• Title/Summary/Keyword: hydration properties

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Effect of Micro Organic-inorganic Complex on the Hydration of Portland Cement(II) (Mcchanical and rheological properties of PVA-montmorillonite complex cemenrt system) (마이크로 유기-무기 복합체가 포오틀랜드 시멘트 수화에 미치는 영향(II) (PVA-점토 복합체-시멘트 계의 기계적 유동학적 특징))

  • 김창은;김배연;최진호;이형복
    • Journal of the Korean Ceramic Society
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    • v.22 no.6
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    • pp.15-20
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    • 1985
  • In the course of cement hydration it was found that the addition of polyvinyl alcohol(contracted as PVA. here after) only in the cement paste could more influence on the set-retardation the depression of heat evol-ution rate than that of montmorillonit only or PVA-montmorillonie intercalation complex (PMIC) due to the effective adsorption of PVA on cement particles. The improved mechanical strength by addition of montmorillonite and PMIC was observed remarkably up to 0.05wt% due to the decrease of macro-pores caused by lowed viscosity or the acceleration of hydration reaction.

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Synthesis of High-Performance Polycarboxylate(PC)-Type Superplasticizer, and Its Fluidity and Hydration Behavior in Cement Based-System (폴리카복실레이트계 고성능 유동화제의 합성과 시멘트계 내의 유동 및 수화 반응 거동)

  • Shin, Jin-Yong;Chae, Eun-Jin;Hong, Ji-Sook;Suh, Jeong-Kwon;Hwang, Eui-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.77-80
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    • 2006
  • Graft copolymerized polycarboxylate(PC)-type superplasticizers(PCs) which have carboxylic acid with $\pi$ bond among the molecular structure and polyethyleneglycol methyl ether methacrylate(PMEM) were synthesized by free radical reaction and investigated the chemical structure, polymerization condition, and physical and chemical properties. Also, the effects of PCs in the dispersion, adsorption and hydration of cement were evaluated. As the molecular weight of graft chain decreases, the adsorption amount on cement particles increased. It was advantageous for the flow to reduce molar ratio, the lower the side bone molecular weight, and increase the molar ratio, the larger the side bone molecular weight. The hydration reaction speed was highly delayed at day 1, due to increase in molar ratio and reduction in side bone molecular weight, but it was recovered in the days after.

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Hydration heat properties of ternary system concrete using rejct fly ash (잔사회를 활용한 3성분계 시멘트의 수화열과 콘크리트의 단열온도 특성)

  • Lee, Seung-Heun;Lee, Seung-Tae;Lee, Jae-Man;Ryu, Deun-Hyun;Kim, Do-Kyun;Seo, Chan-Won
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.331-332
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    • 2009
  • The purpose of this study was to evaluate the effect of rejct fly-ash and blast-furnace slag on hydration heat and strength development of ternary system cement and concrete. Main experimental variables were performed fly-ash contenes (20%) and rejct fly-ash contents (20%) and slag contents (50%, 55%). The hydration heat and insulation temperature, strength development were measured to analyze the concrete of ternary system cement

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The Effect of ZnO on the Hydration Reaction and Physical Properties of Cement (Cement의 수화반응 물리특성에 미치는 ZnO의 영향)

  • 김홍기;추용식;이경희;송명신
    • Journal of the Korean Ceramic Society
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    • v.34 no.4
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    • pp.399-405
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    • 1997
  • With the increase of ZnO content, heat of hydration decreased. For specimens containing ZnO more than 0.6 wt.%, the compressive stength of cement cured for 28 days could not be measured because setting was not occurred. With the increase of ZnO content, Blaine specific surface area of cement was decreased and the residue of 45 ${\mu}{\textrm}{m}$ and 90 ${\mu}{\textrm}{m}$ was increased when cement was ground. That is, grindability became worse as ZnO increased in clinker. The difference of color as a function of ZnO content could not be observed, but in the excess of amount of ZnO added, color became more white and reddish yellow.

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Influences of the N.B.R. Latex on the Hydration of Gypsum Plaster (N. B. R. Latex가 석고 플라스터의 수화에 미치는 영향)

  • 형경우;이홍림;김창은
    • Journal of the Korean Ceramic Society
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    • v.19 no.3
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    • pp.187-192
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    • 1982
  • N.B.R. latex was used as the admixture in order to improve the various properties of gypsum plaster which is widely used as the construction material. The influences of N.B.R. latex on the hydration of gypsum plaster were studied. The results obtained are summerized as follows; 1. The water/gypsum plaster ratio is decreased wth increasing amounts of surfactant (P.O.E. Nonyl Phenol Ether) as the additive. 2. It is the pore of large size (${\gg}$7500A) that is mainly decreased with increasing amounts of surfactant. 3. With the small amount of surfactant as the additive, the hydration was slightly retarded, but was gradually recovered with increasing amounts of surfactant, and their heat of liberation after 20 hours were nearly same.

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Studies on thermal and swelling properties of Poly (NIPAM-co-2-HEA) based hydrogels

  • Shekhar, Suman;Mukherjee, M.;Sen, Akhil Kumar
    • Advances in materials Research
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    • v.1 no.4
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    • pp.269-284
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    • 2012
  • Thermoresponsive hydrogels based on N-Isopropylacrylamide (NIPAM) and 2-Hydroxyethylacrylate (HEA) were prepared by free radical polymerization. The hydrogels were characterized by elemental (CHN) analysis, differential scanning calorimetry (DSC) and thermo gravimetric analysis (TGA). DSC thermogram showed two endothermic transitions which are due to hydration of water present in different environments. One near $0^{\circ}C$ called melting transition of ice and was used to calculate the quantitative determination of the amounts of freezing and non freezing water. The other transition above the ambient temperature was due to the combination of hydrophobic hydration and hydrophilic hydration which changes with the copolymer compositions. Swelling and deswelling studies of the hydrogels were carried out using the aqueous media, salt and urea solutions. The experimental results from swelling studies revealed that copolymers have lower rates of swelling and deswelling than the homopolymer.

Experimental Study Mixing, Placing and Hydration Temperature of 1400kg/$\textrm{cm}^2$ Ultra High-Strength Concrete (1400kg/$\textrm{cm}^2$ 초고강도 콘크리트의 배합, 타설 및 수화온도 이력에 관한 연구)

  • 윤영수;장일영;원종필;최응규
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.430-435
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    • 1997
  • This paper presents the material properties and production of 1400kg/$\textrm{cm}^2$ ultra high-strength concrete in consideration of the history of hydration temperature for the practical utilization. A series of laboratory tests were conducted to optimize the mix proportion and then the full-scall mock up tests were performed to investigate the practicability. The thermal sensors were installed prior to concrete casting into the walls and columns, to measure the hydration temperature during the hardening process, which is inevitable to select the most appropriate curing scheme.

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International Test Mock-up of the Self-Heating of Cement Developed using a Reducing Slag (환원슬래그를 이용하여 개발된 자기발열 시멘트의 해외 Mock-up Test 관한 연구)

  • Min, Tae-Beom;Choi, Hyun-Kuk;Kim, Hyeong-Cheol;Kim, Jae-Young;An, Dong-Hee
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.228-229
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    • 2017
  • MOCK-UP TEST was conducted in the extreme region of the cement which was researched and developed by using the reducing slag Experimental results show that the basic properties (air volume, slump) are improved compared with the specimens using Mongolian cement. The compressive strength achieved the target strength (target strength: age 3day: 7MPa, age 7day 14MPa) and the hydration heat was about 8 ℃ higher than that of Mongolian cement products. Therefore, it is considered that the cement powders developed by our company showed the strength of concrete due to high hydration heat even at extreme temperatures.

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Hydration Properties of Cement Matrix using Surface Treatment Blast Furnace Slag by Arc Discharge (아크방전에 의해 표면개질 된 고로슬래그를 사용한 시멘트 경화체의 수화 특성)

  • Kim, Sun-A;Kim, Hyeon-Sung;Park, Sun-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.91-92
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    • 2018
  • A glassy thin film was formed on the surface of the blast furnace slag. When blast furnace slag is used as an admixture of concrete, addition of alkali activators were required. However, alkali activators are not only dangerous as chemical products, but they are also difficult to use as expensive materials. Therefore, it is necessary to study the way of removal of the glassy thin film of blast furnace slag without the risk and cost increase. In this study, to solve this problem, experiment was carried out to improve the hydration reactivity by treatment the surface of blast furnace slag using arc discharge. Experimental results show that when the surface of the blast furnace slag was tratmented by arc discharge, the glassy thin film was destroyed. And the hydration reactivity was improved, the compressive strength was increased.

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Fouling Mechanism of Microfiltration/Ultrafiltration by Macromolecules and a Suppression Strategy from the Viewpoint of the Hydration Structure at the Membrane Surface

  • Akamatsu, Kazuki;Nagumo, Ryo;Nakao, Shin-ichi
    • Membrane Journal
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    • v.30 no.4
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    • pp.205-212
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    • 2020
  • This short review focuses on fouling by proteins and macromolecules in microfiltration/ultrafiltration. First, an experimental system that enables investigation of how the extent of the adsorption of proteins and macromolecules on membrane surfaces contributes to a decrease in filtrate flux in microfiltration/ultrafiltration is described. Using this system, a causal relationship - not a correlation - indicating that adsorption results in a decrease in filtrate flux could be clearly demonstrated in some cases. Second, a hydration structure at the membrane surface that can suppress adsorption is discussed, inspired by biomaterial research. In their hydrated states, polymers with low-fouling properties have water molecules with a particular structure. Finally, some successful examples of the development of low-fouling membranes via surface modification using low-fouling polymers are discussed.