• 제목/요약/키워드: hydrocarbon(s)

검색결과 437건 처리시간 0.031초

THE CENTRAL REGION OF THE BARRED SPIRAL GALAXY NGC 1097 PROBED BY AKARI NEAR-INFRARED SPECTROSCOPY

  • Kondo, T.;Kaneda, H.;Oyabu, S.;Ishihara, D.;Mori, T.;Yamagishi, M.;Onaka, T.;Sakon, I.;Suzuki, T.
    • 천문학논총
    • /
    • 제27권4호
    • /
    • pp.257-258
    • /
    • 2012
  • With AKARI, we carried out near-infrared spectroscopy of the nearby barred spiral galaxy, NGC 1097, categorized as Seyfert 1 with a circumnuclear starburst ring. Our observations mapped the galactic center region. As a result, we obtain the spatial distributions of the polycyclic aromatic hydrocarbon $3.3{\mu}m$ and the aliphatic hydrocarbon $3.4-3.6{\mu}m$ emission. The former is detected from all the observed regions and the latter is enhanced near the bar connecting the ring with the nucleus. In addition, we detect absorption features due to $H_2O$ ice and CO/SiO at the ring and the galactic center, while we detect the hydrogen recombination line $Br{\alpha}$ only from the ring. Hence the observed spectra change dramatically within the central 1 kpc region.

연변방전에 의한 유해물질의 분해제거 (Decomposition of Harmful Materials by SPCP Discharge)

  • 우인성;황명환
    • 한국전기전자재료학회논문지
    • /
    • 제11권11호
    • /
    • pp.1043-1048
    • /
    • 1998
  • The decomposition performance of the Surface induced Plasma Chemical Processing(SPCP) for benzene, toluene, xylene and $NO_2$ were experimentally examined. Discharge exciting frequency range was 5kHz and 10kHz, and low frequency discharge requires high voltage to inject high electric power in gas and to decompose contaminants. The decomposition rate of dioxide nitrogen for 5kHz power in gas and to decompose contaminants. The decomposition rate of dioxide nitrogen for 5kHz power supply is only 85%, but it’s rate for 10kHz power supply is very high, more than 96% when peak voltage is 12kv. Aromatic hydrocarbon vapor of up to 1000ppm is almost throughly decomposed at the flow rate of 1000$\ell$/min or lower rate under the discharge with electric power of several hundred watts. High decomposition rate is shown in every case, that is, for SPCP reactor is necessary to obtain the decomposition rate of more than 80~98%. The decomposition rate of benzene, toluene and xylene were 90~98% and dioxide nitrogen was 45~96%.

  • PDF

Ligand and Dimerization Dependent Transactivation Capability of Aromatic Hydrocarbon Receptor

  • Park, Hyun-Sung
    • BMB Reports
    • /
    • 제32권3호
    • /
    • pp.279-287
    • /
    • 1999
  • The aromatic hydrocarbon receptor (AhR) is a cytosolic protein that binds the environmental pollutant, dioxin. The liganded AhR translocates into the nucleus where it heterimerizes with a constitutive nuclear protein, AhR nuclear translocator (Arnt). The N-terminal regions of both AhR and Arnt contain basic helix-loop-helix (bHLH) and Per-AhR-Arnt-Sim (PAS) motifs that are required for DNA binding, dimerization, and ligand binding whereas the C-terminal regions of both AhR and Arnt contain transactivation domains. Here, results from the mammalian two-hybrid system indicate that Arnt can make a homodimer but AhR cannot. In the presence of dioxin, the interaction between AhR and Arnt is stronger than that of the Arnt homodimer, suggesting that Arnt prefers to make a heterodimer with the liganded AhR rather than a homodimer. Transfection analyses using the GAL4-driven reporter system suggest that AhR's N-terminal region represses its own transactivation domain, as well as exogenous transactivation domains such as Sp 1 and VP16. Interestingly, the repressed transactivation domains of AhR are activated by ligand-dependent heterodimerization with Arnt. These observations suggest that heterodimerzation with Arnt is necessary not only for DNA binding but also for activation of the repressed transactivation capability of AhR.

  • PDF

PCV 밸브의 스풀 동적거동에 따른 내부유동 특성에 관한 연구 (A STUDY ON INTERNAL FLOW CHARACTERISTICS OF PCV VALVE ACCORDING TO SPOOL DYNAMIC BEHAVIOR)

  • 이종훈;이연원;김재훈
    • 한국전산유체공학회:학술대회논문집
    • /
    • 한국전산유체공학회 2005년도 추계 학술대회논문집
    • /
    • pp.223-227
    • /
    • 2005
  • A PCV valve is a part to control the flow rate of Blowby gas in a PCV system. A PCV system re-burns Blowby gas with fuel in a combustion chamber. Some gas enters to a crankcase room through the gap between piston ring and engine cylinder wall. This gas si called 'Blowby gas'. This gas causes many problems. In environmental view, Blowby gas includes about $25\~35\%$ hydrocarbon{HC) of total generated HC in an automobile. Hydrocarbon is a very harmful pollutant element in our life. In mechanical view, Blowby gas has some reaction with lubricant oil of crankcase room. Then, this causes lubricant oil contamination, crankcase corrosion and a decrease fo engine efficiency. Consequently, Blowby gas must be eliminated from a crankcase room. In this study, we simulated internal flow characteristics in a PCV valve according to spool dynamic behavior using local remeshing method And, we programmed our sub routine to simulate a spool dynamic motion. As results, spool dynamic behavior is periodically oscillated by the relationship between fluid force and elastic force of spring. And its magnitude is linearly increased by the differential pressure between inlet and outlet. Also, as spool is largely moved, flow area is suddenly decreased at orifice. For this reason, flow velocity is rapidly decreased by viscous effect.

  • PDF

DME/Air 비예혼합화염의 NOx 생성에서 산소원자의 역할 (The Role of Oxygen Atom in the NOx Formation of DME/Air Nonpremixed Flames)

  • 김태현;황철홍;이승로;이창언
    • 한국연소학회지
    • /
    • 제14권1호
    • /
    • pp.9-18
    • /
    • 2009
  • The NOx emission characteristics of DME in counterflow nonpremixed flames were investigated numerically, and brief experiments were carried out to compare the flame shapes and NOx emissions with those of $C_{3}H_{8}$ and $C_{2}H_{6}$. The DME flames were calculated using Kaiser's mechanism, while the $C_{2}H_{6}$ flames were calculated using the $C_3$ mechanism. These mechanisms were combined with the modified Miller-Bowman mechanism for the analysis of NOx. Experimental results show that DME flame has the characteristics of partial premixed flame and the flame length becomes very shorter compared with general hydrocarbon fuels and then, the NOx emission of DME is low as much as 60 % of $C_{3}H_{8}$. In the calculated results of counterflow nonpremixed flames, the $EI_{NO}$ of DME nonpremixed flame is low as much as 50 % of the $C_{2}H_{6}$ nonpremixed flame. The cause of $EI_{NO}$ reduction is attributed mainly to the characteristics of partial premixed flame due to the existence of O atom in DME and partly to the O-C bond in DME, instead of C-C bond in hydrocarbon fuels.

  • PDF

프로필렌 냉매의 증발열전달 특성에 관한 실험적 연구 (Experimental Study on Heat Transfer Characteristics of Evaporation using Propylene Refrigerant)

  • 이호생;김재돌;정석권;윤정인
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제28권5호
    • /
    • pp.754-761
    • /
    • 2004
  • In this paper, evaporating heat transfer characteristics in the refrigeration and air-conditioning facilities were studied using the environmentally friendly refrigerants R-1270 (Propylene). R-290 (Propane). R-600a (Iso-butane) and HCFC refrigerant R-22 The test tube was surrounded by an annulus with water flowing counter to the refrigerant. The tube is copper. with an outside diameter of 12.7mm and the wall thickness of 1.315mm. The test results showed that the local evaporating heat transfer coefficients of hydrocarbon refrigerants were superior to that of R-22 and the maximum increasing rate of heat transfer coefficient was found in R-1270. The average evaporating heat transfer coefficient increased with the increase of the mass velocity and it showed the higher values in hydrocarbon refrigerants than R-22 Comparing the heat transfer coefficient of experimental results with that of other correlations. the presented results had agood agreement with the Kandlikar's correlation. This results form the investigation can be used in the design of heat transfer exchangers using hydrocarbons as the refrigerant for the air-conditioning systems.

7.73 mm와 5.80 mm 수평관내 탄화수소 냉매의 응축 열전달 특성 (Condensation Heat Transfer Characteristics of Hydrocarbon Refrigerants in Horizontal Tubes of 7.73 mm and 5.80 mm)

  • 손창효
    • 한국수소및신에너지학회논문집
    • /
    • 제19권4호
    • /
    • pp.331-339
    • /
    • 2008
  • 본 논문은 내경 7.73 mm와 5.80mm의 수평관내 프레온계 냉매 R-22와 탄화수소계 냉매 R-290과 600a의 응축 열전달 계수의 실험적 결과를 나타내었다. 실험장치는 압축기, 응축기, 팽창밸브, 증발기 등으로 구성된다. 응축 실험은 질량유속 $35.5{\sim}210.4\;kg/m^2s$이고, 응축온도 40$^{\circ}C$인 조건에서 수행하였다. 주요 결과를 요약하면 다음과 같다. 탄화수소계 냉매 R-290과 R-600a의 평균 열전달 계수는 프레온계 냉매 R-22보다 높게 나타났으며, R-600a의 평균 열전달 계수가 모든 관경에 대해 가장 높게 나타났다. 실험결과와 종래의 상관식을 비교한 결과, 모든 관경과 냉매에 대해 Haraguchi 등의 상관식이 가장 좋은 일치를 보였다. 그 중에서 Cavallini-Zecchin의 상관식은 7.73 mm 관경의 실험데이터와, Dobson 등의 상관식은 내경 5.80 mm 관경의 데이터와 좋은 일치를 보였다.

DME/Air 비예혼합화염의 NOx 생성 특성에 관한 기초 연구 (Fundamental Studies on NOx Emission Characteristics in a Dimethyl Ether/Air Nonpremixed Flame)

  • 김태현;김종현;이창언
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2008년도 추계학술대회B
    • /
    • pp.1973-1978
    • /
    • 2008
  • The NOx emission characteristics of DME in counterflow nonpremixed flames were investigated numerically, and brief experiments were carried out to compare the flame shapes and NOx emissions with those of $C_3H_8$ and $C_2H_6$. The DME flames were calculated using Kaiser's mechanism, while the $C_2H_6$ flames were calculated using the $C_3$ mechanism. These mechanisms were combined with the modified Miller-Bowman mechanism for the analysis of NOx. Experimental results show that DME flame has the characteristics of partial premixed flame and the flame length becomes very shorter compared with general hydrocarbon fuels and then, the NOx emission of DME is low as much as 60% of $C_3H_8$. In the calculated results of counterflow nonpremixed flames, the EINO of DME nonpremixed flame is low as much as 50% of the $C_2H_6$ nonpremixed flame. The cause of $EI_{NO}$ reduction is attributed mainly to the characteristics of partial premixed flame due to the existence of O atom in DME and partly to the O-C bond in DME, instead of C-C bond in hydrocarbon fuels.

  • PDF

Properties of Sodium Dodecyl Sulfate / Triton X-100 Mixed Micelle

  • Park, Joon-Woo;Chung, Myung-Ae;Choi, Kyung-Moon
    • Bulletin of the Korean Chemical Society
    • /
    • 제10권5호
    • /
    • pp.437-442
    • /
    • 1989
  • The cmc's of sodium dodecyl sulfate (SDS)/Triton X-100 surfactant mixtures were determined by surface tension measurement at various surfactant compositions. The cmc values were lower than those predicted from ideal mixture. The regular solution theory was applied to calculate the interaction parameter, micellar composition, and the activity coefficients of surfactants in the mixed micelle. The interaction parameter (${\beta}$) was - 2.1. The nonideality arised largely from decreased activity of SDS in the mixed micelle. The mean aggregation numbers (${\bar{n}}$) and micropolarity of hydrocarbon region of the mixed micelles were determined by luminescence probe techniques. The total aggregation number (${\bar{n}}_{SDS}+{\bar{n}}_{TX}$) in mixed micelles showed little dependency on the composition of the micelle. The apparent dielectric constant of the hydrocarbon region of the micelle vs micellar composition plot showed positive deviation from linearity. Emission and emission quenching of excited tris(2,2'-bipyridine)ruthenium(Ⅱ) cation, $(Ru(bpy)_3^{2+})$, by methylviologen ($MV^{2+}$) were also investigated in the mixed micellar solutions. The quenching rate was lowest when the mole fraction of SDS in the surfactant mixtures (${\alpha}_{SDS}$) is about 0.25 and highest at ${\alpha}_{SDS}$ = 0.85. This was explained in terms of combined effects of binding of the cations with the micelle and mobility of the bound cations on the surface of the micelles.

Transbilayer Effects of n-Alkanols on the Fluidity of Phospholipid Model Membranes

  • Yun, Il;Kang, Jung-Sook
    • Archives of Pharmacal Research
    • /
    • 제15권2호
    • /
    • pp.152-161
    • /
    • 1992
  • Selective quenching of 1, 6-diphenyl-1, 3, 5-hexatriene (DPH) by trinitrophenyl groups was utilized to examine the transbilayer fluidity asymmetry of model membranes of phospholipids (SPMVPL) extracted from synaptosomal plasma membrane vesicles (SPMV). The polarization (P), anisotropy (r), limiting anisotropy $(r_\infty$), and order parameter (S) of DPH in the inner monolayer were 0.019, 0.014, 0.018, and 0.047, respectively, greater than calculated for the outer monolayer of SPMVPL. Selective quenching of DPH by trinitrophenyl groups was also utilized to examine the effects of n-alkanols on the individual monolayer structure of SPMVPL. n-Alkanols fluidized the hydrocarbon region of bulk SPMVPL and the potencies of n-alkanols up to 1-nonanon increased with carbon chain length. It appears that the potencies in bilayer fluidization increase by 1 order of magnitude as the carbon chain length increases by two carbon atoms. The cut-off phenomenon was reached at 1-decanol, where further increase in hydrocarbon length resulted in a decrease in pharmacological activity. The n-alkanols had greater fluidizing effects on the outer monolayer as compared to the inner monolayer of SPMVPL, even though these selective effects tended to become weaker as the carbon chain length increased. Thus, it has been proven that n-alkanols exhibit selective rather than nonselective fludizing effects within transbilayer domains of SPMVPL.

  • PDF