• Journal of Soil and Groundwater Environment
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• v.11 no.6
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• pp.28-34
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• 2006

Laboratory column tests using $Cl^-$ tracer were conducted to study the correlation of soil particle distribution and hydrodynamic dispersion mechanism with three kinds of ununiformed soil samples, in which the ratio of gravel and sand versus silt and clay is 24.5 for S-1 soil, 4.48 for S-2 soil, and 0.4 for S-3 soil. Chloride breakthrough curves with time were fitted with gaussian functions. The relative concentrations of chloride were converged to 1.0 after 0.7 hours for S-1, 6.3 hours for S-2, and 389 hours for S-3. Average linear velocity, longitudinal dispersion coefficient, and longitudinal dispersivity were calculated by chloride breakthrough curves. Longitudinal dispersion coefficients were $1.20{\times}10^{-4}\;m^2/sec$ for S-1, $8.87{\times}10^{-7}\;m^2/sec$ for S-2, and $1.94{\times}10^{-9}\;m^2/sec$ for S-3. Peclet numbers calculated by the molecular diffusion coefficient of chloride and the mean grain diameters of soils were $2.59{\times}10^2$ for S-1, $6.27{\times}10^0$ for S-2, and $1.35{\times}10^{-4}$ for S-3. Mechanical dispersion was dominant for the hydrodynamic dispersion mechanism of S-1. Both mechanical dispersion and molecular diffusion were dominant for the hydrodynamic dispersion mechanism of S-2, but mechanical dispersion was ascendant over molecular diffusion. Hydrodynamic dispersion in S-3 was occurred mainly by molecular diffusion. When plotting three soils on the graph of $D_L/D_m$ versus Peclet number produced by Bijeljic and Blunt (2006), the values of $D_L/D_m$ for S-1 and S-2 were more than 2.0 order compared to their graph. S-3 was not plotted on their graph because the Peclet number was as small as $1.35{\times}10^{-4}$.

• Journal of Korean Society of Water and Wastewater
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• v.10 no.3
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• pp.64-72
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• 1996

The one of the most important factors we shoud consider in designing the processes using porous media such as activated carbon adsorber is the prediction of the breakthrough curve. In this study, the breakthrough curve of BAC process for the treatment of refractory pollutants was evaluated by simplified engineering analysis. Through the experiments, the slope of the breakthrough curve can be determined by retardation factor, R and apparent dispersion coefficient, $D_{app}$ which is determined by hydrodynamic dispersion, mass transfer effects and isotherm. Estimated concentration of effluent was agreed with the experimental values. Also, it is possible to use this method for predicting the breakthrough curve of the pollutants removal and tranport of pollutants in porous media.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.57-59
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• 2002

The dissolution process of NAPLs is significantly important in predicting the transport and/or fate of the contaminants and designing remedial systems. In this research, experimental observations on dissolution of TCE pool under various hydrodynamic conditions are done using an aquifer model. Hydrodynamic parameters such as linear pore velocity and dispersion coefficient are estimated from the results of preliminary tracer tests using bromide as conservative tracer before doing the TCE dissolution experiments. It is found that hydrodynamic parameters are distinctly affected by the clay lens imbeded in the aquifer model. Nonequilibrium and transient dissolution rates are observed from the results of TCE dissolution experiments.

• Journal of Soil and Groundwater Environment
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• v.13 no.4
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• pp.1-7
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• 2008

This study analyzed for hydrodynamic dispersion characteristics of multi-soil layer (Silt and clay, Find sand, Coarse sand), data of a field tracer test on the multi-soil layer and data of laboratory column experiments on the samples on each soil layers. Through the analysis of permeability and flow, MS (Silt and clay) and FS (Fine sand), which were low effective porosity, were higher average linear velocity while CS (Coarse sand), which was high effective porosity, was higher hydraulic conductivity. Hydraulic conductivity function based on average soil particle diameter was assumed Y=$3.49{\times}10^{-8}e^{15320x}$ and coefficient of determination was 0.90. Average linear velocity function based on average soil particle diameter was assumed Y=$1.88{\times}10^{-7}e^{11459x}$ and coefficient of determination was 0.81. Longitudinal dispersivity function based on average soil particle diameter was Y = 0.00256$e^{5971x}$ and coefficient of determination was 0.98. According to the linear regression analysis of average linear velocity and longitudinal dispersivity, assumed function was Y = 21.7527x + 0.0063, and coefficient of determination was 0.9979. The ratio of field scale/laboratory scale was 54.09, it exhibited scale-dependent effect of hydrodynamic dispersion. Field longitudinal dispersivity (1.39m) was 7.47 times as higher than longitudinal dispersivity estimated by the methods of Xu and Eckstein (1995). Hydrodynamic dispersion on CS layer was occurred mainly by diffusion flow in the test aquifer.

• Biotechnology and Bioprocess Engineering:BBE
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• v.11 no.3
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• pp.268-272
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• 2006

A dense, pellicular UpFront adsorbent ($p=1.5 g/cm^3$, UpFront Chromatography, Cophenhagen, Denmark) was characterized in terms of hydrodynamic properties and protein adsorption performance in expanded bed chromatography. Cibacron Blue 3GA was immobilised into the adsorbent and protein adsorption of bovine serum albumin (BSA) was selected to test the setup. The Bodenstein number and axial dispersion coefficient estimated for this dense pellicular adsorbent was 54 and $1.63{\times}10^{-5}m^2/s$, respectively, indicating a stable expanded bed. It could be shown that the BSA protein was captured by the adsorbent in the presence of 30% (w/v) of whole-yeast cells with an estimated dynamic binding capacity $(C/C_o = 0.01)$ of approximately 6.5 mg/mL adsorbent.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.11
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• pp.1168-1179
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• 2006

The validity of an unsteady two-dimensional(2-D) numerical hydrodynamic and pollutant dispersion model(2DNHPDM) was evaluated using the data obtained from I-sa streams in Sooncheon, Chonnam, during rain-fall run-off. Field observations was conducted for 35 hours during the 10 hours rainfall event on 7th May 2005. The water level, 2-D velocity, flow field, and COD at seven points selected along the river were measured at intervals of one hour. The model was applied to describe two-dimensional movement of dissolved pollutants in meandering non-uniform river. Major physical processes affecting the lateral and horizontal mixing of the river flow were simulated. The model was proved effective in describing the hydrodynamics and dispersion of the river pollutants from its major tributaries as well as non-point sources.

• Nuclear Engineering and Technology
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• v.32 no.4
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• pp.342-349
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• 2000

A soil whose texture is silt loam was collected for the study from an area around a nuclear facility in Korea. The equilibrium sorption coefficient between Co$^{2+}$in water and the soil was 1.51/kg, on the other hand, that between Co$^{2+}$ in EDTA and the soil was 0.21/kg. The values calculated by the developed nonequilibrium sorption code corresponded to the experimental values better than those calculated by the existing equilibrium sorption code. When an EDTA solution was used as a solvent to decontaminate Co$^{2+}$ in the soil column, the relative Co$^{2+}$ concentrations of the effluent were higher at 2~10 pore volumes than those of the case using water. The soil in the column was decontaminated by 95.5% of the total amount of Co$^{2+}$ after being flushed with EDTA solution of 20 pore volumes.e volumes.

• Korean Journal of Soil Science and Fertilizer
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• v.23 no.1
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• pp.8-14
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• 1990

Retardation and hydrodynamic dispersion coefficient necessary for model of water and solute movement in a soil were determined for horizontal soil column with different initial soil water conditions. The soil columns were compacted with sandy loam soil. The bulk density was $1,350+50kg/m^3$, and initial water contents were 0.05, 0.08 and 0.14. Advancement of 0.05% $CaSO_4$ solution was used as the standard and advancements of 0.5% KCl, $CaCl_2$ and $KH_2PO_4$ were compared. Retardation of non-reactive $Cl^-$ was related with the initial soil water content, ${\theta}n$, as ${\theta}/({\theta}-{\theta}n)$, and anion exclusion was ignored. Retardations of active $K^+$, $Ca^{{+}{+}}$ and $H_2PO_4{^-}$ were related as 1/(R+1) $^*{\theta}/({\theta}-{\theta}n)$, in which R was retardation coefficient. Measured R was 0.64 for $K^+$, 0.80 for $Ca^{{+}{+}}$ and 2.6 for $H_2PO_4{^-}$, respectively. Calculated R using Langmuir adsorption isotherm showed fair degree of applicability. Soil water diffusivity, $D({\theta}),m^2/sec$, calculated for different initial water content showed unique function as $$log(D({\theta}))=13.448{\theta}-9.288$$ Hydrodynamic dispersion coefficient of $Cl^-$ above soil water content 0.36 was similar to soil water diffusivity and decreased to near self diffusion coefficient at soil water content near 0.2. Those of $K^+$, $Ca^{{+}{+}}$ $H_2PO_4{^-}$ at soil water content of 0.38 were $5.5{\times}10^{-6}$, $2.4{\times}10^{-6}$ and $7.1{\times}10^{-7}m^2/sec$ and decreased rapidly with decreasing soil water content lower than 0.36.

• Nuclear Engineering and Technology
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• v.22 no.1
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• pp.20-28
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• 1990

In this study the migration experiment using packed column with crushed tuff was conducted as a basic research to develop migration model of radionuclides through geologic media. The main emphasis was put on evaluating the validity of migration models. For this, two models were introduced: one is the model which is based on the assumption of instantaneous equilibrium reaction and the other the model based on kinetic process such as intraparticle diffusion. The coefficient of hydrodynamic dispersion in packed column was determined using iodine as nonsorbing tracer. The hydrodynamic dispersion coefficient, D$_{L}$ was shown to be 0.11$\times$10$^{-2}$ $\textrm{cm}^2$/min under the condition of the column porosity of 0.483 and the average water velocity of 0.915$\times$10$^{-2}$ cm/min. The distribution coefficient, Kd of Cs-137 on crushed tuff was 11.3 cc/g at the concentration of 2$\times$10$^{-6}$ M and the temperature of 2$0^{\circ}C$. The breakthrough curve of Cs-137 through packed column was shown to have an asymmetric curve in which long trailing tail appears at the end part of the curve. The results obtained from the comparison of introduced models with experimental data indicated that the mass transfer model with intraparticle diffusion as rate-controlling step simulated the behaviors of Cs-137 migration more adequately, when compared with the bulk reaction model in which the assumption of instantaneous equilibrium reaction was maded. Consequently, the intraparticle diffusion was found to be an important factor in the migration of Cs-137 through packed column.n.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.3
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• pp.275-282
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• 2010

The laboratory column experiments were used to transport of metal elements by infiltration-related dispersion and/or diffusion in mine tailing of the Guryong gold mine. The mine tailing shows the neutral pH (for a pore water) and contains quartz, chlorite, pyrite and calcite. Both a non-reactive solute ($Cl^-$ of 100 mg $L^{-1}$) and a reactive solute (1N HCl), were injected continuously through columns. The breakthrough curve in the non-reactive experiment reached at a maximum under 1.5 pore volumes (PV). The longitudinal dispersion (0.607 cm) and hydrodynamic dispersion coefficient ($1.96{\times}10^{-7}cm^{2}sec^{-1}$) were calculated by the slope. In the reactive experiment, the plateau curve was appeared in the pH values of 5.3, 4.5 and 1.7. The releases of metal elements such as Fe, Mn, Al, Cu, Zn, Pb, and Cd were observed to be related to the pH buffering. High concentrations of Mn, Cd and Zn were observed at the first pH plateau (4 PV and pH 5.3), whereas Fe, Cu, Al and Pb were released as the pH decreased to 4.0 or less. The resulting order of metals mobility, based on the effluent water, is Mn=Cd>Zn>Cu>Fe>Al>Pb.