• Journal of Korean Vacuum Science & Technology
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• v.3 no.1
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• pp.24-29
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• 1999

The characteristic behaviors of CH3Br were examined first for the dry etching of polysilicon in a Cl2/CH3Br/O2 plasma. CH3Br is revealed one of the excellent additive gases to control anisotropy of etching profile and to give no undercutting for various typed of polysilicons. CH3Br acts as a passivation precursor on the side wall in etch cavity by forming polymer-like films such as CHxBry(x+y=1,2). The decrease of etch selectivity due to the reaction if the C-containing species from CH3Br with the surface O atoms of SiO2 was overcome by the addition of O2 into plasma, resulting that the selectivity increased by 2~3 times. According to the results of optical emission signals, CH3Br should be dissociated into several fragments to give more hydrogen atoms than bromine atoms in our helical resonator system.

• 한국신재생에너지학회:학술대회논문집
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• 2009.11a
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• pp.217-217
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• 2009

In this work, the oxidation-induced characteristics of five nuclear graphites (NBG-17, NBG-18, NBG-25, IG-110, and IG-430) were studied. The oxidation characteristics of nuclear graphites were measured at the three temperature areas (300, 600, and $900^{\circ}C$). As experimental results, the pore size of oxidized graphite was increased with increasing of oxidation time. It was also found that the oxdation rate was propotional to the oxidation temperature and time. This was probably due to the oxidation was occurred on the surface and inner bulk phase of nuclear graphites at the same time by the socalled chemical regime.

• Journal of Powder Materials
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• v.9 no.4
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• pp.203-210
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• 2002

A new PIM in-process joining technique has been developed for more complicated and functional PIM components by application of the exuded wax from the green compacts during solvent debinding step. At first, various stainless steels and iron compacts with rectangular shape were combined, and the joining behaviors and properties were investigated by shear and tensile test, and microscopic observation. Subsequently, perfect joined three pieces of thin and hollow compacts were obtained for the combination of same and different stainless steels, and it was difficult to join the iron and stainless steel compacts in hydrogen atmosphere because of the different starting temperature of shrinkage. However, pretty good joined iron and stainless steel compacts were obtained by consideration of particle size and vacuum atmosphere. Finally, for the combination of ferro-silicon and austenitic stainless steel compacts, high functionality (magnetic (1.60Tes1a) & non-magnetic) and perfect joint were obtained.

• Bulletin of the Korean Chemical Society
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• v.31 no.10
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• pp.2913-2917
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• 2010

When rubber dissolved in toluene was used as a binding material of graphite powder, the mechanical robustness of the carbon paste was guaranteed by the fast volatility of the solvent immediately after electrode construction. This characteristic of the rubber solution met qualifications for practical use of carbon paste electrodes and enabled the design of a new enzyme electrode bound with EPDM. In order to confirm whether the electrode shows quantitative electrochemical behaviors or not, its kinetic parameters, e. g. the symmetry factor (0.2), the exchange current density ($3.66\;{\mu}A/cm^2$), the capacity of the double layer ($2.0{\times}10^{-5}\;F$), the Michaelis constant ($4.39{\times}10^{-3}\;M$), the diffusion coefficient of substrate ($2.58{\times}10^{-12}\;cm^2/sec$), the time constant (0.018 sec) and other factors were investigated.

• Journal of the Korean Ceramic Society
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• v.43 no.10 s.293
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• pp.613-618
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• 2006

Graphite is suitable materials as a moderator, reflector, and supporter of a nuclear reactor because of high tolerance to the high temperature and neutron irradiations. Because graphite is so weak to the oxidation, its oxidation study is essentially demanded for the operation and design of the nuclear reactor. This work focuses on the effect of the surface oxidation of graphite according to the surface treatment. With thermogravimeter (TG), oxidation characteristics of the isotropic graphite are measured at the three temperature areas, and oxidation ratio and amounts are estimated as changing the surface roughness. Furthermore, the polished graphite surface produced fom the surface treatment is investigated with the Raman spectroscopic study. Oxidation behaviors of the surface are also evaluated as elimination the polished layer by washing with strong sonication.

• Journal of the Korean Ceramic Society
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• v.43 no.12 s.295
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• pp.833-838
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• 2006

Graphite is suitable for high temperature structural materials because of chemical stability as well as unique crystal structure. Especially, graphite can be used as a part of a nuclear reactor due to high tolerance at the extreme conditions of high temperature and neutron irradiations. Although study of oxidation properties or behaviors of graphite are very important and essential for the life and stability of the nuclear reactor, most of studies treat this theme lightly. This work focuses on the oxidation characteristics of several grade isotropic graphite of the nuclear reactor.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2000.11a
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• pp.3-8
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• 2000

Chemical nature of nascent metal surfaces which is one of the important active sources for tribochemical reactions was investigated using a newly developed method. Some enhanced activities were observed. For example, organic compounds chemisorbed on nascent gold surfaces and aromatic compounds decomposed on nascent nickel surfaces resulting in hydrogen evolution. Non-polar compounds such as organic sulfides had a higher chemisorption activity on nascent steel surfaces than polar compounds such as fatty acids and phosphates. Organic sulfides reacted directly with nascent steel surfaces and the surface was covered with metal sulfides. The activity for the chemisorption of organic compounds was closely dependent on the electronic structure of metals. Although benzene chemisorbed very easily on nascent surfaces of transition metals, it did not chemisorb ell nascent surfaces of simple metals. Boundary lubricating behaviors of extreme pressure additives were explained on the bases of the chemical activities of nascent surfaces obtained in this investigation. Under mild conditions, polar compounds such as fatty acids and phosphates were effective for boundary lubrication, because surfaces are covered with oxide layers. On the other hand, sulfides were more effective under severe conditions where the oxide layers were removed and the nascent surfaces were formed.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1999.05a
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• pp.89-93
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• 1999

Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value(LCV) gas fuel. Synthetic LCV fuel gas is produced through mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas, and then the syngas mixture is fed to and burnt with air on flat flame burner. Flame behaviors are observed to identify flame instability due to blow-off or flash-back when burning the LCV fuel gas at various equivalence ratio conditions. Measurements of NOx in combustion gas are made for comparing thermal and fuel NOx emissions from the LCV syngas combustion with those of the natural gas one, and for analyzing ammonia to NOx conversion mechanism. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.1
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• pp.85.2-85.2
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• 2019

We developed a new grid-based Monte Carlo code to trace far UV He II line photons that are incident on a thick H I region and subsequently transferred through Rayleigh and Raman scattering with atomic hydrogen. In particular, we consider a neutral region that is moving away from the He II emission source which is either monochromatic or is described by a Gaussian profile. The resultant Raman scattered He II line profiles from a monochromatic source are characterized by a double peaked core part with an extended Raman red tail that is attributed to multiple re-entry events. Complicated behaviors are observed in the case of a Gaussian He II source including the formation of a secondary red peak near the Balmer center dependent on the H I column density. A preliminary application of our results to the CFHT data of the planetary nebula IC 5117 is presented.

• Bulletin of the Korean Chemical Society
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• v.4 no.5
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• pp.203-208
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• 1983

A thermal decomposition of trichloroethylene was studied in the temperature range of 440-$460^{\circ}C$ by using the conventional static system. In order to investigate the pressure dependence of reaction and to eliminate free radical process, propylene was used as the bath gas. The pressure range investigated was 10∼900 Torr. The decomposition was the unimolecular dehydrochlorination and the reaction products were hydrogen chloride and dichloroacetylene. Results were interpreted in terms of the Ric-Ramsperger-Kassel-Marcus (RRKM) unimolecular rate theory and the Arrhenius parameters were determined from fall-off behaviors. The Arrhenius parameters are found to be log $A=13.8{\pm}0.2sec^{-1}$ and E = $56.6{\pm}0.7$ kcal/mole, respectively.