• Title/Summary/Keyword: hydration properties

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Field Application of Low Heat Concrete with Phosphate-PCM in Vietnam (Phosphate-PCM계 보급형 저발열 콘크리트 베트남 지역 현장 적용 평가)

  • Ki, Jun-Do;Lee, Sang-Hyun;Cho, Hong-Bum;Kim, Young-Sun;Jeon, Hyun-Soo;Yang, Wan-Hee
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.171-172
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    • 2022
  • This study aims to develop the hydration heat reducing material (powder type) to lower the heat of hydration of mass members in the extremely hot weather condition. In this study, we applied the developed material to the concrete that used two kinds of binders with cement and evaluate the concrete properties with it.

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A Study on Sodium Sulfate Activited the Hydration Properties of Fly Ash-cement Paste (황산염나트륨 자극제를 사용한 플라이 애쉬 혼입 시멘트 페이스트의 초기 수화 특성에 관한 기초적 연구)

  • Wang, Zihao;Sun, Yang;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.129-130
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    • 2021
  • In order to solve the problem of low early-age compressive strength of high volume fly ash concrete. This paper studies the effect of 2% sodium sulfate (Na2SO4) as a chemical activator on the paste with 40% fly ash content and a water-binder ratio of 0.30. The results indicate that the addition of Na2SO4 can effectively improve the early-age compressive strength of the fly ash-cement system, and the strength improvement rate on the first day reached nearly 70%. In addition, calorimetric analysis reveals that the incorporation of Na2SO4 promotes the early hydration of cement and fly ash, increases the cumulative hydration heat and delays the heat peak of the aluminum phase.

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Resistance of Cementitious Binders against a Fall in the pH at Corrosion Initiation

  • Song, Ha-Won;Jung, Min-Sun;Ann, Ki Yong;Lee, Chang-Hong
    • Corrosion Science and Technology
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    • v.8 no.3
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    • pp.110-115
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    • 2009
  • At the onset of corrosion of steel in concrete, hydrogen ions usually evolve in the process of electrochemical reaction, thereby decreasing the pH of the pore solution, which can be buffered by cement hydration products, as being representatively illustrated by calcium hydroxide. Hence, a fall in the pH is dependent on properties of cement hydration (i.e. hydration products and degree of hydration). The present study tested acid neutralization capacity (ANC) of cementitious binders of OPC(Ordinary Portland Cement), 30% PFA(Pulverized Fuel Ash), 60% GGBS(Ground Granulated Blast Furnace Slag), 10% SF(Silica Fume) to quantify the resistance of cement matrix to a pH fall. Cement pastes were cast at 0.4 of a free W/C ratio with 1.5% chlorides by weight of binder in cast. Powder samples obtained crushed and ground specimen after 200 days of curing were diluted in still water combined with different levels of 1M nitric acid solution, ranging from 0.5 to 20 mol/kg. Then, the pH of diluted solution was monitored until any further change in the pH did not take place. It was seen that the pH of the diluted solution gradually decreased as the molar amount of nitric acid increased. At some particular values of the pH, however, a decrease in the pH was marginal, which can be expressed in the peak resistances to a pH fall in the ANC curve. The peaks occurred at the variations in the pH, depending on binder type, but commonly at about 12.5 in the pH, indicate a resistance of precipitated calcium hydroxide. The measurement of water soluble chloride at the end of test showed that the amount of free chloride was significantly increased at the pH corresponding to the peaks in the ANC curve, which may reflect the adsorption of hydration products to chlorides.

Hydration Heat Properties of High Flowing Self-Compacting Concrete with Normal Strength (보통강도 고유동 자기충전 콘크리트의 수화발열 특성)

  • Choi, Yun-Wang;Kim, Byoung-Kwon;Lee, Jae-Nam;Ryu, Deug-Hyun;Song, Yong-Kyu;Jung, Woo-Yong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.497-500
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    • 2008
  • This research carries out experiments for hydration exothermic rate and adiabatic temperature rise of concrete to examine the characteristics of the hydration heat of high flowing self-compacting concrete with a normal strength. As a result of the hydration exothermic rate experiment, the high flowing self-compacting concrete that used Lime stone powder and fly ash as polymers shows that its hydration heat amount reduces due to the reduction of unit cement. The result measured the adiabatic temperature rise of concrete presents that high flowing self-compacting concrete having lots of binder contents has a good performance in temperature reduction due to the effect of polymer and that triple adding high flowing self-compacting concrete has a similar temperature rise speed with conventional concrete. As a result of the research, high flowing self-compacting concrete shows a better temperature reduction performance for the binder content per unit than conventional concrete. In addition, it is judged that triple adding high flowing self-compacting concrete with a specified concrete strength 30 MPa is more beneficial in temperature reduction and early hydration heat than double adding high flowing self-compacting concrete.

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Characterization of Thermal Properties of Concrte and Temperature Prediction Model (콘크리트재료의 열특성 및 수화열 해석)

  • 양성철
    • Magazine of the Korea Concrete Institute
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    • v.9 no.2
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    • pp.121-132
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    • 1997
  • The thermal behavior of' concrete can be ch;lracterized from a knowledge of concrete ternperatu1.e at early ages, environmental conditions, and cement hydration in the mixture. 'l'o account for thost. interactions, a computer model was developed for prwlicting the temperature pr.ol'ile in hnrdcning c o n c r c t ~ st.r~icture in terms of material and tmvironmcntal factors. The cerncnt hydration cha~.acteristics such as the activating energy, total heat 1ihei.atr.d. anti th\ulcorner degree of' hydration. can represent the internal heat gc,neration. In this study. th(> activating c1ncrgy and the tlcgree of' hydration curve were determined well fmm the rnortn~. compressive strength tests while total amount of heat liberated was determined by tht> isothermal calorimctcr method. The main purpose of' this study is to correlate measured tt>mperaturr distributions in a concrete st1,ucture during thc hardening process with the ~ c s u l t s computed f'ro~n theoretical considrl.ations. Using twodimensional heat transfer model, first. the importance of several parameters will be identified by a parametric analysis. Then, the tcmpcmture distribution of thc cylindrical concrete specimen in the laboratory was mensuwti and compared with that yielded by thc theoretical considel.ations.

Skin Hydration and Collagen Synthesis of AF-343 in HS68 Cell Line and NC/Nga Mice by Filaggrin Expression and Suppression of Matrix Metallopreteinase

  • Cho, Jae-We;Jeong, Yeon-Su;Han, Ji-Won;Chun, Young-Jin;Kim, Hyun-Kyu;Kim, Min-Young;Kim, Beom-Joon;Park, Ki-Moon;Kim, Jong-Keun;Kim, Jae-Hyun;Cho, Soo-Muk
    • Toxicological Research
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    • v.27 no.4
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    • pp.225-229
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    • 2011
  • Extract of Taraxacum platycarpum (AF-343) has been reported to have several biological properties such as skin hydration and anti-inflammatory effects. Although clinical evidences of skin hydration and antiinflammatory effect were proven in clinical trial, precise mechanism of skin hydration was not fully understood yet. In this study, we have focused skin hydration mechanism related filaggrin, collagen, and matrix metalloproteinase (MMP) in vitro and animal study. Herein, skin hydration mechanism of AF-343 is due to recovery of filaggrin in mice model and increased production of collagen with suppression of matrix MMP in vitro fibroblast cell line.

Thermal cracking assessment for nuclear containment buildings using high-strength concrete

  • Yang, Keun-Hyeok;Mun, Jae-Sung;Kim, Do-Gyeum;Chang, Chun-Ho;Mun, Ju-Hyun
    • Computers and Concrete
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    • v.26 no.5
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    • pp.429-438
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    • 2020
  • To shorten the construction times of nuclear facility structures, three high-strength concrete mixtures were developed with specific consideration given to their curing temperatures, their economic efficiency, and the practicality of their quality control. This study was conducted to examine the temperature rise profiles of these three concrete mixtures and the potential for early-age thermal cracking in the primary containment vessel of a nuclear reactor with a wall thickness of 1200 mm. The one-layer placement height of the concrete for the primary containment vessel was increased from the conventional 3 m to 3.5 m. A nonlinear finite element analysis (FEA) was conducted using the thermal properties of concrete determined from the isothermal hydration and adiabatic hydration tests, and tuned through comparisons made with temperature rise profiles obtained for 1200-mm-thick mock-up wall specimens cured at temperatures of 5, 20, and 35℃. The hydration heat performance of the three concrete mixtures and their potential to produce thermal cracking in nuclear facilities indicate that the mixtures have considerable potential for practical application to the primary containment vessel of a nuclear reactor at various curing temperatures, fulfilling the minimum requirements of the ACI 301 and minimizing the likelihood of the occurrence of thermal cracks.

Mechanical Properties of Cement Material for Energy-Foundation (EF) Structures

  • Park, Yong-Boo;Choi, Hang-Seok;Sohn, Jeong-Rak;Sim, Young-Jong;Lee, Chul-Ho
    • Land and Housing Review
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    • v.3 no.1
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    • pp.83-88
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    • 2012
  • In this study, physical characteristics of cement and/or concrete materials that are typically used for energy-foundation (EF) structures have been studied. The thermal conductivity and structural integrity of the cement-based materials were examined, which are commonly encountered in backfilling a vertical ground heat exchangers, cast-in-place concrete piles and concrete lining in tunnel. For this purpose the thermal conductivity and unconfined compression strength of cement-based materials with various curing conditions were experimentally estimated and compared. Hydration heat generated from massive concrete in the cast-in-place concrete energy pile was observed for 4 weeks to estimate its dissipation time in the underground. The hydration heat may mask the in-situ thermal response test (TRT) result performed in the cast-in-place concrete energy pile. It is concluded that at least two weeks are needed to dissipate the hydration heat in this case. In addition, a series of numerical analysis was performed to compare the effect of thermal property of the concrete material on the cast-in-place pile.

Considerations for Making Liposomes by Thin Film-Hydration Method

  • Gyeong-Tak Byeon;Ji-Yoon Son;Jeongsoo Yoo
    • Journal of Radiopharmaceuticals and Molecular Probes
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    • v.8 no.2
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    • pp.151-156
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    • 2022
  • Liposomes are bilayered particles that are surrounded by an aqueous solvent with amphiphilic substances such as phospholipids. Liposomes have the potential to overcome the limitations of physiochemical properties of existing drugs, and are therefore widely used in research for the treatment of many diseases, especially cancer. Currently, there are many liposome manufacturing methods that use various lipids and amphiphiles. Among them, the thin film-hydration method is a traditional and very simple method to prepare liposomes by hydrating a dry lipid film in an aqueous solvent, which has been widely used in the laboratory until recently. Recently, approaches to new nuclear imaging agents and radiotherapy by loading radioactive isotopes inside liposomes have been actively studied. In this review, we would like to discuss considerations for preparing liposomes using the thin film-hydration method.

Hydration Properties of Low Carbon type Low Heat Blended Cement (무기질 자극제를 사용한 탄소배출 저감형 저발열형 혼합시멘트의 수화특성에 관한 연구)

  • Choi, Sung-Woo;Ryu, Deuk-Hyun;Kim, Hun-Sang;Kim, Gyu-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.3
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    • pp.218-226
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    • 2013
  • Of construction materials, cement and steel are the representative material that carbon dioxide. to reduce carbon emissions in the use of these materials The purpose of this study is low heat type blended cement, which is manufactured using a amount of cement than ordinary low heat blended cement. Low heat blended cement, mixing ratio of 10%, was investigated hydration properties and adiabatic temperature of concrete. The study in order to activate the reaction mineral admixture, a separate source of CaO and $SO_3$ areneeded. gypsum and lime, it expected amount of cement, low-carbon low-heat blended cement could reduce the hydration heat concrete than currentlyused low heat blended cement.