD simulations.

• 한국수소및신에너지학회논문집
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• 제33권6호
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• pp.803-807
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• 2022

In this study, the battery performance change according to the change of electrolyte flow rate. With increase of electrolyte flow rate the energy efficiency showed tendency of decrease. The electrochemical impedance spectroscopy results showed the increased resistance.

• 한국수소및신에너지학회논문집
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• 제8권1호
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• pp.5-10
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• 1997

Because of environmental pollution and reserve limitations of fossil fuels, several alternative energies have been developing. One of them, the hydrogen is researched as a highly probable solution. In this study pure hydrogen gas and oxygen gas are burned in combustor to reduce the emission, and a gas turbine is used. Cooling water around the combustor recovers the cooling heat loss to useful work by being expanded from liquid to vapor, being injected into the combustor and making pressure rise with working fluid to get more turbine power. Because pure hydrogen and oxygen are used, there is no carbonic emission such as CO, $CO_2$, HC nor $NO_x$, and $SO_x$. The power is obtained by turbine system, which makes lower noise and vibration than any reciprocating engine. Running of a turbine is searched under various conditions of hydrogen flow rate and water injection rate. Maximum speed of the turbine is obtained when the combustion reaches steady state. It is enable to determine the optimum rate between hydrogen flow and water injection which makes turbine run maximum speed.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.3003-3008
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• 2007

Critical nozzle has been frequently employed to measure the flow rate of various gases, but hydrogen gas, especially being at high-pressure condition, was not nearly dealt with the critical nozzle due to treatment danger. According to a few experimental data obtained recently, it was reported that the discharge coefficient of hydrogen gas through the critical nozzle exceeds unity in a specific range of Reynolds number. No detailed explanation on such an unreasonable value was made, but it was vaguely inferred as real gas effects. For the purpose of practical use of high-pressure hydrogen gas, systematic research is required to clarify the critical nozzle flow of high-pressure hydrogen gas. In the present study, a computational fluid dynamics(CFD) method has been applied to predict the critical nozzle flow of high-pressure hydrogen gas. Redlich-Kwong equation of state that take account for the forces and volume of molecules of hydrogen gas were incorporated into the axisymmetric, compressible Navier-Stokes equations. A fully implicit finite volume scheme was used to numerically solve the governing equations. The computational results were validated with some experimental data available. The results show that the coefficient of discharge coefficient is mainly influenced by the compressibility factor and the specific heat ratio, which appear more remarkable as the inlet total pressure of hydrogen gas increases.

• 한국표면공학회지
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• 제29권6호
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• pp.695-702
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• 1996

Plasma spraying process was employed to produce HA coating on Ti6A14V alloy for the development of a dental implant. The goal of this research was to find optimum spraying conditions for HA coating on Ti6Al4V. This study was thus designed carefully to evaluate how spraying parameters affect various physical properties of a HA coating layer, such as phase composition and bond strength. In plasma spraying, spraying parameters such as hydrogen flow rates and spraying distances were varied systematically to change the degree of the melting of starting HA powder in plasma jet. It was revealed that the deposition efficiency increased with increasing a hydrogen flow rate, and the bond strength between the HA-coated layer and Ti-alloy substrate increased with hydrogen flow rate, but decreased with spraying distance. Therefore, the hydrogen flow rate and the spraying distance should be carefully controlled to obtain the reasonable bond strength simultaneously.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2010년도 하계학술대회 논문집
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• pp.262-262
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• 2010

To investigate the effect of the amount of hydrogen on CVD grown-graphene, the flow rate of hydrogen was changed, while other process parameters were kept constant during CVD synthesis. Substrate which consists of 300nm-nickel/$SiO_2$/Si substrate, and methane gas mixed with hydrogen and argon were used for CVD growth. Graphene was synthesized at $950^{\circ}C$. The thickness and the defect of graphene were analyzed using raman spectroscopy. The synthesized graphene shows non-uniform and more defective below a certain amount of hydrogen.

• 한국수소및신에너지학회논문집
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• 제10권1호
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• pp.19-26
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• 1999

수소 액화시스템의 중요한 구성요소인 열교환기를 이중관 형태로 설계 제작하여 극저온 영역에서의 유용도를 실험적으로 측정하였다. 이중관 열교환기의 내관과 내 외관 사이의 환상 공간으로 수소를 공급하고, 온도와 압력, 유량을 측정하였다. 측정된 온도와 유량으로부터 유용도를 환산한 결과, 열교환면적이 증가함에 따라 열교환기의 유용도는 증가하였다. 또한 저온 수소와 고온 수소의 열용량비가 감소함에 따라 열교환기의 유용도는 증가하나 유용도의 증가폭은 감소하였다. 따라서 본 연구에서는 수소 액화시스템에 필요한 유용도를 얻기 위한 열교환기의 길이 및 열용량비의 선정 기준을 제시하였다.