• 한국윤활학회:학술대회논문집
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• 한국윤활학회 1998년도 제28회 추계학술대회
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• pp.181-189
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• 1998

In order to investigate the effect of base oil composition on the electronic insulating oil's performances, an experimental study has been conducted using different oils. Owing to their properties, like lower pour point and gas absorbing, naphthenic base oils are used more often than paraffmic base oils for the electronic insulating oil application. Naphthenic and paraffinic base oils are significantly different in their aromatic hydrocarbon content. In this paper, PXE(para xylyl ethane), LAB(linear alkylbenzene), C13 aromatic hydrocarbon mixture and C17 aromatic hydrocarbon mixture are investigated regarding their influence on insulating oil's performances. According to present study, breakdown voltage decreased with increasing aromatic lydrocarbon content in a deep dewaxed paraffmic base oil. However, any changing in the dissipation factor was not recognizable at small treated level. Furthermore, the volume resistance was not influenced by aromatic hydrocarbon content. The gassing tendency was found as a highly sensible property, changing with treating aromatic hydrocarbons. The higher benzene ring content in the hydrocarbon, the better gassing tendency.

• 한국연초학회지
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• 제12권2호
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• pp.77-83
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• 1990

This study was conducted to develop the method of hydrocarbon analysis and investigate hydrocarbon contents in flue-cured and burley tobacco leaves harvested in Korea and U.S.A. Tobacco leaf was extract with hexane in soxhlet apparatus. Hydrocarbon was fractionated from hexane extract by silica gel column chromatography, and then separated and indentified by GC, GC/MS using SE-54 fused silica capillary column. The developed method was feasible to analyze neophytadiene, normal and branched hydrocarbons from Clo to Cn. The result of recovery test was decade 99%, eicosane 100%, triacontane 102%. The major hydrocarbon of tobacco leaves were neophytadiene, nC3l, iC31, nC33, aC33, aC32, aC30 and nC29. The amount of total hydrocarbon in burley and flue-cured tobacco leaves harvested in U.S.A. and Korea were 4591, 2931, 2929 and 3015$\mu\textrm{g}$/g, respectively.

• 공업화학
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• 제16권1호
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• pp.21-27
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• 2005

In order to conduct research on oil originated in Mongolia for further application of petroleum not only as fuel but also as raw material for organic synthesis, we need to study the physical, chemical characteristics and individual, group hydrocarbon's compositions of main petroleum fractions. A number of studies and surveys on the physical and chemical characteristics, group hydrocarbon's composition of petroleum deposits in Zuun-Bayan, Sukhaibulag, Tsagaan Elst, Tamsagbulag have been carried out earlier through n-g-M, aniline point and dispersimetric methods successfully. Yet a detailed chromatographical and NMR spectroscopic study for the individual hydrocarbon's composition of Tamsagbulag oil main fractions has not been conducted. In the present study the results of GC analyses of gasoline fractions of wells 19-3, 19-13 and 19-10, Tamsagbulag (Eastern Mongolia) were presence. The gasoline fractions of given wells were characterized by the high concentration of paraffins and presence of trace amount of olefins. There were identified 69 paraffins, 45 naphthenes, 41 aromatics and 3 olefins in total 158 individual hydrocarbons from each samples of gasoline fraction. The first attempts to classify Tamsagbulag oil under the individual hydrocarbon's composition data were successfully conducted and the supposition of a genetic classification of given oil as "sapropelic" type was made.

• International Journal of Automotive Technology
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• 제7권4호
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• pp.399-406
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• 2006

The smoke emission of diesel engines is being recognized as one of the major source of the air pollution problems. This study investigates the potential of esterified rice bran oil to reduce smoke emission as an alternative fuel for diesel engines. Because the esterified rice bran oil has approximately a 10.5% oxygen content, the combustion of the diesel engine improved and exhaust smoke decreased. Gas chromatography was used to analyze not only the total amount of hydrocarbon but also the amount of hydrocarbon components from $C_1$ to $C_6$ in the exhaust gas to determine an exact source responsible for the remarkable reduction in the smoke emission. The number of individual hydrocarbon($C_1{\sim}C_6$) as well as the total amount of hydrocarbon of esterified rice bran oil reduced significantly compared to that of hydrocarbon of diesel fuel.

• International Journal of Automotive Technology
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• 제3권1호
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• pp.41-46
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• 2002

Effect of secondary air injection (SAI) on hydrocarbon reduction has been investigated in a single cylinder Sl engine operating at cold-steady/cold-start conditions. The hydrocarbon emission and exhaust gas temperature with and without catalytic converter were compared with continuous and synchronized SAIs, which injected secondary air intermittently into exhaust port. Effects of SAI location, SAI pressure, SAI timing, and location of catalytic converter have been investigated and the results are compared for both SAls with base condition. At cold-steady condition, the rate of HC reduction increased as the location of SAI was closer to the exhaust valve for both synchronized and continuous SAls. The emission of HC decreased with increasing exhaust-A/F when it was rich, and was relatively insensitive when it was lean. The timing of SAI in synchronized SAI had significant effect on HC reduction and exhaust gas temperature and the synchronized SAI was found to be more effective in HC reduction and exhaust gas temperature compared to the continuous SAI . At cold-start condition, when the catalytic converter was located 20 cm downstream from the exhaust port exit, the catalytic converter warm-up period for both SAls decreased by about 50%, and the accumulated hydrocarbon emission during the first 120 s decreased about by 56% and 22% with the synchronized and continuous SAIs, respectively, compared to that of the base condition.

• 한국자동차공학회논문집
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• 제9권2호
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• pp.67-74
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• 2001

A synchronized secondaty air injection method has been developed to hydrocarbon emission by injecting secondary air intermittently into exhaust port. The method has been tested in a single cylinder spark-ignition engine operating at cold-steady / cold-start conditions. Effects of air injection timing, intake pressure and engine air-fuel ratio have been investigated at cold-steady condition. Also, hydrocarbon emission and exhaust gas temperature with catalytic conberter are compared with a continuous SAI method and base condition at cold-start condition. Resules show that hydrocarbon reduction rate and exhaust gas temperature are sensitive to the timing of synchronized SAI. At cold-steady condition, HC emission is minimum at engine air-fuel ratio of 10. At cold-start condition, the accumulated hydrocarbon emission during the first 120 s decreases about 56% and 22% with the synchronized and continuous SAI, respectively, compared to that of base condition.

• 한국의류학회지
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• 제22권3호
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• pp.265-265
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• 1998

The phase behavior of chlorinated hydrocarbon/mixed surfactants/water microemulsion systems were investigated for dry cleaning solvent properties. With appropriate surfactant mixtures, Winsor type I-III-II microemulsions were generated which is the same as hydrocarbon systems. For perchloroethylene(PCE) with mixed Tween systems, the optimum salinity(S*) decreases and the optimum solubilization parameter(o*) increases with decreas- ing HLB. For PCE with mixed Aerosol MA and ethoxylated alcohol systems, S* and o* both increase with increasing ethylene oxide moles. For dichlorobenzene(DCB) with mixed Aerosol MA and ethoxylated or propoxylated sulfate systems, S* and o* both increase with increasing ethylene oxide moles or propylene oxide moles.

• 한국의류학회지
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• 제22권3호
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• pp.365-373
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• 1998

The phase behavior of chlorinated hydrocarbon/mixed surfactants/water microemulsion systems were investigated for dry cleaning solvent properties. With appropriate surfactant mixtures, Winsor type I-III-II microemulsions were generated which is the same as hydrocarbon systems. For perchloroethylene(PCE) with mixed Tween systems, the optimum salinity(S*) decreases and the optimum solubilization parameter(o*) increases with decreas- ing HLB. For PCE with mixed Aerosol MA and ethoxylated alcohol systems, S* and o* both increase with increasing ethylene oxide moles. For dichlorobenzene(DCB) with mixed Aerosol MA and ethoxylated or propoxylated sulfate systems, S* and o* both increase with increasing ethylene oxide moles or propylene oxide moles.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 추계학술대회논문집B
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• pp.818-823
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• 2001

Because the exhaust emissions from automobiles are increased, our environment is faced with very serious problems related to the air pollution in these days. In particular, the exhaust emissions of diesel engine are recognized main cause which influenced environment strong. Lots of researcher have been attempted to develop various alternative fuel on purpose to reduce these harmful emissions. In this study, the potential possibility of esterfied rice bran oil which is a kind of biodiesel fuel was investigated as an alternative fuel for diesel engine. And, we tried to analysis not only total hydrocarbon but hydrocarbon components from $C_1$ to $C_6$ in exhaust gas using gas chromatography to seek the reason for remarkable reduction of exhaust emission. Individual hydrocarbon$(C_1\simC_6)$ as well as total hydrocarbon of biodiesel fuel is reduced remarkably than that of diesel fuel in this experiment.

• 접착 및 계면
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• 제15권4호
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• pp.145-150
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• 2014

Dicyclopentadiene (DCPD)계 석유수지는 많은 분야에서 점착부여수지로 널리 사용되고 있다. 특히, 수소첨가 반응으로 수지 내 이중결합을 수소로 치환시킨 수첨(水添) DCPD계 석유수지는 무색투명의 색상과 빛과 열에 대한 우수한 안정성으로 인해, 고급 핫멜트접착제(hot melt adhesives, 이하 HMAs) 또는 열용융형 감압접착제(hot melt pressure sensitive adhesives, 이하 HMPSAs) 용도에 널리 사용되고 있다. 본 논문에서는 다양한 수첨 DCPD계 석유수지가 SIS와 SBS와 같은 SBCs를 기본 엘라스토머로 사용한 HMPSAs에서 점착부여수지로 사용될 때의 접착성능에 대해 논의하며, 점착부여 수지의 특성과 HMPSAs의 접착성능과의 상관관계를 보여준다. 높은 연화점의 점착부여수지를 사용할 수록 HMPSAs의 $T_g$, 연화점 그리고 crossover temperature가 높아졌다. 높은 방향족 모노머 함량의 점착부여수지를 사용할 경우에는, PSAs의 crossover temperature 및 연화점 감소로 확인할 수 있듯이 PSAs의 내열온도를 저하시키는 경향을 보였다.