• Title/Summary/Keyword: hydration properties

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Fundamental Properties and Adiabatic Temperature Rise of Concrete with the Combination of Mineral and Chemical Admixture (혼화재료의 조합사용에 따른 콘크리트의 기초물성 및 단열온도상승 특성)

  • Jeon Chung Keun;Kim Jong;Shin Dong-An;Yoon Gi-Won;Han Cheon Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.345-348
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    • 2005
  • This paper presents the result of adiabetic temperature rise and fundamental properties of concrete combining admixtures. According to results, difference of setting time with I5.5hours is observed between S-P and R-F30 mixture. Based on the adiabetic temperature rise test, 8$^{circ}C$of heat producted occurs between E-P and R-F30 mixture. is applied to estimate the temperature rising under adiabetic curing condition, which exhibits closer consistency with tested value. The function mentioned above can account for the effect of dormant period in hydration process at early stage on hydration heat production. It reveals that the consideration of placing layer based on the mixture adjustment(E-P mixture at top layer and R-F30 mixture at bottom layer) in mass concreting will contribute to reduce hydration heat as well as alleviate tensile stress discrepancy between placing layer.

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Effects of Specimen Shape on Hydration Heat and Autogenous shrinkage at an early (시험체 형상에 따른 고강도 콘크리트의 수화열 및 자기수축 초기특성 분석)

  • Lee, Eui-Bae;Koo, Kyung-Mo;Kim, Young-Sun;Kim, Young-Duck;Kim, Gyu-Yong;Kim, Moo-Han
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.915-918
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    • 2008
  • Hydration heat and autogenous shrinkage are generated essentially by the same hydration. Many researchers have studied the close relationship between hydration temperature and autogenous shrinkage but hardly any research has been undertaken to explain the specific numerical relation. In this study, early age properties of hydration heat and autogenous shrinkage of specimen whose section size was changed were analyzed, and relationship between hydration heat and autogenous shrinkage was investigated. In the results of the study, inner temperature and autogenous shrinkage increased as the section size increased. And rise and rise ratio of hydration temperature and autogenous shrinkage in hydration heating section and autogenous shrinking section are increased too. Temperature rise and autogenous shrinkage rise increased respectively, as hydration heating velocity and autogenous shrinking velocity increased. And autogenous shrinkage rise and autogenous shrinking velocity increased as hydration heating velocity increased.

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Hydration and Electrical Resistance of Cement Composites Containing MWCNTs (MWCNT가 첨가된 시멘트복합체의 수화 및 전기저항 특성)

  • Lee, Gun-Cheol;Kim, Young-Min
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.1
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    • pp.11-18
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    • 2020
  • Carbon nanotubes are used in various industries with their excellent mechanical properties and electrical conductivity. In the construction industry, research is being conducted to give self-sensing capabilities to structures, but the results of experiments vary among researchers, and the analysis is insufficient. Therefore, in this study, the hydration and electrical properties of MWCNT-added cement pastes were measured. The electrical resistance values of hydration heat, porosity, Rietveld quantitative analysis, compressive strength, and distance were measured.. The heat resistance, porosity, Rietvelt quantitative analysis, compressive strength and distance were measured according to electrical resistance. Experimental results showed that the heat of hydration decreased with increasing MWCNT. XRD Rietveld quantitative analysis showed that there was no significant difference in the amount of hydration products with increasing addition rate of MWCNT. As a result of SEM analysis, the MWCNT is agglomerated by van der Waals forces, and this area is considered to be caused by voids and weak areas. The electrical resistance value decreases as the addition rate is increased, and thus may play a role for magnetic sensing in the future.

Hydration Characteristics and Synthesis of Hauyne-Belite Cement as Low Temperature Sintering Cementitious Materials

  • Park, Sang-Jin;Jeon, Se-Hoon;Kim, Kyung-Nam;Song, Myong-Shin
    • Journal of the Korean Ceramic Society
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    • v.55 no.3
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    • pp.224-229
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    • 2018
  • OPC production requires high calorific value and emits a large amount of $CO_2$ through decarbonation of limestone, accounting for about 7% of $CO_2$ emissions. To reduce $CO_2$ emissions during the Ordinary Portland Cement (OPC) production process, there is a method of reducing the consumption of cement or lower temperature calcination for OPC product. In this study, for energy consumption reduction, we prepared Hauyne-belite cement by calcination at a low temperature compared to that used for OPC and studied the early hydration properties of the synthesized Hauyne-belite cement. We set the ratios of Hauyne and belite to 8 : 2, 5 : 5 and 3 : 7. For the hydration properties of the synthesized Hauyne-belite cement, we tested heat of hydration of paste and the compressive strength of mortar, using XRD and SEM for analysis of hydrates. As for our results, the temperature for optimum synthesis of Hauyne-belite is $1,250^{\circ}C$. Compressive strength of synthesized Hauyne-belite cement is lower than that of OPC, but it is confirmed that compressive strength of synthesized Hauyne-belite cement with mixing in of some other materials can be similar to that of OPC.

Modeling of chloride diffusion in a hydrating concrete incorporating silica fume

  • Wang, Xiao-Yong;Park, Ki-Bong;Lee, Han-Seung
    • Computers and Concrete
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    • v.10 no.5
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    • pp.523-539
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    • 2012
  • Silica fume has long been used as a mineral admixture to improve the durability and produce high strength and high performance concrete. And in marine and coastal environments, penetration of chloride ions is one of the main mechanisms causing concrete reinforcement corrosion. In this paper, we proposed a numerical procedure to predict the chloride diffusion in a hydrating silica fume blended concrete. This numerical procedure includes two parts: a hydration model and a chloride diffusion model. The hydration model starts with mix proportions of silica fume blended concrete and considers Portland cement hydration and silica fume reaction respectively. By using the hydration model, the evolution of properties of silica fume blended concrete is predicted as a function of curing age and these properties are adopted as input parameters for the chloride penetration model. Furthermore, based on the modeling of physicochemical processes of diffusion of chloride ion into concrete, the chloride distribution in silica fume blended concrete is evaluated. The prediction results agree well with experiment results of chloride ion concentrations in the hydrating concrete incorporating silica fume.

Properties of Hydration and Strength of Sol-gol Derived Fine Particle in the System $CaO-P_2O_5-SiO_2$ (졸겔법에 의한 $CaO-P_2O_5-SiO_2$계 미세분말의 수화 및 강도특성)

  • 이형우;김정환
    • Journal of the Korean Ceramic Society
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    • v.31 no.10
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    • pp.1231-1239
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    • 1994
  • In this study, gel powder which had relatively high hydration reactivity in CaO and P2O5 rich composition of CaO-P2O5-SiO2-H2O system was prepared by sol-gel process and its hydrated specimen was manufactured. The it was investigated to appropriate calcination temperature in sol-gel process which hydrated specimen of gel powder have proven to strength and the effect of factors influenced strength in hydration process. The major product of before and after hydration reaction was hydroxyapatite, and crystalline phase of C-S-H was already formed during gelation process. After hydration reaction of pressed specimen, crystalline phase of C-S-P-H was formed. It was hydrated product of silicocarnotite (5CaO.P2O5.SiO2). Gel phases of C-S-H and C-S-P-H occured as a result of partial substitution of amorphous silica by P2O5 was formed. The strength of hydrated hardened body is developed by strong bonding and bridging between the gel phases of C-S-H or C-S-P-H and the crystalline products such as hydroxyapatite, Ca(OH)2 C-S-H and C-S-P-H. In addition, the ultrafine gel powder have an great effect on increase of hydration reaction.

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Study on the Mechanical Extraction Properties of Tobacco Stem Biomass (담배 주맥 바이오매스의 압착추출특성 연구)

  • Sung, Yong-Joo;Han, Young-Lim;Rhee, Moon-Soo
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.2
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    • pp.65-72
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    • 2008
  • This work evaluated the extractability of tobacco stem biomass for the papermaking type Reconstituted Tobacco Sheet(RTS). The effects of the soaking conditions on the hydration of stem biomass and the effects of the hydrated state on the mechanical extraction were investigated. In order to simulate the mechanical expression process of a papermaking type RTS mill, for example, the screw press process, the novel mechanical pressing analyzer was developed for this study. The hydration of stem biomass by soaking process was greatly affected by the soaking time and the soaking temperature. The longer soaking time and the higher soaking temperature resulted in the higher hydrated stem biomass. Since the higher hydrated stem had more combined water in the inner structure and resulted in the more flexible structure, the higher hydrated stem leaded to the more compressed filter cake and the higher water contents in the filter cake after the mechanical pressing. The pilot pulping experiments showed the difference in hydration and extractability between burley and bright tobacco stem. The bulkier structure of the burley stem resulted in the faster hydration by pilot pulping and leaded to the larger reduction in water soluble components. And the hydration process showed the major influence on the separation efficiency of water soluble components.

An Experimental Study on Hydration Heat and Strength Properties Concrete with High Volume Fly-Ash (플라이애시 콘크리트의 수화발열 특성과 압축강도 특성에 관한 실험적 연구)

  • 김우상;김광기;백민수;김우재;정재영;정상진
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.05a
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    • pp.67-71
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    • 2003
  • This study is for the great quantity use of fly-ash. For the producing of high volume concrete from the use of fly-ash, the method of replacement between bonding agents and fine aggregate by fly-ash at the same time was used. It was used that the adiabatic temperature rise of concrete about the mass member which bad been produced by the method that was mentioned before, and the hydration heat of the core test pieces in concrete was measured. Also the core test pieces which were replaced with fly-ash was studied by the compressive streneth's comparison between standard care test pieces and core test pieces. In the case of mass test pieces, hydration heat and the tine to reach the highest temperature were decreased by an increase in replaced fly-ash's amounts of concrete. In addition, among the test pieces having the same amounts of concrete, the test pieces having more replaced amounts of fly-ash's fine aggregate showed higher hydration heat and the increased time to reach the highest temperature. Compressive strength was also increased by hydration heat's decrease according to fly-ash replacement. Replacement of fly-ash was more effective in high temperature environment.

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Physicochemical Properties and Hydration of Rice on Various Polishing Degrees (도정도에 따른 쌀의 수화와 이화학적 특성)

  • Kim, Kyung-Ae;Jeon, Eun-Ryae
    • Korean Journal of Food Science and Technology
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    • v.28 no.5
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    • pp.959-964
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    • 1996
  • The physicochemical and gelatinization properties of rice flours, which were prepared by polishing nonwaxy brown rice (Dongjin byeo), depending on polishing degrees were investigated. The contents of protein, ash, lipid and fiber decreased significantly as the degrees of polishing increased and water uptake of rice grains decreased during hydration. When the surface of the soaked rice grains was examined by the SEM, extensive crack formation was observed. The water binding capacities, swelling power and solubility of rice flour increased as the polishing degree increased. By the amylogram, the initial gelatinization temperatures of rice flour decreased as the polishing degree increased and the peak viscosities, the breakdown and consistency of rice flour increased as the polishing degree increased.

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Starch properties of milled rices differing in hydration rates (쌀의 수화 그룹별 전분의 성질)

  • Kim, Chang-Joo;Kim, Sung-Kon;Jae, Jae-Chun;Kwon, Joong-Ho
    • Applied Biological Chemistry
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    • v.34 no.1
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    • pp.21-25
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    • 1991
  • Twenty-six japonica and 19 Tongil type milled rices were grouped based on water uptake rate at $23^{\circ}C$ and interrelationships between starch properties and hydration group were investigated. There were no significant differences in relative crystallinity, transmittance increase rate of 0.1% starch suspension and soluble amylose between japonica and Tongil type rices. The gel volume of starch n 3M KSCN solution of Tonsil type rice starch was significantly higher than that of japonica one. However, no correlations were observed between starch properties and hydration groups.

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