• Title/Summary/Keyword: hydration time

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Effect of TEA on Acceleration Shotcrete (숏크리트용 급결제에 미치는 트리에탄올아민의 영향)

  • Chun, Yong-Jin;Cho, Suk-Hyeong;Hong, Young-Ho;Lee, Gun-Jik
    • Applied Chemistry for Engineering
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    • v.10 no.8
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    • pp.1124-1128
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    • 1999
  • In this study the effect of organic additive, triethanolamine(TEA), and temperature change of accelerator for shotcrete was studied. Then the amount of accelerator, temperature and W/C were experimentally investigated. Effects of hydration time and hydration heat of concrete on organic additive amount were analysed by DSC, SEM and XRD. We found that the hydration heat was increased and hydration time was decreased with TEA(<5 wt %). The order of hydration rate of potassium accelerator was PA < PC-3 < PC-5 < PC-8.

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A Study on Expedite Heat Transfer in Packed Bed of Hydration Calcined Dolomite for Chemical Heat Pump (소성 Dolomite 수화물 화학열펌프의 고체반응층 전열촉진 연구)

  • Kim, Jong-Shik;Lee, Han-Gyu;Park, Young-Hae
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.434-439
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    • 2005
  • The reaction of hydration proceeded at the same time the vapor was introduced into the reactor that was filled with calcined dolomite. It has shown that the temperature has begun to fall from the bottom of reactor after increase of temperature by the heat of hydration reaction. The reaction initiated at the pipe wall and the heat was transfer to the center of block between the fins. The results show that the use of copper fin in the reactor reducted the hydration reaction time by half when compared to the case without using the fins.

Cement/PVDF hollow-fiber hybrid basement membrane: Preparation, microstructure, and separation application

  • Yabin, Zhang;Xiongfei, Du;Taotao, Zhao
    • Membrane and Water Treatment
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    • v.13 no.6
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    • pp.291-301
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    • 2022
  • In this study, cement/PVDF hollow-fiber hybrid membranes were prepared via a mixed process of diffusion-induced phase separation and hydration. The presence of X-ray diffraction peaks of Ca(OH)2, an AFt phase, an AFm phase, and C-S-H phase confirmed the hydration reaction. Good hydrophilicity was obtained. The cross-sectional and surface morphologies of the hybrid membranes showed that an asymmetric pore structure was formed. Hydration products comprising parallel plates of Ca(OH)2, fibrous ettringite AFt, and granulated particles AFm were obtained gradually. For the hybrid membranes cured for different time, the pore-size distribution was similar but the porosity decreased because of blocking of the hydration products. In addition, the water flux decreased with hydration time, and carbon retention was 90% after 5 h of rejection treatment. Almost all the Zn2+ ions were adsorbed by the hybrid membrane. The above results proved that the obtained membrane could be alternative as basement membrane for separation application.

Refinement of Phosphogypsum by Selective Dehydration & Hydration (수화특성차이(水和特性差異)를 이용(利用)한 인산부생석고(燐酸副生石膏)로부터 정제석고(精製石膏)의 회수(回收))

  • Lee, Jung-Mi;Song, Young-Jun;Park, Charn-Hoon
    • Resources Recycling
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    • v.15 no.3 s.71
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    • pp.46-57
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    • 2006
  • This study was carried out for the purpose of recovering the refined gypsum from waste phosphogypsum. The refined gypsum was recovered as a under product of 325 mesh wet screening followed by dehydration and hydration stage. The influence of dehydration temperature and time, dehydration rate, aging time, slurry density of hydration and sonication time on the yield and grade of gypsum were investigated. The refined gypsum of $94{\sim}96%$ grade is recovered in 95% yield by wet screening after selective dehydration and hydration process, from the phosphogypsum. For the better separation efficiency of gypsum, it is recommended to treat the phosphogypsum at the conditions of as follows; 6hr's dehydration at $140^{\circ}C$, hydration slury density of $3{\sim}10%$, hydration temperature of $20{\sim}30^{\circ}C$, hydration time of 2hr. In additions, addition of sodium citrate 0.005M and sonication of $5{\sim}10min.$ are effective for increase the recovery of gypsum. On the other hand, aging the dehydrated gypsum 16 hours or longer make decrease the recovery of gypsum remarkably.

Hydration of Portland Cement Containing Blending Components by Impedance Spectroscopy (임피던스 측정에 의한 혼합재를 포함한 포틀랜드 시멘트의 수화)

  • 송종택;김훈상;배승훈
    • Journal of the Korean Ceramic Society
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    • v.39 no.6
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    • pp.540-549
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    • 2002
  • In this work, the hydration behaviour of portland cement pastes containing fly ash, blast-furnace slag and silica fume is investigated by Impedance Spectroscopy(IS). As fly ash or blast-furnace slag was added to portland cement, the values of R$_{t(s+1)}$ and R$_{t(s+1)}$ were decreased in the early hydration period. It showed that hydration of cement containing blending components was slower than it of the reference cement paste with the same W/C ratio. However, the cement paste containing silica fume had a large value of R$_{t(s+1)}$ and R$_{t(int)}$due to very rapid pozzolanic reactivity of silica fume in the hydration time. In OPC-fly ash system, a characteristic plateau region appeared between straight-line and semicircle. The plateau region continued to grow in range with the content of fly ash and the hydration time.

A Mushroom-Rice(Ganoderma lucidum) development which uses the brown rice (현미를 이용한 영지버섯쌀 생산)

  • 정인창;곽희진
    • Journal of Applied Tourism Food and Beverage Management and Research
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    • v.14 no.1
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    • pp.47-58
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    • 2003
  • Brown rice was used as material for solid-substrate cultivation of Ganoderma lucidum. The hydration time with cold water appeared to be 10 hours for brown rice, but the final water content was much less than optimum water content(65%). Hot water reduced the hydration time of brown rice, and the water content reached to 65% within 40 mins. From this result, hot water was better than cold water for the hydration of brown rice. We attempted to develop a practically applicable process by combining the soaking and sterilization. The water content of 65% appeared to be the best for the growth of the fungi and production of glucosamine related to the amount of mycelium. The content of free sugar increased far more in brown rice fermented with mycelium than in brown rice which was not fermented. Addition was most suitable 20% when add mushroom-rice to brown rice.

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A New Approach of Strength Prediction of High Strength Concrete by the Equivalent Age (적산온도기법에 의한 고강도콘크리트의 강도예측)

  • Kwon, Young-Jin
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.8 no.2
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    • pp.177-183
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    • 2004
  • The maturity concept is based on the fact that concrete gains strength with time as a result of the cement hydration and, thus the strength of concrete is related to the degree of hydration of the cement in concrete. The rate of hydration, as in any chemical reaction, depends primarily on the concrete temperature during hydration. Therefore, the aim of the study is to investigate of the correlation between strength of high-strength concrete and maturity that is expressed as a function of an integral of the curing period and temperature.

Hydration Products, Morphology and Microstructure of Activated Slag Cement

  • Murmu, Meena;Singh, Suresh Prasad
    • International Journal of Concrete Structures and Materials
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    • v.8 no.1
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    • pp.61-68
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    • 2014
  • This paper reports the physical properties and hydration products of slag cement that was prepared by activating ground granulated blast furnace slag with commercial lime and plaster of Paris (POP) as activators. The consistency, setting times and soundness of various mixes of slag-lime-POP is reported. The hydration products and formation of bonds in the paste during setting were studied with the help of SEM, FTIR and XRD tests and the same are correlated to the hydration process. The setting times of the mixes are found to be lower than that of the value prescribed for ordinary Portland cement (OPC). Borax is used as a setting retarder and a borax content of 0.4 % by mass gives setting times that are normally prescribed for OPC. In the early stages of setting C-A-S-H gels are found in this cementing material instead of C-S-H gel, as generally observed in the OPC.

Carbonation of Portland Cement Studied by Diffuse Reflection Fourier Transform Infrared Spectroscopy

  • Ylmen, Rikard;Jaglid, Ulf
    • International Journal of Concrete Structures and Materials
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    • v.7 no.2
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    • pp.119-125
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    • 2013
  • Carbonation is a natural ageing process for cement. This study focuses on how the carbonation rate varies with selected hydration times and atmospheric conditions during the early stages of reacting dried cement paste. Diffuse reflection Fourier transform infrared spectroscopy is shown to be a suitable technique to monitor the formation of carbonates in cement. Combined with a previously developed freeze drying technique, carbonation can be studied at specific hydration stages. In ambient air both calcium hydroxide and calcium silicate hydrate (C-S-H) in cement are carbonated. Increased hydration time enhances the carbon dioxide uptake, which indicates that the calcium in the hydration products reacts more easily than the calcium in the clinker phase. In a humid $CO_2$ atmosphere, the carbonation process is so pronounced that it decomposes C-S-H into calcium carbonate and silica. In a moist $N_2$ atmosphere no carbonation occurs, but the sulfate chemistry of the cement seems to be affected due to the formation of ettringite.

An Experimental Study on the Hydration Heat Control of Mass Concrete Using Heat Pipe (히트파이프를 이용한 매스콘크리트의 수화열 제어에 관한 실험 연구)

  • BaeK, Dong-Il
    • Journal of Ocean Engineering and Technology
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    • v.21 no.6
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    • pp.81-86
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    • 2007
  • In order to eliminate the hydration heat of mass concrete, this paper reports the results of hydration heat control in mass concrete using the OCHP (Oscillating capillary tube heat pipe). In the summarized results of the mock up experiments, distributing the heat pipe at 300 mm intervals based on the center of the test specimen was the most effective. A 200 mm turn interval for the heat pipe was measured to be the most appropriate, taking into account the reinforcement placing at the actual site. Therefore, when the hydration heat control method using the heat pipe developed in this study is applied, not only canconstruction efficiency & a reduction in the necessary construction time be expected, but so can outstanding economical effects.