• 제목/요약/키워드: hydration properties

검색결과 694건 처리시간 0.026초

플라이애시로 표면개질한 바텀애시 경량골재의 물리 화학적특성 (Mechanical and Chemical Characteristics of Bottom Ash Aggregates Cold-bonded with Fly Ash)

  • 김형기;하경애;장정국;이행기
    • 한국세라믹학회지
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    • 제51권2호
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    • pp.57-63
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    • 2014
  • Bottom ash can be used as pelletizing seeds in unsintered artificial lightweight aggregates, so it can be called as 'cold-bonded aggregates'. In the present study, the mechanical and chemical characteristics of bottom ash aggregates cold-bonded with fly ash were investigated. The crushing strength and the water transfer characteristic of the aggregates, which may affect the strength gain of the concrete, were evaluated. Moreover, the degree of hydration and the hydration products of the aggregates were analyzed to verify the chemical stability of the aggregates. Compared to commercialized artificial lightweight aggregates manufactured by sintering process, cold-bonded fly/bottom ash aggregates had similar levels of water transfer characteristics, while having lower strengths. The calcium hydroxide in the aggregates was almost completely consumed after 28 days moist curing.

시멘트 혼합재로의 전처리 제지애쉬 적용가능성 연구 (A Study on Pretreated Paper Sludge Ash for Cement Admixture)

  • 정재현;서성관;추용식
    • 자원리싸이클링
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    • 제25권6호
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    • pp.58-64
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    • 2016
  • 제지산업은 다량의 산업부산물을 배출하고 있으며, 제지애쉬 발생량도 증가하고 있다. 본 연구에서는 제지애쉬를 시멘트 혼합재로 사용하기 위해서 수화수를 사용하여 전처리 하였다. 전처리 제지애쉬와 석고를 혼합하여 혼합재를 제조하였으며, 이후 시멘트를 대체하여 사용하였다. 제지애쉬 혼합시멘트는 제지애쉬 함량에 따라 물성이 변화하였으나, 10% 이하 사용시에는 기존 OPC와 동등 물성이 발현되었다. 이때 압축강도는 수화물 중 $Ca(OH)_2$의 생성량과도 일정 상관성을 나타내었으며, 3일 강도는 $Ca(OH)_2$ 함량이 증가할수록, 28일 강도는 감소할수록 압축강도가 증가하였다.

Effect of activator types on cement mortar with polymeric aluminum chloride waste residue

  • Ping Xu;Yuhao Cui;Dong Han;Minxia Zhang;Yahong Ding
    • Advances in concrete construction
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    • 제15권3호
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    • pp.149-159
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    • 2023
  • Water glass (WG) and sodium sulfate (SS) were used to prepare polymeric aluminum chloride residue cement mortar (PACRM) by single and compound blending with polymeric aluminum chloride waste residue, respectively. The structural strength and textural characteristics examinations showed that PACRM consistency increased by incorporating WG, but decreased by incorporating SS. When WG and SS were compounded, the mortar consistency initially rose before falling. The compressive strength of PACRM increased and then decreased as WG was increased. The mechanical properties of PACRM were better enhanced by SS than WG, showing no strength deterioration. The main reason for the improved mechanical properties of polymeric aluminum chloride waste residue in the presence of activators is the increased precipitation of reactive substances, such as C-S-H gels, calcium silica, and Ca(OH)2. The density of the specimens with PACRM and the degree of aggregation of hydration products were significantly enhanced by generating more hydration products in the mortar. Further, the cracks and pores were significantly reduced, and the matrix structure was continuous and dense at 5% SS doping and 3% compound doping.

시멘트 특성의 변화가 고강도콘크리트의 재료특성에 미치는 영향 (The Effects of Various Cement Type and Compositions on the Material Properties of high Strength Concrete)

  • 백상현;이종열;엄태선;임채용;안광원
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2000년도 봄 학술발표회 논문집
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    • pp.47-52
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    • 2000
  • Recently, it is very necessary the development of the manufacturing techniques for high strength concrete(HSC) for the large-scale size and good quality of civil structure. But, the manufacture and quality control of HSC of which shrinkage, heat of hydration and workability at construction filed are considered, is very difficult due to its low water-cement ratio and high quantity of unit cement content. In the present study, we tried to know and assess the influences of chemical and physical properties of cement on the material properties of HSC. We analyzed basic properties of 4 kinds of cement whose chemical and physical properties are different each other through various tests such as chemical analysis and mortal test. Also, we performed the assessment of the material properties of HSC for each dement by the test for the conditions of same mix design and similar compressive strength. From the results in the study, the assessment of the important quality factors of cement influencing the properties of HSC may be utilized to quality control of applied cement to manufacture the HSC of high quality.

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Lignin 화합물의 Concrete 분산성에 대한 연구 (The Effect of Lignin Compound on Dispersibility of Concrete)

  • 문정연;한기성
    • 한국세라믹학회지
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    • 제13권3호
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    • pp.37-42
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    • 1976
  • Although the water mixed into the concrete plays the role of hydration and acquiring the necessary workability, the more portion of water acts to obtain the substantial workability rather than to complete the hydration. However, the excess amount of water causes the poor quality of concrete, therefore it is useful to add the minimum amount of water as required as to acquire the proper workability. There have been the considerable numbers of investigations in which the dispersion phenomena of strong eletrolytic high polymer compounds such as lignosulfate and some of surface activation agents were studied to utilize as the dispersion agent of concrete. In the present study, Na-lignate, dispersion properties of which has not been studied yet, were investigated with the purpose of utilizing as a dispersion agent of concrete. The microscopic observations showed a great improvement in the dispersion of cement particles, also the fluidity and compressive strength of concrete were remarkably increased with the addition of Na-lignate: The addition of Na-lignate by 0.02% showed the increase of 1.76 times and 1.27 times of slump value and flow value respectively, and the compressive strength was increased by 1.07 times.

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폐석고 및 폐석회를 자극제로 이용한 비소성 시멘트의 수화반응 (Hydration Reaction of Non-Sintering Cement using Waste Gypsum and Waste Lime with Activators)

  • 문경주;소양섭
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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    • pp.232-235
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    • 2004
  • This study aims to manufacture non-sintering cement(NSC) by adding phosphogypsum(PG) and waste lime(WL) to granulated blast furnace slag(GBFS) as sulfate and alkali activators. This study also investigates the basic physical properties and hydration reaction of NSC, and evaluates its reusing possibility as construction material. Results obtained from this study have shown that GBFS was affected by $So_4^{2-}$ in waste PG and stimuli under wet condition, left slag components, created Ettringite and CSH gels, and eventually started being hydrated. These hydrated creations formed dense structures like CSH based on Ettringite and contributed in allowing the mortar to reveal high strength.

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The Mechanical Properties of High Strength Concrete in Massive Structures

  • Park, Ki-Bong
    • Architectural research
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    • 제15권1호
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    • pp.53-58
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    • 2013
  • High strength concrete is being used increasingly in mass structure projects. The purpose of this study is to investigate the influence of temperature during mixing, placing and curing on the strength development, hydration products and pore structures of high strength concrete in mass structures. The experiments were conducted with two different model walls, viz.: 1.5 m and 0.3 m under typical summer and winter weather conditions. The final part of this study deal with the clarification of the relationship between the long-term strength loss and the microstructure of the high strength concrete at high temperatures. Test results indicated that high elevated temperatures in mass concrete structures significantly accelerate the strength development of concrete at the early ages, while the long-term strength development is decreased. The long-term strength loss is caused by the decomposition of ettringite and increased the total porosity and amount of small pores.

알칼리 활성화된 도시 폐기물 소각재 모르타르의 특성 (Properties of Alkali Activated MSWI (Municipal Solid Waste Incinerator) Ash Mortar)

  • 조병완;구자갑;박승국;고희철
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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    • pp.773-776
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    • 2005
  • MSWI ash is the residue from waste combustion processes at temperature between $850^{\circ}C\;and\;1000^{\circ}C$. And the main components of MSWI ash are $SiO_2,\;CaO\;and\;Al_2O_3$. The aim of this study is to find a way to useful application of MSWI ash(after treatment) as a structural material and to investigates the hydraulic activity, compressive strength development, composition variation of such chemicallyi-activated MSWI ashes concrete. And it was found that early cement hydration, followed by the breakdown and dissolving of the MSWI-ashes, enhanced the formation of calcium silicate hydrates(C-S-H), The XRD and SEM-EDS results indicate that, both the hydration degree and strength development are closely connected with a curing condition and a chemically-activator. Compressive strengths with values in the 40.5MFa were obtained after curing the activated MSWI ashes with NaOH+water glass at $90^{\circ}C$.

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혼화재를 다량 사용한 저발열 콘크리트의 모의부재실험 (Mock-up Test of Low Heat Concrete Using High Volume Mineral Admixture)

  • 김용로;송영찬;김효락;박종호;유정훈;정용
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2011년도 춘계 학술논문 발표대회 2부
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    • pp.31-34
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    • 2011
  • In this study, for the evaluation of field application of low heat concrete using high volume mineral admixture, the characteristics of hydration heat generation and engineering properties of low heat concrete was investigated by mock-up test according to the replacement ratio of mineral admixture. Also, it was evaluated the compressive strength of low heat concrete with curing temperatures and ages for effective concrete mix design considering seasonal change.

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초기강도 증진을 위한 황산알루미늄 혼입 시멘트 모르타르의 물리적 특성 (Physical Properties of Cement Mortar using Aluminum Sulfate as Admixture for Early Strength)

  • 강내민;문경주;소승영;소양섭
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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    • pp.293-296
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    • 2003
  • The purpose of this study is to examine the effect of aluminium sulfate on setting time and compressive strength of cement mortar as focused on formation of ettringite by the reaction between aluminium sulfate and calcium hydrate. The specific parameter was the addition ratio of aluminium sulfate to cement mortar. After specimens made by admixing aluminium of 0~7% by weight of cement, respectively, to cement mixtures, the experimental items such as setting time, compressive strength and heat of hydration in this study were carried out. As a result of this study, it is possible that aluminium sulfate could be added into cement mixture from a standpoint of increasing early compressive strength as considering the setting time and heat of hydration.

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