• Title/Summary/Keyword: hydrogen explosion

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Poly(vinyl alcohol)-based Polymer Electrolyte Membrane for Solid-state Supercapacitor (고체 슈퍼캐퍼시터를 위한 폴리비닐알콜 고분자 전해질막)

  • Lee, Jae Hun;Park, Cheol Hun;Park, Min Su;Kim, Jong Hak
    • Membrane Journal
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    • v.29 no.1
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    • pp.30-36
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    • 2019
  • In this study, we reported a solid-state supercapacitor consisting of titanium nitride (TiN) nanofiber and poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT-PSS) conducting polymer electrode and poly(vinyl alcohol) (PVA)-based polymer electrolyte membrane. The TiN nanofiber was selected as electrode materials due to high electron conductivity and 2-dimensional structure which is beneficial for scaffold effect. PEDOT-PSS is suitable for organic/inorganic composites due to good redox reaction with hydrogen ions in electrolyte and good dispersion in solution. By synergetic effect of TiN nanofiber and PEDOT-PSS, the PEDOT-PSS/TiN electrode showed higher surface area than the flat Ti foil substrate. The PVA-based polymer electrolyte membrane could prevent leakage and explosion problem of conventional liquid electrolyte and possess high specific capacitance due to the fast ion diffusion of small $H^+$ ions. The specific capacitance of PEDOT-PSS/TiN supercapacitor reached 75 F/g, which was much higher than that of conventional carbon-based supercapacitors.

Design and evaluation of an innovative LWR fuel combined dual-cooled annular geometry and SiC cladding materials

  • Deng, Yangbin;Liu, Minghao;Qiu, Bowen;Yin, Yuan;Gong, Xing;Huang, Xi;Pang, Bo;Li, Yongchun
    • Nuclear Engineering and Technology
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    • v.53 no.1
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    • pp.178-187
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    • 2021
  • Dual-cooled annular fuel allows a significant increase in power density while maintaining or improving safety margins. However, the dual-cooled design brings much higher Zircaloy charge in reactor core, which could cause a great threaten of hydrogen explosion during severe accidents. Hence, an innovative fuel combined dual-cooled annular geometry and SiC cladding was proposed for the first time in this study. Capabilities of fuel design and behavior simulation were developed for this new fuel by the upgrade of FROBA-ANNULAR code. Considering characteristics of both SiC cladding and dual-cooled annular geometry, the basic fuel design was proposed and preliminary proved to be feasible. After that, a design optimization study was conducted, and the optimal values of as-fabricated plenum pressure and gas gap sizes were obtained. Finally, the performance simulation of the new fuel was carried out with the full consideration of realistic operation conditions. Results indicate that in addition to possessing advantages of both dual-cooled annular fuel and accident tolerant cladding at the same time, this innovative fuel could overcome the brittle failure issue of SiC induced by pellet-cladding interaction.

Impact Resistance Characteristics of Cementitious Composites Subjected to High-velocity Projectiles with Reinforcement Types (고속 발사체와 충돌한 시멘트복합체의 보강재 종류에 따른 내충격 특성 연구)

  • Seok, Won-Kyun;Kim, Young-Sun;Lee, Yae-Chan;Nam, Jeong-Soo;Kim, Gyu-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.3
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    • pp.261-272
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    • 2023
  • This research concentrates on the potential explosion hazards that could arise from unforeseen accidents in the rapidly proliferating hydrogen refueling stations and Energy Storage System(ESS) facilities. It underscores the pivotal role of structural protection technology in alleviating such risks. The research contributes primary data for the formulation of structure protection design by assessing the impact resistance across various reinforcement techniques used in cement composites. The experimental results elucidate that reinforced concrete, serving as the quintessential structural material, exhibits a 20% advancement in impact resistance in comparison to its non-reinforced counterpart. In situations typified by rapid loads, such as those seen with high-velocity impacts, the reinforcement of the matrix with fibers is demonstrably more beneficial than local reinforcement. These insights accentuate the importance of judiciously choosing the reinforcement method to augment impact resistance in structural design.